功能化石墨烯/聚苯胺复合电极材料的制备和电化学性能

引用本文: 汪丽丽, 邢瑞光, 张邦文, 侯渊. 功能化石墨烯/聚苯胺复合电极材料的制备和电化学性能[J]. 物理化学学报, 2014, 30(9): 1659-1666. doi: 10.3866/PKU.WHXB201406162 shu

Citation: WANG Li-Li, XING Rui-Guang, ZHANG Bang-Wen, HOU Yuan. Preparation and Electrochemical Properties of Functionalized Graphene/Polyaniline Composite Electrode Materials[J]. Acta Physico-Chimica Sinica, 2014, 30(9): 1659-1666. doi: 10.3866/PKU.WHXB201406162 shu

功能化石墨烯/聚苯胺复合电极材料的制备和电化学性能

基金项目:
国家自然科学基金（51164026)

内蒙古科技大学创新基金（2012NCL007）资助项目

摘要:

利用水合肼还原十八胺（ODA）接枝的氧化石墨烯（），得到了十八胺功能化石墨烯（ODA-G），将ODAG与聚苯胺（PANI）通过溶液共混法，制备了功能化石墨烯和聚苯胺纳米复合材料（ODA-G/PANI）. 采用傅里叶变换红外（FTIR）光谱、X射线衍射（XRD）、热重分析（TGA）、拉曼（Raman）光谱及透射电镜（TEM），对复合材料的结构和形貌进行了表征；利用循环伏安、恒流充放电及交流阻抗谱等，对复合材料的电化学性能进行了测试. 结果显示，少量ODA-G的引入为PANI 的电化学氧化还原反应提供了更多的电子通道和活性位置，有利于提高PANI 的赝电容. 在电流密度1.0 A·g^-1下，2%（w）ODA-G/PANI 的比电容达到787 F·g^-1，而相应的PANI 仅有426 F·g^-1. 此外，ODA-G/PANI的循环稳定性也远高于纯PANI.

关键词:

English

Preparation and Electrochemical Properties of Functionalized Graphene/Polyaniline Composite Electrode Materials

1.
School of Rare Earth, Inner Mon lia University of Science & Technology, Baotou 014010, Inner Mon lia Autonomous Region, P. R. China
Received Date: 19 May 2014
Available Online: 29 August 2014
Fund Project:
国家自然科学基金（51164026)

内蒙古科技大学创新基金（2012NCL007）资助项目

Abstract:

Octadecylamine functionalized graphene (ODA-G) was synthesized by the grafting of graphene oxide ( ) with ODA followed by reduction with hydrazine hydrate. Subsequently, ODA-G/polyaniline (PANI) composites were prepared using a facile solvent-blending procedure. ODA-G and ODA-G/PANI composites were characterized by Fourier transform infrared spectrometry (FTIR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), Raman spectroscopy, and transmission electron microscopy (TEM). The electrochemical properties of the composites were measured based on cyclic voltammetry (CV), galvanostatic charge/discharge, and ac impedance spectroscopy. The results show that ODA-G as a support material provides additional electron transfer paths, as well as active sites, for the electrochemical redox reaction of PANI, which helps to increase its pseudocapacitance. A specific capacitance of 782 F·g^-1 is obtained for 2%(w)ODA-G/PANI at a current density of 1.0 A·g^-1, compared with 426 F·g^-1 for PANI. Furthermore, ODA-G/PANI exhibits better stability than PANI.

Key words:

1. [1]
  
