注册 English

Preparation and characterization of polyphenylene sulfide-based chelating fibers

Dong-Ju Zhou ,  Li-Bo Dai ,  Hui Ni ,  Gen-Lei Hui ,  Si-Guo Yuan

downloadPDF
Citation:  Dong-Ju Zhou, Li-Bo Dai, Hui Ni, Gen-Lei Hui, Si-Guo Yuan. Preparation and characterization of polyphenylene sulfide-based chelating fibers[J]. Chinese Chemical Letters, 2014, 25(2): 221-225. shu

Preparation and characterization of polyphenylene sulfide-based chelating fibers

    • 通讯作者: Si-Guo Yuan,
  • 基金项目:

    We gratefully acknowledge generous support by the National Natural Science Foundation of China (No. 20574063) (No. 20574063)

    Doctoral Foundation of Ministry of Education of China (No. 20104101110005). (No. 20104101110005)

摘要: A series of novel chelating fibers containing sulfur, nitrogen, oxygen heteroatoms were prepared via the functionalization of chloromethylated polyphenylene sulfide (CMPPS). The structures, micromorphology and physicochemical properties of these fibrous adsorptive materials were characterized by FT-IR, elementary analysis, TG and SEM-EDS. The results show that chelating fibers had high functional group contents (3.94 mmol/g for thiourea, 3.85 mmol/g for mercapto, 5.00 mmol/g for methylamine and 6.07 mmol/g for ethylenediamine, respectively). Owing to the unique matrix of polyphenylene sulfide fiber, these fibrous adsorbents possess excellent thermostability. This syntheticmethod proved a simple and efficient way for the preparation of chelating fibers.

English

  • 

    1. [1] Y. Sun, Z.C. Li, Y. Xu, Preparation and application of a novel orotic acid chelating resin for removal of Cu(Ⅱ) in aqueous solutions, Chin. Chem. Lett. 24 (2013) 747- 750.[1] Y. Sun, Z.C. Li, Y. Xu, Preparation and application of a novel orotic acid chelating resin for removal of Cu(Ⅱ) in aqueous solutions, Chin. Chem. Lett. 24 (2013) 747- 750.

    2. [2] S. Kagaya, E. Maeba, Y. Inoue, et al., A solid phase extraction using a chelate resin immobilizing carboxymethylated pentaethylenehexamine for separation and preconcentration of trace elements in water samples, Talanta 79 (2009) 146-152.[2] S. Kagaya, E. Maeba, Y. Inoue, et al., A solid phase extraction using a chelate resin immobilizing carboxymethylated pentaethylenehexamine for separation and preconcentration of trace elements in water samples, Talanta 79 (2009) 146-152.

    3. [3] S. Kagaya, H. Miyazaki, Y. Inoue, et al., Chelating fibers prepared with a wet spinning technique using a mixture of a viscose solution and a polymer ligand for the separation of metal ions in an aqueous solution, J. Hazard. Mater. 203-204 (2012) 370-373.[3] S. Kagaya, H. Miyazaki, Y. Inoue, et al., Chelating fibers prepared with a wet spinning technique using a mixture of a viscose solution and a polymer ligand for the separation of metal ions in an aqueous solution, J. Hazard. Mater. 203-204 (2012) 370-373.

    4. [4] M. Monier, N. Nawar, D.A. Abdel-Latif, Preparation and characterization of chelating fibers based on natural wool for removal Hg(Ⅱ), Cu(Ⅱ) and Co(Ⅱ) metal ions from aqueous solution, J. Hazard. Mater. 184 (2010) 118-125.[4] M. Monier, N. Nawar, D.A. Abdel-Latif, Preparation and characterization of chelating fibers based on natural wool for removal Hg(Ⅱ), Cu(Ⅱ) and Co(Ⅱ) metal ions from aqueous solution, J. Hazard. Mater. 184 (2010) 118-125.

    5. [5] Y. Tian, M. Wu, R.G. Liu, et al., Modified native cellulose fibers - a novel efficient adsorbent for both fluoride and arsenic, J. Hazard. Mater. 185 (2011) 93-100.[5] Y. Tian, M. Wu, R.G. Liu, et al., Modified native cellulose fibers - a novel efficient adsorbent for both fluoride and arsenic, J. Hazard. Mater. 185 (2011) 93-100.

    6. [6] L. Xu, J.N. Wang, Y. Meng, A.M. Li, Fast removal of heavy metal ions and phytic acids from water using new modified chelating fiber, Chin. Chem. Lett. 23 (2012) 105-108.[6] L. Xu, J.N. Wang, Y. Meng, A.M. Li, Fast removal of heavy metal ions and phytic acids from water using new modified chelating fiber, Chin. Chem. Lett. 23 (2012) 105-108.

    7. [7] A. Jyo, J.Y. Hamabe, H. Matsuura, et al., Preparation of bifunctional chelating fiber containing iminodi(methylphosphonate) and sulfonate and its performances in column-mode uptake of Cu(Ⅱ) and Zn(Ⅱ), React. Funct. Polym. 70 (2010) 508-515.[7] A. Jyo, J.Y. Hamabe, H. Matsuura, et al., Preparation of bifunctional chelating fiber containing iminodi(methylphosphonate) and sulfonate and its performances in column-mode uptake of Cu(Ⅱ) and Zn(Ⅱ), React. Funct. Polym. 70 (2010) 508-515.

    8. [8] K. Ikeda, D. Umeno, K. Sario, et al., Removal of boron using nylon-based chelating fibers, Ind. Eng. Chem. Res. 50 (2011) 5727-5732.[8] K. Ikeda, D. Umeno, K. Sario, et al., Removal of boron using nylon-based chelating fibers, Ind. Eng. Chem. Res. 50 (2011) 5727-5732.

    9. [9] L.H. Zhang, X.S. Zhang, P.P. Li, W.Q. Zhang, Effective Cd2+ chelating fiber based on polyacrylonitrile, React. Funct. Polym. 69 (2009) 48-54.[9] L.H. Zhang, X.S. Zhang, P.P. Li, W.Q. Zhang, Effective Cd2+ chelating fiber based on polyacrylonitrile, React. Funct. Polym. 69 (2009) 48-54.

    10. [10] Y. Meng, J.N. Wang, L. Xu, A.M. Li, Fast removal of Pb2+ from water using new chelating fiber modified with acylamino and amino groups, Chin. Chem. Lett. 23 (2012) 496-499.[10] Y. Meng, J.N. Wang, L. Xu, A.M. Li, Fast removal of Pb2+ from water using new chelating fiber modified with acylamino and amino groups, Chin. Chem. Lett. 23 (2012) 496-499.

    11. [11] X.R. Li, J.J. Huang, S.G. Yuan, Preparation of polyphenylene sulfide strong acid ion exchange fiber and the adsorption properties for Cr(Ⅲ), Polym. Mater. Sci. Eng. 28 (2012) 145-149.[11] X.R. Li, J.J. Huang, S.G. Yuan, Preparation of polyphenylene sulfide strong acid ion exchange fiber and the adsorption properties for Cr(Ⅲ), Polym. Mater. Sci. Eng. 28 (2012) 145-149.

    12. [12] J.J. Huang, X. Zhang, L.L. Bai, S.G. Yuan, Polyphenylene sulfide based anion exchange fiber: synthesis, characterization and adsorption of Cr(VI), J. Environ. Sci. 24 (2012) 1433-1438.[12] J.J. Huang, X. Zhang, L.L. Bai, S.G. Yuan, Polyphenylene sulfide based anion exchange fiber: synthesis, characterization and adsorption of Cr(VI), J. Environ. Sci. 24 (2012) 1433-1438.

    13. [13] L.Q. Yang, Y.F. Li, X.L. Jin, et al., Synthesis and characterization of a series of chelating resins containing amino/imino-carboxyl groups and their adsorption behavior for lead in aqueous phase, Chem. Eng. J. 168 (2011) 115-124.[13] L.Q. Yang, Y.F. Li, X.L. Jin, et al., Synthesis and characterization of a series of chelating resins containing amino/imino-carboxyl groups and their adsorption behavior for lead in aqueous phase, Chem. Eng. J. 168 (2011) 115-124.

    14. [14] Q.S. Ren, W.Q. Huang, B.L. He, Synthesis of polystyrylsulfonylthiourea resin and its chelate property for Au3+ ion, Ion Exch. Adsorp. 5 (1989) 131-134.[14] Q.S. Ren, W.Q. Huang, B.L. He, Synthesis of polystyrylsulfonylthiourea resin and its chelate property for Au3+ ion, Ion Exch. Adsorp. 5 (1989) 131-134.

    15. [15] X.M. Wu, C.H. Xiong, Z.N. Shu, Adsorption of silver onto thiol-resin and its mechanism, J. Chem. Ind. Eng. 54 (2003) 1466-1469.[15] X.M. Wu, C.H. Xiong, Z.N. Shu, Adsorption of silver onto thiol-resin and its mechanism, J. Chem. Ind. Eng. 54 (2003) 1466-1469.

    16. [16] A. Wolowicz, Z. Hubicki, The use of the chelating resin of a new generation Lewatit Monoplus TP-220 with the bis-picolylamine functional groups in the removal of selected metal ions from acidic solutions, Chem. Eng. J. 197 (2012) 493-508.[16] A. Wolowicz, Z. Hubicki, The use of the chelating resin of a new generation Lewatit Monoplus TP-220 with the bis-picolylamine functional groups in the removal of selected metal ions from acidic solutions, Chem. Eng. J. 197 (2012) 493-508.

    17. [17] L. Niu, S.B. Deng, G. Yu, J. Huang, Efficient removal of Cu(Ⅱ), Pb(Ⅱ), Cr(VI) and As(V) from aqueous solution using an aminated resin prepared by surface-initiated atom transfer radical polymerization, Chem. Eng. J. 165 (2010) 751-757.[17] L. Niu, S.B. Deng, G. Yu, J. Huang, Efficient removal of Cu(Ⅱ), Pb(Ⅱ), Cr(VI) and As(V) from aqueous solution using an aminated resin prepared by surface-initiated atom transfer radical polymerization, Chem. Eng. J. 165 (2010) 751-757.

    18. [18] N.F. Ma, Y. Yang, S.X. Chen, Q.K. Zhang, Preparation of amine group-containing chelating fiber for thorough removal of mercury ions, J. Hazard. Mater. 171 (2009) 288-293.[18] N.F. Ma, Y. Yang, S.X. Chen, Q.K. Zhang, Preparation of amine group-containing chelating fiber for thorough removal of mercury ions, J. Hazard. Mater. 171 (2009) 288-293.

  • 加载中
WeChat 扫一扫看文章
计量
  • PDF下载量:  0
  • 文章访问数:  1426
  • HTML全文浏览量:  57
文章相关
  • 收稿日期:  2013-07-22
  • 网络出版日期:  2013-11-06
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章

All Rights Reserved by the Chinese Chemical Society   中国化学会 版权所有 京ICP备05002797号

本系统由北京仁和汇智信息技术有限公司开发    技术支持: info@rhhz.net