Simultaneous determination of dihydroxybenzene isomers utilizing a thiadiazole film electrode

Chang-Zhi Zhao Jun-Yu Liang Xiao-Lei Gu Hui Liu

Citation:  Chang-Zhi Zhao, Jun-Yu Liang, Xiao-Lei Gu, Hui Liu. Simultaneous determination of dihydroxybenzene isomers utilizing a thiadiazole film electrode[J]. Chinese Chemical Letters, 2014, 25(2): 370-374. shu

Simultaneous determination of dihydroxybenzene isomers utilizing a thiadiazole film electrode

    通讯作者: Chang-Zhi Zhao,
摘要: The present study reports a sensitive electro-analytical method for the simultaneous determination of dihydroxybenzene isomers by using a thiadiazole film electrode, which was readily prepared by electropolymerization of 2,5-dimercapto-1,3,4-thiadiazole on a glassy carbon electrode with cyclic voltammetry. The functionalized electrode has a distinguishable and sensitive response to dihydroxybenzene isomers. Under the optimized conditions, the linear stripping peak currents showed good linear relationships with hydroquinone, catechol and resorcinol at concentration ranges 0.50-120, 0.50-110 and 1.00-110 μmol/L, and the detection limits are 0.1, 0.1 and 0.3 μmol/L, respectively. The proposed method is applicable to the simultaneous determination of dihydroxybenzene isomers in real samples with the relative standard deviations of less than 5.7% and the recovery rates of 95.6%-106%. The constructed electrode is characterized by simple preparation, good selectivity, and high sensitivity advantages.

English

  • 
    1. [1] K.J. Huang, S. Yu, L. Wang, T. Gan, M. Li, Simultaneous determination of hydroquinone, catechol and resorcinol based on graphene/cobalt hexacyanoferrate modified glassy carbon, electrode, Acta Chim. Sinica 70 (2012) 735-740.[1] K.J. Huang, S. Yu, L. Wang, T. Gan, M. Li, Simultaneous determination of hydroquinone, catechol and resorcinol based on graphene/cobalt hexacyanoferrate modified glassy carbon, electrode, Acta Chim. Sinica 70 (2012) 735-740.

    2. [2] X. Zhang, S. Duan, X. Xu, S. Xu, C. Zhou, Electrochemical behavior and simultaneous determination of dihydroxybenzene isomers at a functionalized SBA-15 mesoporous silica modified carbon paste electrode, Electrochim. Acta 56 (2011) 1981-1987.[2] X. Zhang, S. Duan, X. Xu, S. Xu, C. Zhou, Electrochemical behavior and simultaneous determination of dihydroxybenzene isomers at a functionalized SBA-15 mesoporous silica modified carbon paste electrode, Electrochim. Acta 56 (2011) 1981-1987.

    3. [3] H.S. Yin, Q.M. Zhang, Y.L. Zhou, et al., Electrochemical behavior of catechol, resorcinol and hydroquinone at graphene-chitosan composite film modified glassy carbon electrode and their simultaneous determination in water samples, Electrochim. Acta 56 (2011) 2748-2753.[3] H.S. Yin, Q.M. Zhang, Y.L. Zhou, et al., Electrochemical behavior of catechol, resorcinol and hydroquinone at graphene-chitosan composite film modified glassy carbon electrode and their simultaneous determination in water samples, Electrochim. Acta 56 (2011) 2748-2753.

    4. [4] D.W. Li, Y.T. Li, W. Song, Y.T. Long, Simultaneous determination of dihydroxybenzene isomers using disposable screen-printed electrode modified by multiwalled carbon nanotubes and gold nanoparticles, Anal. Methods 2 (2010) 837-843.[4] D.W. Li, Y.T. Li, W. Song, Y.T. Long, Simultaneous determination of dihydroxybenzene isomers using disposable screen-printed electrode modified by multiwalled carbon nanotubes and gold nanoparticles, Anal. Methods 2 (2010) 837-843.

    5. [5] D.D. Zhang, Y.G. Peng, H.L. Qi, Q. Gao, C.X. Zhang, Application of multielectrode array modified with carbon nanotubes to simultaneous amperometric determination of dihydroxybenzene isomers, Sens. Actuators B 136 (2009) 113-121.[5] D.D. Zhang, Y.G. Peng, H.L. Qi, Q. Gao, C.X. Zhang, Application of multielectrode array modified with carbon nanotubes to simultaneous amperometric determination of dihydroxybenzene isomers, Sens. Actuators B 136 (2009) 113-121.

