Synthesis of a novel naphthyl-based self-catalyzed phthalonitrile polymer

注册 English

Synthesis of a novel naphthyl-based self-catalyzed phthalonitrile polymer

Feng-Hua Zhao , Ruo-Jin Liu , Xiao-Yan Yu , Kimiyoshi-Naito , Cheng-Chun Tang , Xiong-Wei Qua , Qing-Xin Zhang

Citation: Feng-Hua Zhao, Ruo-Jin Liu, Xiao-Yan Yu, Cheng-Chun Tang, Xiong-Wei Qua, Qing-Xin Zhang. Synthesis of a novel naphthyl-based self-catalyzed phthalonitrile polymer[J]. Chinese Chemical Letters, 2015, 26(6): 727-729. doi: 10.1016/j.cclet.2015.03.025 shu

shu

Synthesis of a novel naphthyl-based self-catalyzed phthalonitrile polymer

通讯作者: Xiao-Yan Yu,
Qing-Xin Zhang,

基金项目:

Innovative Research Team in University (No. IRT13060). The authors also thank the financial support from Natural Science Foundation of Hebei Province (No. E2014202033). (No. IRT13060)

摘要: A novel naphthyl-based self-catalyzed phthalonitrile monomer was prepared via nucleophilic displacement reaction. The structure was characterized by Fourier infrared spectrum (FT-IR) and nuclear magnetic resonance (¹H NMR). The polymerization mechanism was explored. Thermal properties were characterized by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA), which demonstrated self-promoted behavior and excellent heat resistance.

关键词:

English

Synthesis of a novel naphthyl-based self-catalyzed phthalonitrile polymer

1.
a Institute of Polymer Science and Engineering, School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300130, China;
2.
b Key Lab for Micro-and Nano-Scale Boron Nitride Materials in Hebei Province, Hebei University of Technology, Tianjin 300130, China;
3.
c National Institute for Materials Science (NIMS), 1-2-1 Sengen, Tsukuba-city, Ibaraki 305-0047, Japan

Corresponding author: Xiao-Yan Yu, Qing-Xin Zhang,

Received Date: 01 December 2014
Available Online: 28 March 2015

Abstract: A novel naphthyl-based self-catalyzed phthalonitrile monomer was prepared via nucleophilic displacement reaction. The structure was characterized by Fourier infrared spectrum (FT-IR) and nuclear magnetic resonance (¹H NMR). The polymerization mechanism was explored. Thermal properties were characterized by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA), which demonstrated self-promoted behavior and excellent heat resistance.

Key words:

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