新型含三氟甲基八羟基喹啉锌配合物的合成及紫外、荧光性质研究

引用本文: 聂晓李, 霍延平, 陆天华, 胡升, 易国斌, 袁国赞. 新型含三氟甲基八羟基喹啉锌配合物的合成及紫外、荧光性质研究[J]. 无机化学学报, 2013, 29(9): 1805-1812. doi: 10.3969/j.issn.1001-4861.2013.00.254 shu

Citation: NIE Xiao-Li, HUO Yan-Ping, LU Tian-Hua, HU Sheng, YI Guo-Bin, YUAN Guo-Zan. Synthesis and Photophysics of Novel Zn Metal Complex Based on 2-Substituted-8-hydroxyquinoline with Trifluoromethylbenzene Group[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(9): 1805-1812. doi: 10.3969/j.issn.1001-4861.2013.00.254 shu

新型含三氟甲基八羟基喹啉锌配合物的合成及紫外、荧光性质研究

基金项目:
国家自然科学基金(Nos.21172047, 21001030, 51273048)资助项目。 (Nos.21172047, 21001030, 51273048)

摘要: 设计合成了含三氟甲基8-羟基喹啉衍生物配体(E)-2-[2-(2-三氟甲基苯基)乙烯基]-8-羟基喹啉(4)及其相应的锌配合物5,产物经¹H NMR,IR,MS和元素分析进行了结构表征。利用X射线单晶衍射仪测定了配体L(4)的单晶结构,发现其具有独特的螺旋形结构。通过核磁滴定以及紫外和荧光滴定模拟了配体L(4)在溶液中与金属锌的配位过程,荧光光谱显示在甲醇溶液中配体的λ_max=474 nm(蓝色),配合物的λ_max=601 nm(橙黄色)。同时测定了配体和配合物的固体荧光寿命,两者的荧光寿命分别为15.6 ms和18.1 ms。

关键词:

8-羟基喹啉;三氟甲基;锌配合物;荧光光谱;荧光寿命

English

Synthesis and Photophysics of Novel Zn Metal Complex Based on 2-Substituted-8-hydroxyquinoline with Trifluoromethylbenzene Group

1.
1 School of Light Idustry and Chemical Engineering, Guangdong University of Technology, Guangzhou 510006, China;
Received Date: 20 November 2012
Fund Project:
国家自然科学基金(Nos.21172047, 21001030, 51273048)资助项目。

Abstract: A novel 8-hydroxyquinoline derivative ligand containing trifluoromethylbenzene Group: (E)-2-[2-(2-trifluromethylphenyl)vinyl]-8-hydroxyquinoline(4) and its zinc complex(5) have been synthesized and identified by ¹H NMR, FFIR, MS techniques and elemental analyses. The crystal structure of ligand 4 was determined by X-ray single crystal diffraction, and its network structure is special spiral. The aggregation behavior of Zn(AcO)₂·2H₂O and the ligand 4 in solvents was investigated by UV-Vis, fluorescence spectrum and ¹H NMR spectra titration. Fluorescence emission results showed that the λ_max of ligand 4 and complex 5 were 474 nm and 601 nm, respectively. The fluorescence lifetime of ligand 4 and complex 5 were investigated in the solid state, their values are 15.6 ms and 18.1 ms, respectively. CCDC: 910120.

Key words:

8-hydroxyquinoline;trifluoromethylbenzene;zinc complex;fluorescence;fluorescence lifetime

