静电自组装方法合成的具有多孔三维网络结构的Fe<sub>3</sub>O<sub>4</sub>/石墨烯复合材料作为高性能锂离子电池负极材料

引用本文: 刘建华, 刘宾虹, 李洲鹏. 静电自组装方法合成的具有多孔三维网络结构的Fe₃O₄/石墨烯复合材料作为高性能锂离子电池负极材料[J]. 物理化学学报, 2014, 30(9): 1650-1658. doi: 10.3866/PKU.WHXB201406181 shu

Citation: LIU Jian-Hua, LIU Bin-Hong, LI Zhou-Peng. Fe₃O₄/Graphene Composites with a Porous 3D Network Structure Synthesized through Self-Assembly under Electrostatic Interactions as Anode Materials of High-Performance Li-Ion Batteries[J]. Acta Physico-Chimica Sinica, 2014, 30(9): 1650-1658. doi: 10.3866/PKU.WHXB201406181 shu

静电自组装方法合成的具有多孔三维网络结构的Fe₃O₄/石墨烯复合材料作为高性能锂离子电池负极材料

基金项目:
国家自然科学基金（51271164，21276229)

浙江省自然科学基金（Z4110126)

浙江省重点科技创新团队（2010R50013）资助项目

摘要:

采用静电自组装方法，分两步合成Fe（OH）₃/ 前驱体（：氧化石墨烯），再通过水热反应和600 ℃高纯氮气气氛下煅烧，获得了Fe₃O₄/石墨烯复合材料. 通过X射线衍射（XRD）、扫描电镜（SEM）、高分辨透射电镜（HRTEM）、拉曼（Raman）光谱等多种分析，发现该复合材料具有三维多孔石墨烯网络结构. 把合成的这种Fe₃O₄/石墨烯复合材料作为锂离子电池负极材料，电化学测试结果表明其具有优良的电化学性能：首次放电容量为1390 mAh·g^-1，50次循环后容量为819 mAh·g^-1. 通过对比实验表明，三维石墨烯网络结构的形成对复合材料的电化学循环稳定性起着关键作用.

关键词:

English

Fe₃O₄/Graphene Composites with a Porous 3D Network Structure Synthesized through Self-Assembly under Electrostatic Interactions as Anode Materials of High-Performance Li-Ion Batteries

1.
1. Depatment of Materials Science & Engineering, Zhejiang University, Hangzhou 310027, P. R. China;
2. Department of Chemical & Biological Engineering, Zhejiang University, Hangzhou 310027, P. R. China
Received Date: 27 March 2014
Available Online: 29 August 2014
Fund Project:
国家自然科学基金（51271164，21276229)

浙江省自然科学基金（Z4110126)

浙江省重点科技创新团队（2010R50013）资助项目

Abstract:

Fe₃O₄/graphene composites with a conductive, porous three-dimensional (3D) graphene network were synthesized through a facile method. In the preparation process, Fe(OH)₃ colloid was formed in situ by adding FeCl₃ solution to a boiling graphene oxide ( ) suspension, with Fe(OH)₃/ precipitated because of the electrostatic interaction between the two components. The precipitate was separated and added to a second suspension to achieve additional encapsulation. This self-assembled Fe(OH)₃/ precursor was then hydrothermally and heat treated, resulting in the formation of Fe₃O₄/graphene composites. X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), and Raman spectroscopy results revealed that the Fe₃O₄/graphene composites possess a favorable 3D porous graphene network embedding 50- to 100-nm-sized Fe₃O₄ nanoparticles. The Fe₃O₄/graphene composites exhibit od electrochemical performance as an anode material for Li-ion batteries. The electrode composed of the Fe₃O₄/graphene composite delivered a capacity of 1390 mAh·g^-1 for the first lithiation and retained a capacity of 819 mAh·g^-1 after 50 cycles. The electrodes also exhibited od rate capability. The present results demonstrate that the electrochemical performance of the Fe₃O₄/graphene composite is highly sensitive to its preparation procedure and to the resulting nanostructure. Each of the four preparation procedures was experimentally shown to be important for achieving the final nanostructure and od electrochemical performance. A formation mechanism for the Fe₃O₄/graphene composite is also proposed.

Key words:

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

静电自组装方法合成的具有多孔三维网络结构的Fe₃O₄/石墨烯复合材料作为高性能锂离子电池负极材料

English

Fe₃O₄/Graphene Composites with a Porous 3D Network Structure Synthesized through Self-Assembly under Electrostatic Interactions as Anode Materials of High-Performance Li-Ion Batteries

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

静电自组装方法合成的具有多孔三维网络结构的Fe3O4/石墨烯复合材料作为高性能锂离子电池负极材料

English

Fe3O4/Graphene Composites with a Porous 3D Network Structure Synthesized through Self-Assembly under Electrostatic Interactions as Anode Materials of High-Performance Li-Ion Batteries

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

静电自组装方法合成的具有多孔三维网络结构的Fe₃O₄/石墨烯复合材料作为高性能锂离子电池负极材料

Fe₃O₄/Graphene Composites with a Porous 3D Network Structure Synthesized through Self-Assembly under Electrostatic Interactions as Anode Materials of High-Performance Li-Ion Batteries

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs