注册 English

盐酸和磺基水杨酸复合掺杂聚苯胺的热电性能

卢艳 ,  宋英 ,  孙秋 ,  王福平

downloadPDF
引用本文: 卢艳, 宋英, 孙秋, 王福平. 盐酸和磺基水杨酸复合掺杂聚苯胺的热电性能[J]. 无机化学学报, 2013, 29(9): 1887-1892. doi: 10.3969/j.issn.1001-4861.2013.00.276 shu
Citation:  LU Yan, SONG Ying, SUN Qiu, WANG Fu-Ping. Thermoelectric Properties of Conducting Polyaniline Co-Doped with Hydrochloric Acid and Sulfosalicylic Acid[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(9): 1887-1892. doi: 10.3969/j.issn.1001-4861.2013.00.276 shu

盐酸和磺基水杨酸复合掺杂聚苯胺的热电性能

  • 基金项目:

    国家自然科学基金(No.50772026)资助项目。 (No.50772026)

摘要: 以苯胺为单体,过硫酸铵为氧化剂,采用化学氧化聚合法在盐酸和磺基水杨酸混合溶液中制备了导电聚苯胺。通过XRD、SEM、FTIR等分析手段,对所得产物的结构进行研究,并探讨在相同聚合条件下,不同的磺基水杨酸和盐酸的物质的量浓度比(cSSA:cHCl)对聚苯胺热电性能的影响。结果显示,混合酸掺杂聚苯胺的电导率随cSSA:cHCl的增加而增大,但Seebeck系数的变化趋势却与之相反。当cSSA:cHCl=0.25:1时,掺杂态聚苯胺的功率因子在175℃时达到最大值为0.46 μW·m-1·K-2,分别是相同条件下HCl和SSA掺杂聚苯胺的1.7和1.9倍。这表明适当配比的有机酸与无机酸混合掺杂比单一酸掺杂更有利于聚苯胺热电性能的提高。

English

  • 

    1. [1] Du Y, Shen S Z, Cai K F, et al. Prog. Polym. Sci., 2012,37: 820-841[1] Du Y, Shen S Z, Cai K F, et al. Prog. Polym. Sci., 2012,37: 820-841

    2. [2] Dubey N, Leclerc M. J. Polym. Sci. Pol. Phys., 2011,49:467-475[2] Dubey N, Leclerc M. J. Polym. Sci. Pol. Phys., 2011,49:467-475

    3. [3] LIU Jun(刘军), ZHANG Lian-Meng(张联盟), HE Li(何莉), et al. J. Wuhan Univ. Technol.(Wuhan Ligongdaxue Xuebao), 2003,18:53-55[3] LIU Jun(刘军), ZHANG Lian-Meng(张联盟), HE Li(何莉), et al. J. Wuhan Univ. Technol.(Wuhan Ligongdaxue Xuebao), 2003,18:53-55

    4. [4] Yoon C O, Kim J H, Sung H K, et al. Synth. Metal, 1996,81: 75-80[4] Yoon C O, Kim J H, Sung H K, et al. Synth. Metal, 1996,81: 75-80

    5. [5] Yan H, Ohta T, Toshima N. Macromol. Mater. Eng., 2001, 286:139-142[5] Yan H, Ohta T, Toshima N. Macromol. Mater. Eng., 2001, 286:139-142

    6. [6] Yan H, Toshima N. Chem. Lett., 1999,28:1217-1218[6] Yan H, Toshima N. Chem. Lett., 1999,28:1217-1218

    7. [7] Toshima N. Macromol. Symp., 2002,186:81-86[7] Toshima N. Macromol. Symp., 2002,186:81-86

    8. [8] Sun Y N, Wei Z M, Xu W, et al. Synth. Metal, 2010,160: 2371-2376[8] Sun Y N, Wei Z M, Xu W, et al. Synth. Metal, 2010,160: 2371-2376

    9. [9] Yao Q, Chen L, Xu X, et al. Chem. Lett., 2005,34:522-523[9] Yao Q, Chen L, Xu X, et al. Chem. Lett., 2005,34:522-523

