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自组装铝/氧化铜和铝/氧化铁及其性能评估

王晓倩 ,  张琳 ,  朱顺官 ,  赵佳

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引用本文: 王晓倩, 张琳, 朱顺官, 赵佳. 自组装铝/氧化铜和铝/氧化铁及其性能评估[J]. 无机化学学报, 2013, 29(9): 1799-1804. doi: 10.3969/j.issn.1001-4861.2013.00.228 shu
Citation:  WANG Xiao-Qian, ZHANG Lin, ZHU Shun-Guan, ZHAO Jia. Preparation and Performance of Self-assembled Al/Fe2O3 and Al/CuO[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(9): 1799-1804. doi: 10.3969/j.issn.1001-4861.2013.00.228 shu

自组装铝/氧化铜和铝/氧化铁及其性能评估

  • 基金项目:

    国家自然科学基金(No.61106078) (No.61106078)

    南京理工大学自主科研重大研究计划(No.2011ZDJH28)资助项目。 (No.2011ZDJH28)

摘要: 本文分别采用模板法制备氧化铜纳米花,水热法制备氧化铁纳米环,并自组装制备了铝/氧化铜和铝/氧化铁2种铝热剂。自组装增大了异相材料之间的接触,分别使得铝/氧化铜的反应放热量和压力由523 J·g-1、1 858 kPa增加至1 069 J·g-1、 4 389 kPa;铝/氧化铁的反应放热量和压力由1 448 J·g-1、749 kPa增加至2 039 J·g-1、2 280 kPa。两种铝热剂的放热量和压力差别较大,且铝/氧化铜的静电感度高于大多数含能材料,铝/氧化铁的撞击感度特别低,显示出不同的应用特点。

English

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  • 收稿日期:  2013-01-11
  • 网络出版日期:  2013-03-17
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