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氨基化多壁碳纳米管的制备与表征

郭冰之 ,  赵芸 ,  黎汉生 ,  矫庆泽

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引用本文: 郭冰之, 赵芸, 黎汉生, 矫庆泽. 氨基化多壁碳纳米管的制备与表征[J]. 无机化学学报, 2013, 29(9): 1825-1829. doi: 10.3969/j.issn.1001-4861.2013.00.194 shu
Citation:  GUO Bing-Zhi, ZHAO Yun, LI Han-Sheng, JIAO Qing-Ze. Preparation and Characterization of Amino-functionalized Multi-walled Carbon Nanotubes[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(9): 1825-1829. doi: 10.3969/j.issn.1001-4861.2013.00.194 shu

氨基化多壁碳纳米管的制备与表征

  • 基金项目:

    国家自然科学基金(No.21071017)资助项目。 (No.21071017)

摘要: 以多壁碳纳米管(MWNTs)为原料,经自由基反应,制备了氰基改性的多壁碳纳米管,然后采用Al-NiCl2·6H2O-THF体系还原氰基得到了氨基化的碳纳米管。通过拉曼光谱仪、热重分析仪、X射线光电子能谱仪和透射电子显微镜对产物的结构与形貌进行了表征。结果表明:氨基通过共价键枝接在MWNTs的表面,氨基化多壁碳纳米管每1000个表面碳原子中有17.1个转化为氨基;该反应条件温和,反应时间短,且不破坏MWNTs的结构。

English

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  • 收稿日期:  2012-01-06
  • 网络出版日期:  2013-03-12
通讯作者: 陈斌, bchen63@163.com
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