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A ladder conjugated polymer transducer for solid-contact Cu2+-selective electrodes

Shun-Yang Yu ,  Yan-Cang Li ,  Tao Xiong ,  Qun Yuan ,  Yong-Ming Liu ,  Zhong-Yi Yuan ,  Yi Xiao

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Citation:  Shun-Yang Yu, Yan-Cang Li, Tao Xiong, Qun Yuan, Yong-Ming Liu, Zhong-Yi Yuan, Yi Xiao. A ladder conjugated polymer transducer for solid-contact Cu2+-selective electrodes[J]. Chinese Chemical Letters, 2014, 25(2): 364-366. shu

A ladder conjugated polymer transducer for solid-contact Cu2+-selective electrodes

    • 通讯作者: Shun-Yang Yu,
    Tao Xiong,
  • 基金项目:

    This work was financially supported by the National Natural Science Foundation of China (No. 21107134) (No. 21107134)

    Chinese Academy of Sciences (No. KZCX2-YW-JS208) (No. KZCX2-YW-JS208)

    ong Province (No. JQ200814)  (No. JQ200814)

摘要: In recent years, there has been a pronounced interest in solid-contact ion-selective electrodes (SC-ISEs), with emphasis on the use of conducting polymers as ion-to-electron transducer. In this work, a ladder conjugated polymer, thieno[3,2-b]thiophene (LCPT), was investigated in fabricating Cu2+-selective electrodes for the first time. The resulting electrodes were characterized by electrochemical impedance spectroscopy (EIS), chronopotentiometry, and the water layer test. Results proved that the active LCPT facilitates the ion-to-electron transduction, and avoids the detrimental aqueous layer formed at the interface of SC-ISEs.

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  • 收稿日期:  2013-07-19
  • 网络出版日期:  2013-10-14
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