1. [1] ZHANG Pei-Quan(张培全), ZENG He-Ping(曾和平). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2008,24(1): 124-129[1] ZHANG Pei-Quan(张培全), ZENG He-Ping(曾和平). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2008,24(1): 124-129
2. [2] Tang C W, VanSlyke S A. Appl. Phys. Lett., 1987,51:913-916[2] Tang C W, VanSlyke S A. Appl. Phys. Lett., 1987,51:913-916
3. [3] Matsumoto N, Miyazaki T, Nishiyama M, et al. J. Phys. Chem. C., 2009,113:6261-6265[3] Matsumoto N, Miyazaki T, Nishiyama M, et al. J. Phys. Chem. C., 2009,113:6261-6265
4. [4] WEI Fang-Fang(卫芳芳), WANG Hua(王华), XU Yang (徐阳), et al. J. Synth. Cryst.(Rengong Jingti Xuebao), 2009,38(3):757-760[4] WEI Fang-Fang(卫芳芳), WANG Hua(王华), XU Yang (徐阳), et al. J. Synth. Cryst.(Rengong Jingti Xuebao), 2009,38(3):757-760
5. [5] Gather M C, Alle R, Becker H, et al. Adv. Mater., 2007,19: 4460-4465[5] Gather M C, Alle R, Becker H, et al. Adv. Mater., 2007,19: 4460-4465
6. [6] Sharma A, Singh D, Makrandi J K, et al. Mater. Lett., 2007,61:4614-4617[6] Sharma A, Singh D, Makrandi J K, et al. Mater. Lett., 2007,61:4614-4617
7. [7] Deng J Y, Guo L H, Xiu Q, et al. Mater. Chem. Phys., 2012,133:452-458[7] Deng J Y, Guo L H, Xiu Q, et al. Mater. Chem. Phys., 2012,133:452-458
8. [8] Li S J, Li Y, Zhang J A. Inorg. Chem. Commun., 2012(20): 334-339[8] Li S J, Li Y, Zhang J A. Inorg. Chem. Commun., 2012(20): 334-339
9. [9] Kwong C Y, Djurisic A B, Choy W C H, et al. Mater. Sci. Eng. B., 2005,116:75-81[9] Kwong C Y, Djurisic A B, Choy W C H, et al. Mater. Sci. Eng. B., 2005,116:75-81
10. [10] Pohl R, Anzenbacher P. Org. Lett., 2003,5(16):2769-2772[10] Pohl R, Anzenbacher P. Org. Lett., 2003,5(16):2769-2772
11. [11] LOU Shuang-Ling(娄双玲), YU Jun-Sheng(于军胜), JIANG Ya-Dong(蒋亚东), et al. Chin. Sci. Bull. (Kexue Tongbao), 2008,53(13):1523-1527[11] LOU Shuang-Ling(娄双玲), YU Jun-Sheng(于军胜), JIANG Ya-Dong(蒋亚东), et al. Chin. Sci. Bull. (Kexue Tongbao), 2008,53(13):1523-1527
12. [12] Huo Y P, Zhu S Z, Hu S. Tetrahedron., 2010,66:8635-8640[12] Huo Y P, Zhu S Z, Hu S. Tetrahedron., 2010,66:8635-8640
13. [13] WANG Hua(王华). Thesis for the Doctorate of Taiyuan University of Technology(太原理工大学博士论文). 2007.[13] WANG Hua(王华). Thesis for the Doctorate of Taiyuan University of Technology(太原理工大学博士论文). 2007.
14. [14] Xiang Y C, Dong H X, Chong C, et al. J. Colloid Interface Sci., 2013,393:241-248[14] Xiang Y C, Dong H X, Chong C, et al. J. Colloid Interface Sci., 2013,393:241-248
15. [15] Gao B J, Wei X P, Zhang Y Y. Opt. Mater., 2013,35:536-542[15] Gao B J, Wei X P, Zhang Y Y. Opt. Mater., 2013,35:536-542
16. [16] Yuan G Z, Huo Y P, Nie X L, et al. Tetrahedron., 2012,68: 8018-8023[16] Yuan G Z, Huo Y P, Nie X L, et al. Tetrahedron., 2012,68: 8018-8023
17. [17] LIU Lei(刘磊), ZHANG Ping(张萍), LI Yuan(李媛), et al. Chin. J. Struct. Chem.(Jiegou Huaxue), 2002,5(21):545-548[17] LIU Lei(刘磊), ZHANG Ping(张萍), LI Yuan(李媛), et al. Chin. J. Struct. Chem.(Jiegou Huaxue), 2002,5(21):545-548
18. [18] Xie X, Jiang X J, Liu J, et al. Inorg. Chim. Acta, 2012,383: 132-136[18] Xie X, Jiang X J, Liu J, et al. Inorg. Chim. Acta, 2012,383: 132-136
19. [19] Zeng H P, Wang G R, Zeng G C, et al. Dyes Pigments., 2009,83:155-159[19] Zeng H P, Wang G R, Zeng G C, et al. Dyes Pigments., 2009,83:155-159
20. [20] Ballardini R, Varani G, Indelli M T, et al. Inorg. Chem., 1986,25:3858-3865[20] Ballardini R, Varani G, Indelli M T, et al. Inorg. Chem., 1986,25:3858-3865
21. [21] Sapochak L S, Benincasa F E, Schofield R S, et al. J. Am. Chem. Soc., 2002,124:6119-6123[21] Sapochak L S, Benincasa F E, Schofield R S, et al. J. Am. Chem. Soc., 2002,124:6119-6123
22. [22] Yue C, Jiang F, Xu Y, et al. Cryst. Growth Des., 2008,8: 2721-2726[22] Yue C, Jiang F, Xu Y, et al. Cryst. Growth Des., 2008,8: 2721-2726

扫一扫看文章

计量

PDF下载量: 0
文章访问数: 772
HTML全文浏览量: 118

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

新型含三氟甲基八羟基喹啉锌配合物的合成及紫外、荧光性质研究

English

Synthesis and Photophysics of Novel Zn Metal Complex Based on 2-Substituted-8-hydroxyquinoline with Trifluoromethylbenzene Group

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

新型含三氟甲基八羟基喹啉锌配合物的合成及紫外、荧光性质研究

English

Synthesis and Photophysics of Novel Zn Metal Complex Based on 2-Substituted-8-hydroxyquinoline with Trifluoromethylbenzene Group

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs