pH responsive Janus polymeric nanosheets

Peng Zhou Qian Wang Cheng-Liang Zhang Fu-Xin Liang Xiao-Zhong Qu Jiao-Li Li Zhen-Zhong Yang

Citation:  Peng Zhou, Qian Wang, Cheng-Liang Zhang, Fu-Xin Liang, Xiao-Zhong Qu, Jiao-Li Li, Zhen-Zhong Yang. pH responsive Janus polymeric nanosheets[J]. Chinese Chemical Letters, 2015, 26(6): 657-661. doi: 10.1016/j.cclet.2015.04.006 shu

pH responsive Janus polymeric nanosheets

    通讯作者: Qian Wang,
    Zhen-Zhong Yang,
  • 基金项目:

    Technology of China (No. 2012CB933200) (No. 2012CB933200)

摘要: pH responsive polymeric Janus nanosheets with poly(maleic acid) moiety and crosslinked PS onto the corresponding sides have been synthesized by free radical polymerization. The Janus nanosheets can serve as solid emulsifier to stabilize an oil/water emulsion, whose stability is easily triggered by changing pH across pKa of the poly(maleic acid).

English

  • 
    1. [1] P.G. de Gennes, Soft matter, Rev. Mod. Phys. 64 (1992) 645-648.[1] P.G. de Gennes, Soft matter, Rev. Mod. Phys. 64 (1992) 645-648.

    2. [2] L. Hong, A. Cacciuto, E. Luijten, S. Granick, Clusters of charged Janus spheres, Nano Lett. 6 (2006) 2510-2514.[2] L. Hong, A. Cacciuto, E. Luijten, S. Granick, Clusters of charged Janus spheres, Nano Lett. 6 (2006) 2510-2514.

    3. [3] A. Perro, S. Reculusa, S. Ravaine, E. Bourgeat-Lami, E. Duguet, Design and synthesis of Janus micro- and nanoparticles, J. Mater. Chem. 15 (2005) 3745-3760.[3] A. Perro, S. Reculusa, S. Ravaine, E. Bourgeat-Lami, E. Duguet, Design and synthesis of Janus micro- and nanoparticles, J. Mater. Chem. 15 (2005) 3745-3760.

    4. [4] A. Walther, A.H.E. Müller, Janus particles: synthesis, self-assembly, physical properties, and applications, Rev. Chem. 113 (2013) 5194-5261.[4] A. Walther, A.H.E. Müller, Janus particles: synthesis, self-assembly, physical properties, and applications, Rev. Chem. 113 (2013) 5194-5261.

    5. [5] S. Jiang, S. Granick, Janus Particles Synthesis Self-Assembly and Applications, RSC, London, England, 2012.[5] S. Jiang, S. Granick, Janus Particles Synthesis Self-Assembly and Applications, RSC, London, England, 2012.

    6. [6] F.X. Liang, C.L. Zhang, Z.Z. Yang, Rational design and synthesis of Janus composites, Adv. Mater. 26 (2014) 6944-6949.[6] F.X. Liang, C.L. Zhang, Z.Z. Yang, Rational design and synthesis of Janus composites, Adv. Mater. 26 (2014) 6944-6949.

    7. [7] R. Erhardt, A. Böker, H. Zettl, et al., Janus micelles, Macromolecules 34 (2001) 1069-1075.[7] R. Erhardt, A. Böker, H. Zettl, et al., Janus micelles, Macromolecules 34 (2001) 1069-1075.

    8. [8] Q. Xu, X.W. Kang, R.A. Bogomolni, S.W. Chen, Controlled assembly of Janus nanoparticles, Langmuir 26 (2010) 14923-14928.[8] Q. Xu, X.W. Kang, R.A. Bogomolni, S.W. Chen, Controlled assembly of Janus nanoparticles, Langmuir 26 (2010) 14923-14928.

    9. [9] M. Paulus, P. Degen, T. Brenner, et al., Sticking polydisperse hydrophobic magnetite nanoparticles to lipid membranes, Langmuir 26 (2010) 15945-15947.[9] M. Paulus, P. Degen, T. Brenner, et al., Sticking polydisperse hydrophobic magnetite nanoparticles to lipid membranes, Langmuir 26 (2010) 15945-15947.

    10. [10] J.P. Ge, Y.X. Hu, T.R. Zhang, Y.D. Yin, Superparamagnetic composite colloids with anisotropic structures, J. Am. Chem. Soc. 129 (2007) 8974-8975.[10] J.P. Ge, Y.X. Hu, T.R. Zhang, Y.D. Yin, Superparamagnetic composite colloids with anisotropic structures, J. Am. Chem. Soc. 129 (2007) 8974-8975.

    11. [11] K.P. Yuet, D.K. Hwang, R. Haghgooie, P.S. Doyle, Multifunctional superparamagnetic Janus particles, Langmuir 26 (2010) 4281-4287.[11] K.P. Yuet, D.K. Hwang, R. Haghgooie, P.S. Doyle, Multifunctional superparamagnetic Janus particles, Langmuir 26 (2010) 4281-4287.

    12. [12] L. Baraban, D. Makarov, R. Streubel, et al., Catalytic Janus motors on microfluidic chip: deterministic motion for targeted cargo delivery, ACS Nano 6 (2012) 3383- 3389.[12] L. Baraban, D. Makarov, R. Streubel, et al., Catalytic Janus motors on microfluidic chip: deterministic motion for targeted cargo delivery, ACS Nano 6 (2012) 3383- 3389.

    13. [13] N. Chaturvedi, Y.Y. Hong, A. Sen, D. Velegol, Magnetic enhancement of phototaxing catalytic motors, Langmuir 26 (2010) 6308-6313.[13] N. Chaturvedi, Y.Y. Hong, A. Sen, D. Velegol, Magnetic enhancement of phototaxing catalytic motors, Langmuir 26 (2010) 6308-6313.

    14. [14] L. Cheng, G.Z. Zhang, L. Zhu, D.Y. Chen, M. Jiang, Nanoscale tubular and sheetlike superstructures from hierarchical self-assembly of polymeric Janus particles, Angew. Chem. Int. Ed. 47 (2008) 10171-10174.[14] L. Cheng, G.Z. Zhang, L. Zhu, D.Y. Chen, M. Jiang, Nanoscale tubular and sheetlike superstructures from hierarchical self-assembly of polymeric Janus particles, Angew. Chem. Int. Ed. 47 (2008) 10171-10174.

    15. [15] Z.H. Nie, D. Fava, E. Kumacheva, et al., Self-assembly of metal-polymer analogues of amphiphilic triblock copolymers, Nat. Mater. 6 (2007) 609-614.[15] Z.H. Nie, D. Fava, E. Kumacheva, et al., Self-assembly of metal-polymer analogues of amphiphilic triblock copolymers, Nat. Mater. 6 (2007) 609-614.

    16. [16] B. Dong, B. Li, C.Y. Li, Janus nanoparticle dimers and chains via polymer single crystals, J. Mater. Chem. 21 (2011) 13155-13158.[16] B. Dong, B. Li, C.Y. Li, Janus nanoparticle dimers and chains via polymer single crystals, J. Mater. Chem. 21 (2011) 13155-13158.

    17. [17] T.Wang, S.R. Chen, F. Jin, et al., Droplet-assisted fabrication of colloidal crystals from flower-shaped porphyrin Janus particles, Chem. Commun. 51 (2015) 1367-1370.[17] T.Wang, S.R. Chen, F. Jin, et al., Droplet-assisted fabrication of colloidal crystals from flower-shaped porphyrin Janus particles, Chem. Commun. 51 (2015) 1367-1370.

    18. [18] A. Walther, K. Matussek, A.H.E. Müller, Engineering nanostructured polymer blends with controlled nanoparticle location using Janus particles, ACS Nano 2 (2008) 1167-1178.[18] A. Walther, K. Matussek, A.H.E. Müller, Engineering nanostructured polymer blends with controlled nanoparticle location using Janus particles, ACS Nano 2 (2008) 1167-1178.

    19. [19] H. Xu, R. Erhardt, V. Abetz, A.H.E. Müller, W.A. Goedel, Janus micelles at the air/water interface, Langmuir 17 (2001) 6787-6793.[19] H. Xu, R. Erhardt, V. Abetz, A.H.E. Müller, W.A. Goedel, Janus micelles at the air/water interface, Langmuir 17 (2001) 6787-6793.

    20. [20] S.H. Kim, A. Abbaspourrad, D.A. Weitz, Amphiphilic crescent-moon-shaped microparticles formed by selective adsorption of colloids, J. Am. Chem. Soc. 133 (2011) 5516-5524.[20] S.H. Kim, A. Abbaspourrad, D.A. Weitz, Amphiphilic crescent-moon-shaped microparticles formed by selective adsorption of colloids, J. Am. Chem. Soc. 133 (2011) 5516-5524.

    21. [21] A. Walther, M. Hoffmann, A.H.E. Müller, Emulsion polymerization using Janus particles as stabilizers, Angew. Chem. Int. Ed. 47 (2008) 711-714.[21] A. Walther, M. Hoffmann, A.H.E. Müller, Emulsion polymerization using Janus particles as stabilizers, Angew. Chem. Int. Ed. 47 (2008) 711-714.

