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邻菲啰啉衍生物与柔性二羧酸构筑的铅(Ⅱ)配位聚合物：合成、结构与表征

孔治国 ,  孙旭冉 ,  李赫 ,  范艳佳 ,  张林

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引用本文: 孔治国, 孙旭冉, 李赫, 范艳佳, 张林. 邻菲啰啉衍生物与柔性二羧酸构筑的铅(Ⅱ)配位聚合物：合成、结构与表征[J]. 无机化学学报, 2013, 29(9): 1942-1946. doi: 10.3969/j.issn.1001-4861.2013.00.249 shu
Citation:  KONG Zhi-Guo, SUN Xu-Ran, LI He, FAN Yan-Jia, ZHANG Lin. Synthesis, Structure and Characterization of Pb(Ⅱ) Coordination Polymer Constructed by 1,10-Phenanthroline Derivative and Succinic Acid[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(9): 1942-1946. doi: 10.3969/j.issn.1001-4861.2013.00.249 shu

邻菲啰啉衍生物与柔性二羧酸构筑的铅(Ⅱ)配位聚合物：合成、结构与表征

  • 基金项目:

    吉林省科技发展计划项目基金(No.201105085)资助项目。 (No.201105085)

摘要: 通过水热合成的方法得到了一个新的化合物[Pb2(L1)2(L2)2],并对该化合物进行了元素分析、红外、热重和单晶X-射线表征(H2L1为丁二羧酸阴离子,L2为邻菲啰啉衍生物)。该化合物属于单斜晶系,空间群P21/c,晶胞参数:a=0.795 40(10) nm,b=2.649 0(3) nm,c=1.996 9(2) nm,β=99.784(2)°,V=4.1463(9) nm3,Z=4,R=0.038 0,wR=0.084 5。在该化合物中,丁二酸阴离子连接着铅原子形成一维链状结构。此外,链与链之间的π-π相互作用使一维链形成了三维超分子结构。最后,N-H…29…29O氢键进一步地稳定了此三维超分子结构。

English

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  • 收稿日期:  2012-10-18
  • 网络出版日期:  2013-03-28
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