    6. [6] L. Han, X.L. Zhang, Simultaneous voltammetry determination of dihydroxybenzene isomers by nanogold modified electrode, Electroanalysis 21 (2009) 124-129.[6] L. Han, X.L. Zhang, Simultaneous voltammetry determination of dihydroxybenzene isomers by nanogold modified electrode, Electroanalysis 21 (2009) 124-129.

    7. [7] J.P. Dong, X.M. Qu, L.J. Wang, C.J. Zhao, J.Q. Xu, Electrochemistry of nitrogen-doped carbon nanotubes (CNx) with different nitrogen content and its application in simultaneous determination of dihydroxybenzene isomers, Electroanalysis 20 (2008) 1981-1986.[7] J.P. Dong, X.M. Qu, L.J. Wang, C.J. Zhao, J.Q. Xu, Electrochemistry of nitrogen-doped carbon nanotubes (CNx) with different nitrogen content and its application in simultaneous determination of dihydroxybenzene isomers, Electroanalysis 20 (2008) 1981-1986.

    8. [8] P.H. Yang,W.Z. Wei, C.Y. Tao, J.X. Zeng, Simultaneous voltammetry determination of dihydroxybenzene isomers by poly-bromophenol blue/carbon nanotubes composite modified electrode, Bull. Environ. Contam. Toxicol. 79 (2007) 5-10.[8] P.H. Yang,W.Z. Wei, C.Y. Tao, J.X. Zeng, Simultaneous voltammetry determination of dihydroxybenzene isomers by poly-bromophenol blue/carbon nanotubes composite modified electrode, Bull. Environ. Contam. Toxicol. 79 (2007) 5-10.

    9. [9] P.H. Yang, W.Z. Wei, L. Yang, Simultaneous voltammetric determination of dihydroxybenzene isomers using a poly(acid chrome blue K) carbon nanotube composite electrode, Microchim. Acta 157 (2007) 229-235.[9] P.H. Yang, W.Z. Wei, L. Yang, Simultaneous voltammetric determination of dihydroxybenzene isomers using a poly(acid chrome blue K) carbon nanotube composite electrode, Microchim. Acta 157 (2007) 229-235.

    10. [10] S. Cosnier, M. Holzinger, Electrosynthesized polymers for biosensing, Chem. Soc. Rev. 40 (2011) 2146-2156.[10] S. Cosnier, M. Holzinger, Electrosynthesized polymers for biosensing, Chem. Soc. Rev. 40 (2011) 2146-2156.

    11. [11] P. Kalimuthu, S.A. John, Electropolymerized film of functionalized thiadiazole on glassy carbon electrode for the simultaneous determination of ascorbic acid, dopamine and uric acid, Bioelectrochemistry 77 (2009) 13-18.[11] P. Kalimuthu, S.A. John, Electropolymerized film of functionalized thiadiazole on glassy carbon electrode for the simultaneous determination of ascorbic acid, dopamine and uric acid, Bioelectrochemistry 77 (2009) 13-18.

    12. [12] C.Z. Zhao, H. Liu, L. Wang, Simultaneous determination of Pb(Ⅱ) and Cd(Ⅱ) using an electrode modified with electropolymerized thiadiazole film, Anal. Methods 4 (2012) 3586-3592.[12] C.Z. Zhao, H. Liu, L. Wang, Simultaneous determination of Pb(Ⅱ) and Cd(Ⅱ) using an electrode modified with electropolymerized thiadiazole film, Anal. Methods 4 (2012) 3586-3592.

    13. [13] T. Tatsuma, Y. Yokoyama, D.A. Buttry, N. Oyama, Electrochemical polymerization and depolymerization of 2,5-dimercapto-1,3,4-thiadiazole. QCM and spectroscopic analysis, J. Phys. Chem. B 101 (1997) 7556-7562.[13] T. Tatsuma, Y. Yokoyama, D.A. Buttry, N. Oyama, Electrochemical polymerization and depolymerization of 2,5-dimercapto-1,3,4-thiadiazole. QCM and spectroscopic analysis, J. Phys. Chem. B 101 (1997) 7556-7562.

    14. [14] D.T. Harvey, Modern Analytical Chemistry, McGraw-Hill, New York, 2000, p. 151.[14] D.T. Harvey, Modern Analytical Chemistry, McGraw-Hill, New York, 2000, p. 151.

  • 加载中
计量
  • PDF下载量:  0
  • 文章访问数:  1373
  • HTML全文浏览量:  30
文章相关
  • 收稿日期:  2013-08-28
  • 网络出版日期:  2013-10-25
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章