    22. [22] B.P. Binks, P.D.I. Fletcher, Particles adsorbed at the oil-water interface: a theoretical comparison between spheres of uniform wettability and "Janus" particles, Langmuir 17 (2001) 4708-4710.[22] B.P. Binks, P.D.I. Fletcher, Particles adsorbed at the oil-water interface: a theoretical comparison between spheres of uniform wettability and "Janus" particles, Langmuir 17 (2001) 4708-4710.

    23. [23] N. Glaser, D.J. Adams, A. Böker, G. Krausch, Janus particles at liquid-liquid interfaces, Langmuir 22 (2006) 5227-5229.[23] N. Glaser, D.J. Adams, A. Böker, G. Krausch, Janus particles at liquid-liquid interfaces, Langmuir 22 (2006) 5227-5229.

    24. [24] Y.J. Liu, F.X. Liang, Q. Wang, X.Z. Qu, Z.Z. Yang, Flexible responsive Janus nanosheets, Chem. Commun. 51 (2015) 3562-3565.[24] Y.J. Liu, F.X. Liang, Q. Wang, X.Z. Qu, Z.Z. Yang, Flexible responsive Janus nanosheets, Chem. Commun. 51 (2015) 3562-3565.

    25. [25] T. Isojima, M. Lattuada, J.B.V. Sande, T.A. Hatton, Reversible clustering of pHand temperature-responsive Janus magnetic nanoparticles, ACS Nano 2 (2008) 1799-1806.[25] T. Isojima, M. Lattuada, J.B.V. Sande, T.A. Hatton, Reversible clustering of pHand temperature-responsive Janus magnetic nanoparticles, ACS Nano 2 (2008) 1799-1806.

    26. [26] T. Tanaka, M. Okayama, H. Minami, M. Okubo, Dual stimuli-responsive mushroom-like Janus polymer particles as particulate surfactants, Langmuir 26 (2010) 11732-11736.[26] T. Tanaka, M. Okayama, H. Minami, M. Okubo, Dual stimuli-responsive mushroom-like Janus polymer particles as particulate surfactants, Langmuir 26 (2010) 11732-11736.

    27. [27] H.L. Yang, F.X. Liang, X. Wang, et al., Responsive Janus composite nanosheets, Macromolecules 46 (2013) 2754-2759.[27] H.L. Yang, F.X. Liang, X. Wang, et al., Responsive Janus composite nanosheets, Macromolecules 46 (2013) 2754-2759.

    28. [28] T. Nisisako, T. Torii, T. Takahashi, Y. Takizawa, Synthesis of monodisperse bicolored Janus particles with electrical anisotropy using a microfluidic co-flow system, Adv. Mater. 18 (2006) 1152-1156.[28] T. Nisisako, T. Torii, T. Takahashi, Y. Takizawa, Synthesis of monodisperse bicolored Janus particles with electrical anisotropy using a microfluidic co-flow system, Adv. Mater. 18 (2006) 1152-1156.

    29. [29] S.H. Kim, S.J. Jeon, W.C. Jeong, H.S. Park, S.M. Yang, Optofluidic synthesis of electroresponsive photonic Janus balls with isotropic structural colors, Adv. Mater. 20 (2008) 4129-4134.[29] S.H. Kim, S.J. Jeon, W.C. Jeong, H.S. Park, S.M. Yang, Optofluidic synthesis of electroresponsive photonic Janus balls with isotropic structural colors, Adv. Mater. 20 (2008) 4129-4134.

    30. [30] X.Y. Ji, Q. Zhang, F.X. Liang, et al., Ionic liquid functionalized Janus nanosheets, Chem. Commun. 50 (2014) 5706-5709.[30] X.Y. Ji, Q. Zhang, F.X. Liang, et al., Ionic liquid functionalized Janus nanosheets, Chem. Commun. 50 (2014) 5706-5709.

    31. [31] Y. Nonomura, S. Komura, K. Tsujii, Adsorption of microstructured particles at liquid-liquid interfaces, J. Phys. Chem. B 110 (2006) 13124-13129.[31] Y. Nonomura, S. Komura, K. Tsujii, Adsorption of microstructured particles at liquid-liquid interfaces, J. Phys. Chem. B 110 (2006) 13124-13129.

    32. [32] Y. Nonomura, S. Komura, K. Tsujii, Adsorption of disk-shaped Janus beads at liquid-liquid interfaces, Langmuir 20 (2004) 11821-11823.[32] Y. Nonomura, S. Komura, K. Tsujii, Adsorption of disk-shaped Janus beads at liquid-liquid interfaces, Langmuir 20 (2004) 11821-11823.

    33. [33] F.X. Liang, K. Shen, X.Z. Qu, et al., Inorganic Janus nanosheets, Angew. Chem. Int. Ed. 50 (2011) 2379-2382.[33] F.X. Liang, K. Shen, X.Z. Qu, et al., Inorganic Janus nanosheets, Angew. Chem. Int. Ed. 50 (2011) 2379-2382.

