纸基食品接触材料中4-肉桂苯酚和水杨酸对叔丁基苯酯向干性食品模拟物TenaxTA的迁移

引用本文: 韩伟, 于艳军, 李宁涛, 王利兵. 纸基食品接触材料中4-肉桂苯酚和水杨酸对叔丁基苯酯向干性食品模拟物TenaxTA的迁移[J]. 色谱, 2014, 32(12): 1349-1355. doi: 10.3724/SP.J.1123.2014.08031 shu

Citation: HAN Wei, YU Yanjun, LI Ningtao, WANG Libing. Kinetic migration of 4-cumylphenol and 4-tert-butylphenyl salicylate from paper packaging to dry food simulant Tenax TA[J]. Chinese Journal of Chromatography, 2014, 32(12): 1349-1355. doi: 10.3724/SP.J.1123.2014.08031 shu

纸基食品接触材料中4-肉桂苯酚和水杨酸对叔丁基苯酯向干性食品模拟物TenaxTA的迁移

韩伟 ^1, ,
于艳军 ^1, ,
李宁涛 ^1, ,
王利兵 ^{2,
,}

通讯作者: 王利兵,E-mail:whan@iccas.ac.cn.

基金项目:
国家质检总局科技计划项目(2013IK214) (2013IK214)

国家高技术研究发展计划项目(2012AA06A303) (2012AA06A303)

国家科技支撑计划项目(2012BAD29B05). (2012BAD29B05)

摘要: 以纸基食品接触材料中的4-肉桂苯酚(CP)和水杨酸对叔丁基苯酯(TBS)为模拟迁移物,对其向干性食品模拟物Tenax TA中的迁移规律采用超高效液相色谱结合荧光检测(UPLC-FLR)方法进行了研究。在不同温度下对CP和TBS的迁移动力学进行了考察,并对其在封闭环境和敞开环境下的迁移率进行对比研究。通过设计不同质量的Tenax TA接触直径为3.5 cm圆片样品的迁移试验,探索了迁移试验中合适的模拟物质量/接触材料面积比条件。系列试验结果表明,迁移物迁移时间越长,迁移温度越高,相应的迁移率就越高;在高的迁移温度下,迁移物在Tenax TA上的解吸会导致迁移率的下降;在封闭条件下CP和TBS的迁移率要高于敞开条件下的迁移率;迁移试验中,4.16 g/dm²的模拟物质量/接触材料面积比是利用干性食品模拟物进行食品接触材料暴露评估的合适的迁移试验条件。密闭条件下市售的8种食品接触材料干性食品模拟物迁移实验研究表明,TBS存在于用于包装坚果类食品的包装纸中,含量为15.54 mg/kg。

关键词:

English

Kinetic migration of 4-cumylphenol and 4-tert-butylphenyl salicylate from paper packaging to dry food simulant Tenax TA

HAN Wei ^1, ,
YU Yanjun ^1, ,
LI Ningtao ^1, ,
WANG Libing ^{2,
,}

1.
1. Technical Center for Safety of Industrial Products, Tianjin Entry-Exit Inspection & Quarantine Bureau, Tianjin 300308, China;

Corresponding author: 王利兵,E-mail:whan@iccas.ac.cn.

Received Date: 28 August 2014
Fund Project:
国家质检总局科技计划项目(2013IK214)

国家高技术研究发展计划项目(2012AA06A303)

国家科技支撑计划项目(2012BAD29B05).

Abstract: Migration investigations were carried out on paper food packaging in contact with dry food simulant Tenax TA. The aim was to explore the migration behaviours of 4-cumylphenol (CP) and 4-tert-butylphenyl salicylate (TBS) as potential contaminants, from paper materials to Tenax TA at different migration temperatures for variant migration times. A method based on ultrahigh performance liquid chromatography coupled with fluorescence detection (UPLC-FLR) was developed to determine CP and TBS migrated into the simulant. Two independent migration tests performed under open system and closed system were contrastively studied. At the same time, a series of migration tests by using different masses of Tenax TA to contact round paper samples with the diameter of 3.5 cm was conducted to explore the proper ratio between the mass of Tenax TA and the area of food packaging sample. Based on the analytical results, high temperature and long contact time had positive effect on the migration rate of the contaminants. However, persistent high migration temperature would lead to decrease the migration rate due to desorption of CP and TBS from Tenax TA. Migration rate in closed system was higher than that in open system. In the process of migration test, a ratio of 4.16 g/dm² was an appropriate experimental condition to conduct the migration test. All of the migration results revealed that the proper ratio of mass of Tenax TA to area of paper sample was the key to conduct the exposure assessment of food contact materials.

Key words:

ultrahigh performance liquid chromatography (UPLC)
/ fluorescence detection (FLR)
/ 4-cumylphenol (CP)
/ 4-tert-butylphenyl salicylate
/ food contact materials
/ dry food simulant
/ Tenax TA
/ migration