  (1) Yang, G.W.; Xu, C. L.; Li, H. L. Chem. Commun. 2008, 6537.
  (1) Yang, G.W.; Xu, C. L.; Li, H. L. Chem. Commun. 2008, 6537.
2. [2]
  (2) Brownson, D. A. C.; Kampouris, D. K.; Banks, C. E. J. Power Sources 2011, 196, 4873. doi: 10.1016/j.jpowsour.2011.02.022(2) Brownson, D. A. C.; Kampouris, D. K.; Banks, C. E. J. Power Sources 2011, 196, 4873. doi: 10.1016/j.jpowsour.2011.02.022
3. [3]
  (3) Dikin, D. A.; Stankovich, S.; Zimney, E. J.; Piner, R. D.; Dommett, G. H. B.; Evmenenko, G.; Nguyen, S. T.; Ruoff, R. S. Nature 2007, 448, 457. doi: 10.1038/nature06016(3) Dikin, D. A.; Stankovich, S.; Zimney, E. J.; Piner, R. D.; Dommett, G. H. B.; Evmenenko, G.; Nguyen, S. T.; Ruoff, R. S. Nature 2007, 448, 457. doi: 10.1038/nature06016
4. [4]
  (4) Stoller, M. D.; Park, S. J.; Zhu, Y.W.; An, J.; Ruoff, R. S. Nano Lett. 2008, 8, 3498. doi: 10.1021/nl802558y(4) Stoller, M. D.; Park, S. J.; Zhu, Y.W.; An, J.; Ruoff, R. S. Nano Lett. 2008, 8, 3498. doi: 10.1021/nl802558y
5. [5]
  (5) Wu, H. Y.;Wang, H.W. Acta Phys. -Chim. Sin. 2013, 29, 1501. [吴红英, 王欢文. 物理化学学报, 2013, 29, 1501.] doi: 10.3866/PKU.WHXB201304241(5) Wu, H. Y.;Wang, H.W. Acta Phys. -Chim. Sin. 2013, 29, 1501. [吴红英, 王欢文. 物理化学学报, 2013, 29, 1501.] doi: 10.3866/PKU.WHXB201304241
6. [6]
  (6) Xu, G. Y.; Ding, B.; Nie, P.; Luo, H. J.; Zhang, X. G. Acta Phys. -Chim. Sin. 2013, 29, 546. [徐桂银, 丁兵, 聂平, 骆宏钧, 张校刚. 物理化学学报, 2013, 29, 546.] doi: 10.3866/PKU.WHXB201301081(6) Xu, G. Y.; Ding, B.; Nie, P.; Luo, H. J.; Zhang, X. G. Acta Phys. -Chim. Sin. 2013, 29, 546. [徐桂银, 丁兵, 聂平, 骆宏钧, 张校刚. 物理化学学报, 2013, 29, 546.] doi: 10.3866/PKU.WHXB201301081
7. [7]
  (7) Wang, H. Z.; Gao, C. X.; Zhang, P.; Yao, S.W.; Zhang,W. G. Acta Phys. -Chim. Sin. 2013, 29, 117. [王宏智, 高翠侠, 张鹏, 姚素薇, 张卫国. 物理化学学报, 2013, 29, 117.] doi: 10.3866/PKU.WHXB201210234(7) Wang, H. Z.; Gao, C. X.; Zhang, P.; Yao, S.W.; Zhang,W. G. Acta Phys. -Chim. Sin. 2013, 29, 117. [王宏智, 高翠侠, 张鹏, 姚素薇, 张卫国. 物理化学学报, 2013, 29, 117.] doi: 10.3866/PKU.WHXB201210234
8. [8]
  (8) Sun, Y.;Wu, Q.; Shi, G. Energy Environ. Sci. 2011, 4, 1113. doi: 10.1039/c0ee00683a(8) Sun, Y.;Wu, Q.; Shi, G. Energy Environ. Sci. 2011, 4, 1113. doi: 10.1039/c0ee00683a
9. [9]
  (9) Gómez, H.; Ram, M. K.; Alvi, F.; Villalba, P.; Stefanakos, E.; Kumar, A. J. Power Sources 2011, 196, 4102. doi: 10.1016/j.jpowsour.2010.11.002(9) Gómez, H.; Ram, M. K.; Alvi, F.; Villalba, P.; Stefanakos, E.; Kumar, A. J. Power Sources 2011, 196, 4102. doi: 10.1016/j.jpowsour.2010.11.002
10. [10]
