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Heterometallic zinc uranium oxyfluorides incorporating imidazole ligands

Xiao-Xiao Liu ,  Yuan Wang ,  Wan-Guo Tian ,  Weiting Yang ,  Zhong-Ming Sun

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Citation:  Xiao-Xiao Liu, Yuan Wang, Wan-Guo Tian, Weiting Yang, Zhong-Ming Sun. Heterometallic zinc uranium oxyfluorides incorporating imidazole ligands[J]. Chinese Chemical Letters, 2015, 26(6): 641-645. doi: 10.1016/j.cclet.2015.03.024 shu

Heterometallic zinc uranium oxyfluorides incorporating imidazole ligands

    • 通讯作者: Yuan Wang,
    Zhong-Ming Sun,
摘要: Two heterometallic uranium oxyfluorides with hybrid networks were hydrothermally synthesized by incorporating two imidazoles, 1-(biphenyl-4-yl)-1H-imidazole (bpi) and 1,4-di(1H-imidazol-1-yl)benzene (dib), formulated as Zn(bpi)2(UO2)2(H2O)F6 (1) and Zn(dib)(UO2)F4·0.5H2O (2). Compound 1 consists of chains of edge-sharing UO2F5 and UO2F4(H2O) pentagonal bipyramids, which are linked by Zn(bpi)2 moieties to form the sheet structure with decorated bpi. While in compound 2, sheets of edgesharing dimers of UO2F5 pentagonal bipyramids and ZnF3N2 polyhedra are linked by dib, creating a pillared three-dimensional framework. The two compounds represent the few examples of heterometallic uranium oxyfluorides incorporating organic ligands. The syntheses, structure as well as the IR spectra, UV-vis spectra and luminescent properties of the bimetallic uranium oxyfluorides are studied.

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  • 发布日期:  2015-03-27
  • 收稿日期:  2015-01-21
  • 网络出版日期:  2015-03-11
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