    10. [10] Yan H, Sada N, Toshima N. J. Therm. Anal. Calorim., 2002, 69:881-887[10] Yan H, Sada N, Toshima N. J. Therm. Anal. Calorim., 2002, 69:881-887

    11. [11] Yoon C, Reghu M, Moses D, et al. Synth. Metal, 1995,69: 273-274[11] Yoon C, Reghu M, Moses D, et al. Synth. Metal, 1995,69: 273-274

    12. [12] Yakuphanoglu F, Senkal B F, Sarac A. J. Electron. Mater., 2008,37:930-934[12] Yakuphanoglu F, Senkal B F, Sarac A. J. Electron. Mater., 2008,37:930-934

    13. [13] Li J, Tang X, Li H, et al. Synth. Metal, 2010,160:1153-1158[13] Li J, Tang X, Li H, et al. Synth. Metal, 2010,160:1153-1158

    14. [14] Joo J, Long S M, Pouget J P, et al. Phys. Rev. B, 1998,57: 9567-9580[14] Joo J, Long S M, Pouget J P, et al. Phys. Rev. B, 1998,57: 9567-9580

    15. [15] WANG Feng-Chun(王凤春), LÜ Ying(吕莹), XU Min(徐敏) et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2009, 25(3):465-468[15] WANG Feng-Chun(王凤春), LÜ Ying(吕莹), XU Min(徐敏) et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2009, 25(3):465-468

    16. [16] Kang E T, Neoh K G, Tan K L. Prog. Polym. Sci., 1998,23: 277-324[16] Kang E T, Neoh K G, Tan K L. Prog. Polym. Sci., 1998,23: 277-324

    17. [17] ZHU Dao-Ben(朱道本), WAMG Fo-Song(王佛松). Organic Solids(有机固体). Shanghai: Shanghai Science and Technology Press, 1999.[17] ZHU Dao-Ben(朱道本), WAMG Fo-Song(王佛松). Organic Solids(有机固体). Shanghai: Shanghai Science and Technology Press, 1999.

    18. [18] HUANG Hui(黄惠), XU Jin-Quan(许金泉), LIU Xiao-Li (刘小丽) et al. Chemistry (Huaxue Tongbao). 2009,8:744-748[18] HUANG Hui(黄惠), XU Jin-Quan(许金泉), LIU Xiao-Li (刘小丽) et al. Chemistry (Huaxue Tongbao). 2009,8:744-748

    19. [19] HUANG Hui(黄惠), GUO Zhong-Cheng(郭忠诚). Preparation and Application of Conductive Polyaniline(导电 聚苯胺的制备及应用). Beijing: Science Press, 2010.[19] HUANG Hui(黄惠), GUO Zhong-Cheng(郭忠诚). Preparation and Application of Conductive Polyaniline(导电 聚苯胺的制备及应用). Beijing: Science Press, 2010.

    20. [20] Jin J Z, Wang Q, Haque M A. Org. Electrn., 2010,11:29-35[20] Jin J Z, Wang Q, Haque M A. Org. Electrn., 2010,11:29-35

    21. [21] LI Jun-Jie(李珺杰), TANG Xin-Feng(唐新峰). J. Mater. Sci. & Eng. (Cailiao Kexue Yu Gongcheng Xuebao), 2010,28: 263-266[21] LI Jun-Jie(李珺杰), TANG Xin-Feng(唐新峰). J. Mater. Sci. & Eng. (Cailiao Kexue Yu Gongcheng Xuebao), 2010,28: 263-266

  • 加载中
WeChat 扫一扫看文章
计量
  • PDF下载量:  0
  • 文章访问数:  637
  • HTML全文浏览量:  40
文章相关
  • 收稿日期:  2012-12-20
  • 网络出版日期:  2013-05-02
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章

All Rights Reserved by the Chinese Chemical Society   中国化学会 版权所有 京ICP备05002797号

本系统由北京仁和汇智信息技术有限公司开发    技术支持: info@rhhz.net