阳离子和两性表面活性剂在聚甲基丙烯酸甲酯表面的吸附行为

引用本文: 刘丹丹, 徐志成, 赵群, 张磊, 张路, 赵濉. 阳离子和两性表面活性剂在聚甲基丙烯酸甲酯表面的吸附行为[J]. 物理化学学报, 2013, 29(03): 569-575. doi: 10.3866/PKU.WHXB201212284 shu

Citation: LIU Dan-Dan, XU Zhi-Cheng, ZHAO Qun, ZHANG Lei, ZHANG Lu, ZHAO Sui. Adsorption Behavior of Cationic and Zwitterionic Surfactants on Poly(methyl methacrylate)[J]. Acta Physico-Chimica Sinica, 2013, 29(03): 569-575. doi: 10.3866/PKU.WHXB201212284 shu

阳离子和两性表面活性剂在聚甲基丙烯酸甲酯表面的吸附行为

刘丹丹 ^1,2, ,
徐志成 ^1, ,
赵群 ^3, ,
张磊 ^1, ,
张路 ^1, ,
赵濉 ^1,

基金项目:
国家科技重大专项(2011ZX05011-004)资助项目 (2011ZX05011-004)

摘要:

利用座滴法研究了阳离子表面活性剂十六烷基醚羟丙基季铵盐(C₁₆PC)、十六烷基聚氧乙烯醚羟丙基季铵盐(C₁₆(EO)₃PC)和两性离子表面活性剂十六烷基醚羟丙基羧酸甜菜碱(C₁₆PB)、十六烷基聚氧乙烯醚羟丙基羧酸甜菜碱(C₁₆(EO)₃PB)溶液在聚甲基丙烯酸甲酯(PMMA)表面上的润湿性质, 考察了表面活性剂类型及浓度对接触角的影响趋势. 研究发现: 低浓度条件下表面活性剂分子可能以平躺的方式吸附到固体界面, 且亲水基团靠近固体界面, PMMA表面被轻微疏水化; 在高浓度时则通过Lifshitz-van der Waals 作用吸附, 亲水基团在外, PMMA表面被亲水改性. 聚氧乙烯基团(EO基团)的引入对阳离子表面活性剂的接触角影响不大; 而含有聚氧乙烯基团的两性离子表面活性剂在PMMA界面上以类似半胶束的聚集体吸附, 大幅度降低接触角.

关键词:

English

Adsorption Behavior of Cationic and Zwitterionic Surfactants on Poly(methyl methacrylate)

1.
1 Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China;
2 Graduate University of Chinese Academy of Sciences, Beijing 100049, P. R. China;
3 Petrochina Liaohe Oilfield Company Xinglongtai Oil Production Plant, Panjin 124000, Liaoning Province, P. R. China
Received Date: 01 November 2012
Available Online: 25 February 2013
Fund Project:
国家科技重大专项(2011ZX05011-004)资助项目

Abstract:

The wetting behavior of poly(methyl methacrylate) (PMMA) surfaces by aqueous solutions of cationic surfactants, hexadecanol glycidyl ether ammonium chloride (C₁₆PC), hexadecanol polyoxyethylene (3) glycidyl ether ammonium chloride (C₁₆(EO)₃PC), and zwitterionic surfactants, hexadecanol glycidyl ether glycine betaine (C₁₆PB) and hexadecanol polyoxyethylene(3) glycidyl ether glycine betaine (C₁₆(EO)₃PB), were investigated by sessile drop analysis. The influence of surfactant type and concentration on contact angle was determined. The PMMA surface is modified hydrophobically only slightly at low bulk concentration because the surfactant molecules are parallel to the substrate surface and the hydrophilic groups are close to the surface. However, at high concentration, the surfactant molecules can adsorb onto the PMMA surface through Lifshitz-van der Waals interactions and hydrophilic groups directed towards the bulk phase of solution, which increases the hydrophilic character of the PMMA surface. The contact angles of cationic surfactants show little variation following the insertion of polyoxyethylene units. However, the presence of polyoxyethylene units in the zwitterionic surfactants leads to an obvious decrease of contact angle because of the formation of hemimicelles on the PMMA surface.

Key words:

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

阳离子和两性表面活性剂在聚甲基丙烯酸甲酯表面的吸附行为

English

Adsorption Behavior of Cationic and Zwitterionic Surfactants on Poly(methyl methacrylate)

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

阳离子和两性表面活性剂在聚甲基丙烯酸甲酯表面的吸附行为

English

Adsorption Behavior of Cationic and Zwitterionic Surfactants on Poly(methyl methacrylate)

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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