    34. [34] J.R. Dorvee, A.M. Derfus, S.N. Bhatia, M.J. Sailor, Manipulation of liquid droplets using amphiphilic, magnetic one-dimensional photonic crystal chaperones, Nat. Mater. 3 (2004) 896-899.[34] J.R. Dorvee, A.M. Derfus, S.N. Bhatia, M.J. Sailor, Manipulation of liquid droplets using amphiphilic, magnetic one-dimensional photonic crystal chaperones, Nat. Mater. 3 (2004) 896-899.

    35. [35] F.X. Liang, J.G. Liu, X.Z. Qu, et al., Janus hollow spheres by emulsion interfacial selfassembled sol-gel process, Chem. Commun. 47 (2011) 1231-1233.[35] F.X. Liang, J.G. Liu, X.Z. Qu, et al., Janus hollow spheres by emulsion interfacial selfassembled sol-gel process, Chem. Commun. 47 (2011) 1231-1233.

    36. [36] Y. Chen, F.X. Liang, H.L. Yang, et al., Janus nanosheets of polymer-inorganic layered composites, Macromolecules 45 (2012) 1460-1467.[36] Y. Chen, F.X. Liang, H.L. Yang, et al., Janus nanosheets of polymer-inorganic layered composites, Macromolecules 45 (2012) 1460-1467.

    37. [37] A. Walther, X. André, M. Drechsler, V. Abetz, A.H.E. Müller, Janus discs, J. Am. Chem. Soc. 129 (2007) 6187-6198.[37] A. Walther, X. André, M. Drechsler, V. Abetz, A.H.E. Müller, Janus discs, J. Am. Chem. Soc. 129 (2007) 6187-6198.

    38. [38] A. Walther, M. Drechsler, A.H.E. Müller, Structures of amphiphilic Janus discs in aqueous media, Soft Matter 5 (2009) 385-390.[38] A. Walther, M. Drechsler, A.H.E. Müller, Structures of amphiphilic Janus discs in aqueous media, Soft Matter 5 (2009) 385-390.

    39. [39] L. Gao, K. Zhang, Y.M. Chen, Dumpling-like nanocomplexes of foldable Janus polymer sheets and spheres, ACS Macro Lett. 1 (2012) 1143-1145.[39] L. Gao, K. Zhang, Y.M. Chen, Dumpling-like nanocomplexes of foldable Janus polymer sheets and spheres, ACS Macro Lett. 1 (2012) 1143-1145.

    40. [40] A. Wolf, A. Walther, A.H.E. Müller, Janus triad: three types of nonspherical, nanoscale Janus particles from one single triblock terpolymer, Macromolecules 44 (2011) 9221-9229.[40] A. Wolf, A. Walther, A.H.E. Müller, Janus triad: three types of nonspherical, nanoscale Janus particles from one single triblock terpolymer, Macromolecules 44 (2011) 9221-9229.

    41. [41] R.H. Deng, F.X. Liang, P. Zhou, et al., Janus nanodisc of diblock copolymers, Adv. Mater. 26 (2014) 4469-4472.[41] R.H. Deng, F.X. Liang, P. Zhou, et al., Janus nanodisc of diblock copolymers, Adv. Mater. 26 (2014) 4469-4472.

    42. [42] J. He, D. Chen, X.M. Fan, et al., Reactive poly(divinyl benzene-co-maleic anhydride) nanoparticles: preparation and characterization, Chin. Chem. Lett. 24 (2013) 970-974.[42] J. He, D. Chen, X.M. Fan, et al., Reactive poly(divinyl benzene-co-maleic anhydride) nanoparticles: preparation and characterization, Chin. Chem. Lett. 24 (2013) 970-974.

    43. [43] H. Pan, M. Qi, Z.J. Zhang, Synthesis and study of MPNS/SMA nano-composite tanning agent, Chin. Chem. Lett. 19 (2008) 435-437.[43] H. Pan, M. Qi, Z.J. Zhang, Synthesis and study of MPNS/SMA nano-composite tanning agent, Chin. Chem. Lett. 19 (2008) 435-437.

    44. [44] T. Kitano, S. Kawaguchi, K. Ito, A. Minakata, Dissociation behavior of poly(fumaric acid) and poly(maleic acid), Macromolecules 20 (1987) 1598-1606.[44] T. Kitano, S. Kawaguchi, K. Ito, A. Minakata, Dissociation behavior of poly(fumaric acid) and poly(maleic acid), Macromolecules 20 (1987) 1598-1606.

  • 加载中
计量
  • PDF下载量:  0
  • 文章访问数:  1350
  • HTML全文浏览量:  22
文章相关
  • 发布日期:  2015-04-13
  • 收稿日期:  2015-02-12
  • 网络出版日期:  2015-03-23
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章