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以4’-羟基-联苯-4-羧酸和1,3-二(4-吡啶基)丙烷构筑的一维锌配位聚合物的晶体结构与荧光性质

刘道森 ,  梁法库 ,  王志武

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引用本文: 刘道森, 梁法库, 王志武. 以4’-羟基-联苯-4-羧酸和1,3-二(4-吡啶基)丙烷构筑的一维锌配位聚合物的晶体结构与荧光性质[J]. 无机化学学报, 2013, 29(9): 2007-2012. doi: 10.3969/j.issn.1001-4861.2013.00.262 shu
Citation:  LIU Dao-Sen, LIANG Fa-Ku, WANG Zhi-Wu. Synthesis, Structure and Luminescence of a 1D Zinc(Ⅱ) Coordination Polymer Constructed from 4’-Hydroxyl-biphenyl-4-carboxylate and 1,3-Bis(4-pyridyl)propane Ligands[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(9): 2007-2012. doi: 10.3969/j.issn.1001-4861.2013.00.262 shu

以4’-羟基-联苯-4-羧酸和1,3-二(4-吡啶基)丙烷构筑的一维锌配位聚合物的晶体结构与荧光性质

  • 基金项目:

    齐齐哈尔大学青年教师科研启动基金(No．2011K-M07)资助项目。 (No．2011K-M07)

摘要: 水热条件下采用Zn(NO3)2·6H2O,4'-羟基-联苯-4-羧酸和1,3-二(4-吡啶基)丙烷作为反应物合成出一个新的一维锌金属配位聚合物{[Zn(Hhbc)2(bpp)]·H2O}n (1)(Hhbc=4'-羟基-联苯-4-羧酸,bpp=1,3-二(4-吡啶基)丙烷),并分别用元素分析、红外光谱、差热分析、X-射线粉末衍射和X-射线单晶衍射等表征了该结构。晶体结构分析结果表明:化合物1为一维链状锌(Ⅱ)配位聚合物,通过分子间的O-H…O氢键作用,一维链进一步被连接成二维超分子结构。荧光分析表明常温固态下配合物1发射蓝色荧光,荧光寿命为3.08 ns(480 nm)。

English

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  • 收稿日期:  2013-01-19
  • 网络出版日期:  2013-03-25
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