新型蓝色上转换荧光分子的合成、表征与双光子吸收性能

引用本文: 蔡志彬, 刘立芬, 孔成, 朱耀信. 新型蓝色上转换荧光分子的合成、表征与双光子吸收性能[J]. 物理化学学报, 2014, 30(1): 164-170. doi: 10.3866/PKU.WHXB201311051 shu

Citation: CAI Zhi-Bin, LIU Li-Fen, KONG Cheng, ZHU Yao-Xin. Synthesis, Characterization and Two-Photon Absorption Properties of Novel Blue Up-Converted Fluorescent Molecules[J]. Acta Physico-Chimica Sinica, 2014, 30(1): 164-170. doi: 10.3866/PKU.WHXB201311051 shu

新型蓝色上转换荧光分子的合成、表征与双光子吸收性能

基金项目:
国家自然科学基金(21103151) (21103151)

浙江省重点科技创新团队(2010R50018)资助项目 (2010R50018)

摘要:

设计并合成了3 个新的受体-给体-受体(A-D-A)构型上转换荧光分子，用傅里叶变换红外光谱、核磁共振氢谱、质谱和元素分析进行了表征. 测定了它们在不同溶剂中的线性吸收光谱、单光子荧光光谱和荧光量子产率. 以飞秒激光作为光源，研究了它们的双光子吸收和上转换荧光特性. 结果表明：该类化合物的荧光量子产率为0.20-0.68，双光子吸收截面为16×10^-50-101×10^-50 cm⁴·s·photon^-1，具有较强的蓝色上转换荧光发射.

关键词:

English

Synthesis, Characterization and Two-Photon Absorption Properties of Novel Blue Up-Converted Fluorescent Molecules

1.
College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310014, P. R. China
Received Date: 16 August 2013
Available Online: 01 January 2014
Fund Project:
国家自然科学基金(21103151)

浙江省重点科技创新团队(2010R50018)资助项目

Abstract:

Three new acceptor-donor-acceptor (A-D-A) up-converted fluorescent molecules were designed and synthesized. Their structures were characterized using Fourier transform infrared and hydrogen nuclear magnetic resonance spectroscopy, mass spectrometry, and elemental analysis. The linear absorption spectra, single-photon excited fluorescence spectra, and fluorescence quantum yields were measured in different solvents. The two-photon absorption and up-converted fluorescent properties were studied using a femtosecond laser. The results showed that the fluorescence quantum yields were 0.20-0.68, the two-photon absorption cross-sections were 16×10^-50-101×10^-50 cm⁴·s·photon^-1, and they exhibited strong blue up-converted fluorescence.

Key words:

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沈阳化工大学材料科学与工程学院沈阳 110142

新型蓝色上转换荧光分子的合成、表征与双光子吸收性能

English

Synthesis, Characterization and Two-Photon Absorption Properties of Novel Blue Up-Converted Fluorescent Molecules

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

新型蓝色上转换荧光分子的合成、表征与双光子吸收性能

English

Synthesis, Characterization and Two-Photon Absorption Properties of Novel Blue Up-Converted Fluorescent Molecules

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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