2D Naphthalenedisulfonate-cadmiun coordination polymer with 2, 4, 5-tri(4-pyridyl)-imidazole as a co-ligand：Structure and catalytic property

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2D Naphthalenedisulfonate-cadmiun coordination polymer with 2, 4, 5-tri(4-pyridyl)-imidazole as a co-ligand：Structure and catalytic property

Xing-Wei Wang , Hui Guo , Meng-Jie Liu , Xin-Yi Wang , Dong-Sheng Deng

Citation: Xing-Wei Wang, Hui Guo, Meng-Jie Liu, Xin-Yi Wang, Dong-Sheng Deng. 2D Naphthalenedisulfonate-cadmiun coordination polymer with 2, 4, 5-tri(4-pyridyl)-imidazole as a co-ligand：Structure and catalytic property[J]. Chinese Chemical Letters, 2014, 25(2): 243-246. shu

shu

2D Naphthalenedisulfonate-cadmiun coordination polymer with 2, 4, 5-tri(4-pyridyl)-imidazole as a co-ligand：Structure and catalytic property

通讯作者: Xin-Yi Wang,
Dong-Sheng Deng,

基金项目:
We gratefully acknowledge the financial support from the National Natural Science Foundation of China (No.21272109) (No.21272109)

the Natural Science Foundation of Henan Province (No.112300410138) (No.112300410138)

the Foundation of the Education Department of Henan Province (No.2011B150021) (No.2011B150021)

摘要: A new 2D coordination polymer, [Cd(tpim)(1,5-nds)]_n(1), was constructed from 1,5-naphthalenedisulfonate (1,5-nds), 2,4,5-tri(4-pyridyl)-imidazole (tpim) and Cd(CH₃COO)₂·2H₂O, which can be subsequently used to promote the epoxide ring-opening reaction of epoxides and amines with remarkable catalytic activity. In addition, the thermal and luminescent properties of 1 in the solid state were also investigated.

关键词:

English

2D Naphthalenedisulfonate-cadmiun coordination polymer with 2, 4, 5-tri(4-pyridyl)-imidazole as a co-ligand：Structure and catalytic property

1.
a Institute of Resources & Environment, Henan Polytechnic University, Jiaozuo 454150, China;
2.
b College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, China

Corresponding author: Xin-Yi Wang, Dong-Sheng Deng,

Received Date: 29 July 2013
Fund Project:

Abstract: A new 2D coordination polymer, [Cd(tpim)(1,5-nds)]_n(1), was constructed from 1,5-naphthalenedisulfonate (1,5-nds), 2,4,5-tri(4-pyridyl)-imidazole (tpim) and Cd(CH₃COO)₂·2H₂O, which can be subsequently used to promote the epoxide ring-opening reaction of epoxides and amines with remarkable catalytic activity. In addition, the thermal and luminescent properties of 1 in the solid state were also investigated.

Key words:

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