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Synthesis and structural studies of copper(II) complex supported by -ONNO- tetradentate ligand: Efficient catalyst for the ring-opening polymerization of lactide

Anita Routaray ,  Nibedita Nath ,  Somanath Mantri ,  Tungabidya Maharana ,  Alekha Kumar Sutar

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引用本文: Anita Routaray, Nibedita Nath, Somanath Mantri, Tungabidya Maharana, Alekha Kumar Sutar. Synthesis and structural studies of copper(II) complex supported by -ONNO- tetradentate ligand: Efficient catalyst for the ring-opening polymerization of lactide[J]. 催化学报, 2015, 36(5): 764-770. doi: 10.1016/S1872-2067(14)60293-X shu
Citation:  Anita Routaray, Nibedita Nath, Somanath Mantri, Tungabidya Maharana, Alekha Kumar Sutar. Synthesis and structural studies of copper(II) complex supported by -ONNO- tetradentate ligand: Efficient catalyst for the ring-opening polymerization of lactide[J]. Chinese Journal of Catalysis, 2015, 36(5): 764-770. doi: 10.1016/S1872-2067(14)60293-X shu

Synthesis and structural studies of copper(II) complex supported by -ONNO- tetradentate ligand: Efficient catalyst for the ring-opening polymerization of lactide

    通讯作者: Tungabidya Maharana, Alekha Kumar Sutar; Tungabidya Maharana, Alekha Kumar Sutar
摘要: The -ONNO- tetradentate Schiff base ligand N,N'-bis(2-hydroxy-3-methoxybenzaldehyde)benzene-1,2-diamine (HMBBD) has been synthesized. The ligand was attached to copper (Cu-HMBBD) in methanol under N2 atmosphere to give a mononuclear complex. The reactivity of this complex in the ring-opening polymerization (ROP) of lactide has been studied. The complex has a square planner geometry, as determined by X-ray diffraction studies. The copper complex is highly active towards the ring-opening polymerization of lactide, and the rate of polymerization is heavily dependent on the initiator used. The copper complex allows controlled ring-opening polymerization, as shown by the linear relationship between the percentage conversion and the number average molecular weight. Based on the literature, a mechanism for the ROP of lactide has been proposed.

English

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  • 发布日期:  2015-05-20
  • 收稿日期:  2014-12-12
  • 网络出版日期:  2015-01-12
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