  (10) Yan, J.;Wei, T.; Shao, B.; Fan, Z.; Qian,W.; Zhang, M.;Wei, F. Carbon 2010, 48, 487. doi: 10.1016/j.carbon.2009.09.066(10) Yan, J.;Wei, T.; Shao, B.; Fan, Z.; Qian,W.; Zhang, M.;Wei, F. Carbon 2010, 48, 487. doi: 10.1016/j.carbon.2009.09.066
11. [11]
  (11) Zhang, K.; Zhang, L. L.; Zhao, X. S.;Wu, J. Chem. Mater. 2010, 22, 1392. doi: 10.1021/cm902876u(11) Zhang, K.; Zhang, L. L.; Zhao, X. S.;Wu, J. Chem. Mater. 2010, 22, 1392. doi: 10.1021/cm902876u
12. [12]
  (12) Liu, Y.; Deng, R.;Wang, Z.; Liu, H. J. Mater. Chem. 2012, 22, 13619. doi: 10.1039/c2jm32479b(12) Liu, Y.; Deng, R.;Wang, Z.; Liu, H. J. Mater. Chem. 2012, 22, 13619. doi: 10.1039/c2jm32479b
13. [13]
  (13) Lai, L.; Yang, H.;Wang, L.; Teh, B. K.; Zhong, J.; Chou, H.; Chen, L.; Chen,W.; Shen, Z.; Ruoff, R. S.; Lin, J. ACS Nano 2012, 6, 5941. doi: 10.1021/nn3008096(13) Lai, L.; Yang, H.;Wang, L.; Teh, B. K.; Zhong, J.; Chou, H.; Chen, L.; Chen,W.; Shen, Z.; Ruoff, R. S.; Lin, J. ACS Nano 2012, 6, 5941. doi: 10.1021/nn3008096
14. [14]
  (14) Wang, D.W.; Li, F.; Zhao, J.; Ren,W.; Chen, Z. G.; Tan, J.;Wu, Z. S.; Gentle, I.; Lu, G. Q.; Cheng, H. M. ACS Nano 2009, 3, 1745. doi: 10.1021/nn900297m(14) Wang, D.W.; Li, F.; Zhao, J.; Ren,W.; Chen, Z. G.; Tan, J.;Wu, Z. S.; Gentle, I.; Lu, G. Q.; Cheng, H. M. ACS Nano 2009, 3, 1745. doi: 10.1021/nn900297m
15. [15]
  (15) Zhang, Q.; Li, Y.; Feng, Y.; Feng,W. Electrochim. Acta 2013, 90, 95. doi: 10.1016/j.electacta.2012.11.035(15) Zhang, Q.; Li, Y.; Feng, Y.; Feng,W. Electrochim. Acta 2013, 90, 95. doi: 10.1016/j.electacta.2012.11.035
16. [16]
  (16) (a) Luo, B.; Liu, S.; Zhi, L. Small 2012, 8, 630.(16) (a) Luo, B.; Liu, S.; Zhi, L. Small 2012, 8, 630.
17. [17]
  (b) Singh, V.; Joung, D.; Zhai, L.; Das, S.; Khondaker, S. I.; Seal, S. Prog. Mater. Sci. 2011, 56, 1178. doi: 10.1002/smll.v8.5(b) Singh, V.; Joung, D.; Zhai, L.; Das, S.; Khondaker, S. I.; Seal, S. Prog. Mater. Sci. 2011, 56, 1178. doi: 10.1002/smll.v8.5
18. [18]
  (17) Li,W.; Tang, X. Z.; Zhang, H. B.; Jiang, Z. G.; Yu, Z. Z.; Du, X. S.; Mai, Y.W. Carbon 2011, 49, 4724. doi: 10.1016/j.carbon.2011.06.077(17) Li,W.; Tang, X. Z.; Zhang, H. B.; Jiang, Z. G.; Yu, Z. Z.; Du, X. S.; Mai, Y.W. Carbon 2011, 49, 4724. doi: 10.1016/j.carbon.2011.06.077
19. [19]
  (18) Kovtyukhova, N. I.; Ollivier, P. J.; Martin, B. R.; Mallouk, T. E.; Chizhik, S. A.; Buzaneva, E. V.; rchinskiy, A. D. Chem. Mater. 1999, 11, 771. doi: 10.1021/cm981085u(18) Kovtyukhova, N. I.; Ollivier, P. J.; Martin, B. R.; Mallouk, T. E.; Chizhik, S. A.; Buzaneva, E. V.; rchinskiy, A. D. Chem. Mater. 1999, 11, 771. doi: 10.1021/cm981085u
20. [20]
