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The preparation and performance of visible-light-sensitized luminescent nanoparticles based on europium complex

Fu-Min Xue ,  Ming-Hui Liang ,  Zhen-Hua Wang ,  Ling-Yu Luan ,  Fu-Wei Li ,  Yan Cheng ,  Guang-Sheng Shao

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Citation:  Fu-Min Xue, Ming-Hui Liang, Zhen-Hua Wang, Ling-Yu Luan, Fu-Wei Li, Yan Cheng, Guang-Sheng Shao. The preparation and performance of visible-light-sensitized luminescent nanoparticles based on europium complex[J]. Chinese Chemical Letters, 2014, 25(2): 247-252. shu

The preparation and performance of visible-light-sensitized luminescent nanoparticles based on europium complex

    • 通讯作者: Fu-Min Xue,
  • 基金项目:

    ing Young Scientist Award (No. BS2011SW031). (No. BS2011SW031)

摘要: Long-wavelength-sensitized luminescent materials are desired for bio-detection. In this paper, we prepared a new kind of luminescent europium nanoparticles by a co-precipitation-condensation method. The luminescent europiumcomplex Eu(tta)3·bpt (tta = thenoyltrifluoroacetonate; bpt = 2-(N,N-di- ethylanilin-4-yl)-4,6-bis(pyrazol-1-yl)-1,3,5-triazine) was used as the active material, being encapsulated in the nanoparticles formed from 1H, 1H, 2H, 2H-perfluorooctyltrimethoxysilane (PFOTS) and poly(styrene-co-methyl methacrylate) [P(ST-co-MMA)]. The prepared nanoparticles not only can be well dispersed in water but also were of high photostability. Importantly, the nanoparticles displayed maximal excitation wavelength at 425 nm as well as an extended excitation wavelength up to 480 nm and a quantum yield for Eu3+ luminescence of 0.22 (λex = 425 nm, room temperature).

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  • 收稿日期:  2013-09-30
  • 网络出版日期:  2013-10-15
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