1. [1] Song Y S, Park H J, Komolprasert V. J Agric Food Chem, 2000, 48(12): 5856 [1] Song Y S, Park H J, Komolprasert V. J Agric Food Chem, 2000, 48(12): 5856
2. [2] Ozaki A, Yamaguchi Y, Fujita T, et al. Food Chem Toxicol, 2004, 42(8): 1323 [2] Ozaki A, Yamaguchi Y, Fujita T, et al. Food Chem Toxicol, 2004, 42(8): 1323
3. [3] Li Y, Li C F, Xiao D Q, et al. Chinese Journal of Chromatography (李英, 李成发, 肖道清, 等. 色谱), 2013, 31(1): 46[3] Li Y, Li C F, Xiao D Q, et al. Chinese Journal of Chromatography (李英, 李成发, 肖道清, 等. 色谱), 2013, 31(1): 46
4. [4] Bai W W, Liu S H, Cao J P, et al. Chinese Journal of Chromatography (白玮玮, 刘书慧, 曹江平, 等. 色谱), 2013, 31(3): 254 [4] Bai W W, Liu S H, Cao J P, et al. Chinese Journal of Chromatography (白玮玮, 刘书慧, 曹江平, 等. 色谱), 2013, 31(3): 254
5. [5] Commission Regulation (EU) No 10/2011 of 14 January 2011 on plastic materials and articles intended to come into contact with food. Official Journal of the European Union, 2011, 15.1: L12/1. [2014-08-28]. http://eur-lex.europa.eu/LexUriServ/LexUriServ.do?uri=CONSLEG:2011R0010:20111230:EN:PDF[5] Commission Regulation (EU) No 10/2011 of 14 January 2011 on plastic materials and articles intended to come into contact with food. Official Journal of the European Union, 2011, 15.1: L12/1. [2014-08-28]. http://eur-lex.europa.eu/LexUriServ/LexUriServ.do?uri=CONSLEG:2011R0010:20111230:EN:PDF
6. [6] Boccacci Mariani M, Chiacchierini E, Gesumundo C. Food Addit Contam, 1999, 16(5): 207 [6] Boccacci Mariani M, Chiacchierini E, Gesumundo C. Food Addit Contam, 1999, 16(5): 207
7. [7] Reinas I, Oliveira J, Pereira J, et al. Food Control, 2012, 28(2): 333 [7] Reinas I, Oliveira J, Pereira J, et al. Food Control, 2012, 28(2): 333
8. [8] Nerin C, Acosta D. J Agric Food Chem, 2002, 50(25): 7488 [8] Nerin C, Acosta D. J Agric Food Chem, 2002, 50(25): 7488
9. [9] López P, Batlle R, Salafranca J, et al. J Food Prot, 2008, 71(9): 1889[9] López P, Batlle R, Salafranca J, et al. J Food Prot, 2008, 71(9): 1889
10. [10] Zülch A, Piringer O. Food Addit Contam A, 2010, 27(9): 1306 [10] Zülch A, Piringer O. Food Addit Contam A, 2010, 27(9): 1306
11. [11] Wang J G, Li J X, Han F C. Speciality Petrochemicals (王建刚, 李健秀, 韩福成. 精细石油化工), 2003(5): 62[11] Wang J G, Li J X, Han F C. Speciality Petrochemicals (王建刚, 李健秀, 韩福成. 精细石油化工), 2003(5): 62
12. [12] Wang S Q, Gao C. Plastic Additives (王树清, 高崇. 塑料助剂), 2007, 46(4): 27[12] Wang S Q, Gao C. Plastic Additives (王树清, 高崇. 塑料助剂), 2007, 46(4): 27
13. [13] Asensio E. [PhD Dissertation]. Zaragoza: University of Zaragoza, 2002[13] Asensio E. [PhD Dissertation]. Zaragoza: University of Zaragoza, 2002
14. [14] Lin Q B, Wang T J, Song H, et al. Food Addit Contam A, 2011, 28(9): 1294 [14] Lin Q B, Wang T J, Song H, et al. Food Addit Contam A, 2011, 28(9): 1294
15. [15] Aurela B, Ohra-aho T, Söderhjelm L. Packag Technol Sci, 2001, 14(2): 71 [15] Aurela B, Ohra-aho T, Söderhjelm L. Packag Technol Sci, 2001, 14(2): 71
16. [16] Nerín C, Contín E, Asensio E. Anal Bioanal Chem, 2007, 387(6): 2283 [16] Nerín C, Contín E, Asensio E. Anal Bioanal Chem, 2007, 387(6): 2283
17. [17] Aurela B, Kulmala H, Söderhjelm L. Food Addit Contam, 1999, 16(12): 571 [17] Aurela B, Kulmala H, Söderhjelm L. Food Addit Contam, 1999, 16(12): 571
18. [18] Ozaki A, Ooshima T, Mori Y. Food Addit Contam, 2006, 23(8): 854 [18] Ozaki A, Ooshima T, Mori Y. Food Addit Contam, 2006, 23(8): 854
19. [19] GB/T 5009-2003[19] GB/T 5009-2003

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沈阳化工大学材料科学与工程学院沈阳 110142

纸基食品接触材料中4-肉桂苯酚和水杨酸对叔丁基苯酯向干性食品模拟物TenaxTA的迁移

通讯作者: 王利兵,E-mail:whan@iccas.ac.cn.

English

Kinetic migration of 4-cumylphenol and 4-tert-butylphenyl salicylate from paper packaging to dry food simulant Tenax TA

Corresponding author: 王利兵,E-mail:whan@iccas.ac.cn.

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

纸基食品接触材料中4-肉桂苯酚和水杨酸对叔丁基苯酯向干性食品模拟物TenaxTA的迁移

通讯作者: 王利兵,E-mail:whan@iccas.ac.cn.

English

Kinetic migration of 4-cumylphenol and 4-tert-butylphenyl salicylate from paper packaging to dry food simulant Tenax TA

Corresponding author: 王利兵,E-mail:whan@iccas.ac.cn.

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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