Spectral and self-assembly properties of a series of asymmetrical pyrene derivatives

注册 English

Spectral and self-assembly properties of a series of asymmetrical pyrene derivatives

Peng-Xia Liang , Dong Wang , Zong-Cheng Miao , Zhao-Kui Jin , Huai Yang , Zhou Yang

Citation: Peng-Xia Liang, Dong Wang, Zong-Cheng Miao, Zhao-Kui Jin, Huai Yang, Zhou Yang. Spectral and self-assembly properties of a series of asymmetrical pyrene derivatives[J]. Chinese Chemical Letters, 2014, 25(2): 237-242. shu

shu

Spectral and self-assembly properties of a series of asymmetrical pyrene derivatives

通讯作者: Dong Wang,
Zhou Yang,

基金项目:
This work was partially supported by Beijing Natural Science Foundation (No. 2122042) (No. 2122042)

the Fundamental Research Funds for the Central Universities (No. FRF-TP-09-010B) (No. FRF-TP-09-010B)

the National Natural Science Fund for Distinguished Young Scholar (No. 51025313). (No. 51025313)

摘要: A series of pyrene derivatives with different asymmetrical substituents were successfully synthesized and characterized. The geometrical electronic structures of the asymmetrical pyrene derivatives were performed by density functional theory (DFT) calculations. The results of photophysical spectra and electrochemical analysis indicated that the optical or electric properties of the pyrene derivatives could be tuned by adjust the π-conjugation lengths of the substituents. Furthermore, through a phase exchange self-assembly method, the highly organized morphologies were observed by SEM.

关键词:

Asymmetrical
/ Pyrene
/ Self-assembly

English

Spectral and self-assembly properties of a series of asymmetrical pyrene derivatives

1.
School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China

Corresponding author: Dong Wang, Zhou Yang,

Received Date: 14 August 2013
Fund Project:

Abstract: A series of pyrene derivatives with different asymmetrical substituents were successfully synthesized and characterized. The geometrical electronic structures of the asymmetrical pyrene derivatives were performed by density functional theory (DFT) calculations. The results of photophysical spectra and electrochemical analysis indicated that the optical or electric properties of the pyrene derivatives could be tuned by adjust the π-conjugation lengths of the substituents. Furthermore, through a phase exchange self-assembly method, the highly organized morphologies were observed by SEM.

Key words:

Asymmetrical
/ Pyrene
/ Self-assembly

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