  (19) Jeong, H. K.; Lee, Y. P.; Jin, M. H.; Kim, E. S.; Bae, J. J.; Lee, Y. H. Chem. Phys. Lett. 2009, 470, 255. doi: 10.1016/j.cplett.2009.01.050(19) Jeong, H. K.; Lee, Y. P.; Jin, M. H.; Kim, E. S.; Bae, J. J.; Lee, Y. H. Chem. Phys. Lett. 2009, 470, 255. doi: 10.1016/j.cplett.2009.01.050
21. [21]
  (20) Stankovich, S.; Dikin, D. A.; Piner, R. D.; Kohlhaas, K. A.; Kleinhammes, A.; Jia, Y.;Wu, Y.; Nguyen, S. T.; Ruoff, R. S. Carbon 2007, 45, 1558. doi: 10.1016/j.carbon.2007.02.034(20) Stankovich, S.; Dikin, D. A.; Piner, R. D.; Kohlhaas, K. A.; Kleinhammes, A.; Jia, Y.;Wu, Y.; Nguyen, S. T.; Ruoff, R. S. Carbon 2007, 45, 1558. doi: 10.1016/j.carbon.2007.02.034
22. [22]
  (21) Li,W. P.; Liu, S. H.; Duan, Y. P.; Li, C. M. J. Mater. Sci. Technol. Eng. 2007, 25, 376. [李伟平, 刘顺华, 段玉平, 李长茂. 材料科学与工程学报, 2007, 25, 376.](21) Li,W. P.; Liu, S. H.; Duan, Y. P.; Li, C. M. J. Mater. Sci. Technol. Eng. 2007, 25, 376. [李伟平, 刘顺华, 段玉平, 李长茂. 材料科学与工程学报, 2007, 25, 376.]
23. [23]
  (22) Malarda, L. M.; Pimenta, M. A.; Dresselhaus, G.; Dresselhaus, M. S. Phys. Rep. 2009, 473, 51. doi: 10.1016/j.physrep.2009.02.003(22) Malarda, L. M.; Pimenta, M. A.; Dresselhaus, G.; Dresselhaus, M. S. Phys. Rep. 2009, 473, 51. doi: 10.1016/j.physrep.2009.02.003
24. [24]
  (23) Ferrari, A. C. Solid State Commun. 2007, 143, 47. doi: 10.1016/j.ssc.2007.03.052(23) Ferrari, A. C. Solid State Commun. 2007, 143, 47. doi: 10.1016/j.ssc.2007.03.052
25. [25]
  (24) Ganesan, R.; Shanmugam, S.; Gedanken, A. Synth. Met. 2008, 158, 848. doi: 10.1016/j.synthmet.2008.06.001(24) Ganesan, R.; Shanmugam, S.; Gedanken, A. Synth. Met. 2008, 158, 848. doi: 10.1016/j.synthmet.2008.06.001
26. [26]
  (25) Cochet, M.; Louarn, G.; Quillard, S.; Buisson, J. P.; Lefrant, S. J. Raman Spectrosc. 2000, 31, 1041.(25) Cochet, M.; Louarn, G.; Quillard, S.; Buisson, J. P.; Lefrant, S. J. Raman Spectrosc. 2000, 31, 1041.
27. [27]
  (26) Stoller, M. D.; Ruoff, R. S. Energy Environ. Sci. 2010, 3, 1294. doi: 10.1039/c0ee00074d
  (26) Stoller, M. D.; Ruoff, R. S. Energy Environ. Sci. 2010, 3, 1294. doi: 10.1039/c0ee00074d

扫一扫看文章

计量

PDF下载量: 734
文章访问数: 932
HTML全文浏览量: 18

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

功能化石墨烯/聚苯胺复合电极材料的制备和电化学性能

English

Preparation and Electrochemical Properties of Functionalized Graphene/Polyaniline Composite Electrode Materials

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

功能化石墨烯/聚苯胺复合电极材料的制备和电化学性能

English

Preparation and Electrochemical Properties of Functionalized Graphene/Polyaniline Composite Electrode Materials

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs