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Synthesis of calix[4]arene derivatives via a Pd-catalyzed Sonogashira reaction and their recognition properties towards phenols

Yue Sun ,  Fan Zhang ,  Li Zhang ,  Li Luo ,  Zhi-Long Zou ,  Xian-Liang Cao ,  Shi-Liang Tan ,  Jia-Hai Bi ,  De-Mei Tian ,  Hai-Bing Li

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Citation:  Yue Sun, Fan Zhang, Li Zhang, Li Luo, Zhi-Long Zou, Xian-Liang Cao, Shi-Liang Tan, Jia-Hai Bi, De-Mei Tian, Hai-Bing Li. Synthesis of calix[4]arene derivatives via a Pd-catalyzed Sonogashira reaction and their recognition properties towards phenols[J]. Chinese Chemical Letters, 2014, 25(2): 226-228. shu

Synthesis of calix[4]arene derivatives via a Pd-catalyzed Sonogashira reaction and their recognition properties towards phenols

    • 通讯作者: De-Mei Tian,
    Hai-Bing Li,
  • 基金项目:

    This work was financially supported by the National Natural Science Foundation of China (Nos. 21372092, 21072072, 21102051) (Nos. 21372092, 21072072, 21102051)

    PCSIRT (No. IRTO953) (No. IRTO953)

    Program for New Century Excellent Talent in University (No. NCET-10-0428) (No. NCET-10-0428)

    operation of MOE (Nos. CCNU11C01002, CCNU13F005) (Nos. CCNU11C01002, CCNU13F005)

    Chemometrics (201003). (201003)

摘要: A novel series of calix[4]arene derivatives were synthesized via a Pd-catalyzed Sonogashira coupling reaction from para-substituted iodobenzene and 25,27-dipropargyl-calix[4]arene. Fluorescence studies found that nitro-phenols clearly exhibited quenching effects on 2c. Moreover, we minimized the free energy of the complexes by theoretical calculations. As the result, the π-π stacking interactions take place between the 4-nitrophenol and calix[4]arene, which may lead to the significant fluorescence quench.

English

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  • 收稿日期:  2013-07-22
  • 网络出版日期:  2013-09-26
通讯作者: 陈斌, bchen63@163.com
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