金属有机骨架材料MIL-53(Al)负载纳米Pd颗粒：一种CO氧化的活性催化剂

引用本文: 梁倩, 赵震, 刘坚, 韦岳长, 姜桂元, 段爱军. 金属有机骨架材料MIL-53(Al)负载纳米Pd颗粒：一种CO氧化的活性催化剂[J]. 物理化学学报, 2014, 30(1): 129-134. doi: 10.3866/PKU.WHXB201311201 shu

Citation: LIANG Qian, ZHAO Zhen, LIU Jian, WEI Yue-Chang, JIANG Gui-Yuan, DUAN Ai-Jun. Pd Nanoparticles Deposited on Metal-Organic Framework of MIL-53(Al)：an Active Catalyst for CO Oxidation[J]. Acta Physico-Chimica Sinica, 2014, 30(1): 129-134. doi: 10.3866/PKU.WHXB201311201 shu

金属有机骨架材料MIL-53(Al)负载纳米Pd颗粒：一种CO氧化的活性催化剂

基金项目:
国家自然科学基金(21073235，21173270，21177160) (21073235，21173270，21177160)

国家高技术研究发展计划(863) (2013AA061902)资助项目 (863) (2013AA061902)

摘要:

通过等体积浸渍法制备了金属有机骨架材料MIL-53(Al) (MIL：Materials of Institut Lavoisier)负载纳米Pd催化剂. 采用X射线衍射(XRD)、透射电子显微镜(TEM)和X射线光电子能谱(XPS)等手段对催化剂的结构进行了表征. 催化剂在反应前后XRD衍射峰保持不变，说明载体MIL-53(Al)具有良好的稳定性. 采用TEM对催化剂进行表征，结果表明，MIL-53(Al)的多孔晶体结构有助于形成高度分散的纳米Pd颗粒，样品2.7% (w) Pd/MIL-53 中Pd颗粒的平均粒径为2.21 nm. 该催化剂在CO氧化反应中表现出较高的催化活性，115 ℃达到完全转化. 同时催化剂可循环使用，多次反应后催化活性和催化剂结构都保持稳定.

关键词:

English

Pd Nanoparticles Deposited on Metal-Organic Framework of MIL-53(Al)：an Active Catalyst for CO Oxidation

1.
State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249, P. R. China
Received Date: 26 August 2013
Available Online: 01 January 2014
Fund Project:
国家自然科学基金(21073235，21173270，21177160)

国家高技术研究发展计划(863) (2013AA061902)资助项目

Abstract:

Pd nanoparticles (NPs) supported on a metal-organic framework (MOF), MIL-53(Al) (MIL: Materials of Institut Lavoisier), were prepared using the incipient wetness impregnation method. The structures of the synthesized Pd/MIL-53(Al) catalysts were determined using X-ray diffraction (XRD), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS). The same peaks were observed in the XRD patterns of Pd/MIL-53(Al) before and after the catalytic reaction, confirming that the integrity of the MIL-53(Al) support was maintained. The TEM results indicated that the crystalline porous structure of MIL-53(Al) favored the formation of highly dispersed Pd NPs of average size 2.21 nm. The heterogeneous catalytic composite materials exhibited high activities for CO oxidation, with full conversion at 115 ℃. The catalytic activity and structure of Pd/MIL-53(Al) were stable after several reaction runs.

Key words:

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

金属有机骨架材料MIL-53(Al)负载纳米Pd颗粒：一种CO氧化的活性催化剂

English

Pd Nanoparticles Deposited on Metal-Organic Framework of MIL-53(Al)：an Active Catalyst for CO Oxidation

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

金属有机骨架材料MIL-53(Al)负载纳米Pd颗粒：一种CO氧化的活性催化剂

English

Pd Nanoparticles Deposited on Metal-Organic Framework of MIL-53(Al)：an Active Catalyst for CO Oxidation

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

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