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3,4-吡啶二酸钡配合物的合成、结构、荧光和热稳定性研究

左锣 ,  冯建华 ,  郭莉 ,  李会会 ,  吴刚

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引用本文: 左锣, 冯建华, 郭莉, 李会会, 吴刚. 3,4-吡啶二酸钡配合物的合成、结构、荧光和热稳定性研究[J]. 无机化学学报, 2013, 29(9): 1979-1984. doi: 10.3969/j.issn.1001-4861.2013.00.291 shu
Citation:  ZUO Luo, FENG Jian-Hua, GUO Li, LI Hui-Hui, WU Gang. Synthesis, Structure, Luminescest and Thermal Stable Properties of 3,4-Pyridinedicarboxylic Acid Barium Complex[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(9): 1979-1984. doi: 10.3969/j.issn.1001-4861.2013.00.291 shu

3,4-吡啶二酸钡配合物的合成、结构、荧光和热稳定性研究

  • 基金项目:

    安徽省自然科学基金(No.1208085MB31) (No.1208085MB31)

    安徽省应用化学重点建设学科基金(No.200802187C) (No.200802187C)

    安徽省化学工程与工艺教学团队 (No.20101035) (No.20101035)

    滁州学院大学生科研项目(No.2012XS18,2012XS19)资助项目。 (No.2012XS18,2012XS19)

摘要: BaCl2·2H2O和配体3,4-吡啶二酸在溶剂热条件下反应生成了配合物[Ba2(pdc)2(H2O)3]n (1)(H2pdc=3,4-吡啶二酸),用单晶X-射线、元素分析和FT-IR对生成的晶体进行了表征。Ba1和Ba2分别采取了八配位扭曲四方反棱柱和十配位的双帽四棱柱几何构型,整个pdc2-作为四齿桥联配体连结4个不同的Ba(Ⅱ)原子形成二维网结构,O-H…N氢键将二维网结合在一起形成三维结构。还研究了配合物1的荧光和热重性质。

English

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  • 收稿日期:  2012-07-23
  • 网络出版日期:  2013-05-04
通讯作者: 陈斌, bchen63@163.com
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