微接触印刷技术在ITO基底上快速转移Au纳米粒子图案

引用本文: 汤儆, 庞文辉, 任禾, 陈巧兰, 宋子旺, 林建航. 微接触印刷技术在ITO基底上快速转移Au纳米粒子图案[J]. 物理化学学报, 2013, 29(03): 612-618. doi: 10.3866/PKU.WHXB201212281 shu

Citation: TANG Jing, PANG Wen-Hui, Ren He, CHEN Qiao-Lan, SONG Zi-Wang, LIN Jian-Hang. Rapid Transfer of Au Nanoparticle Pattern onto ITO Substrate Using Microcontact Printing Technique[J]. Acta Physico-Chimica Sinica, 2013, 29(03): 612-618. doi: 10.3866/PKU.WHXB201212281 shu

微接触印刷技术在ITO基底上快速转移Au纳米粒子图案

汤儆 ^1, ,
庞文辉 ^1, ,
任禾 ^1, ,
陈巧兰 ^1, ,
宋子旺 ^1, ,
林建航 ^2,

基金项目:
国家自然科学基金(21173048, 21073038)资助项目 (21173048, 21073038)

摘要:

采用无氰化学镀金法在聚二甲基硅氧烷(PDMS)印章表面镀金, 通过微接触印刷技术将PDMS印章上的Au 纳米粒子(AuNPs)分别转移到氧化铟锡(ITO)透明导电膜玻璃, 修饰了(3-巯基丙基)三甲氧基硅烷(MPTMS)的ITO基底(MPTMS/ITO)和表面电镀了铜膜的ITO(Cu/ITO)表面上, 同时形成有序的结构或者图案.通过场发射扫描电镜(FE-SEM), 原子力显微镜(AFM)和显微共聚焦激光拉曼光谱仪等对实验结果进行表征.结果表明, 该转移AuNPs的方法对基底表面特性并无特殊要求, 是一种简单、快速、无污染、低成本的AuNPs转移技术, 而且转移了AuNPs的ITO基底具有表面增强拉曼光谱(SERS)活性, 有望在SERS中有所应用.

关键词:

English

Rapid Transfer of Au Nanoparticle Pattern onto ITO Substrate Using Microcontact Printing Technique

1.
1 Key Laboratory of Analysis and Detection Technology for Food Safety, Ministry of Education, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, P. R. China;
2 Instrμmental Measurement and Analysis Center, Fuzhou University, Fuzhou 350002, P. R. China
Received Date: 09 October 2012
Available Online: 25 February 2013
Fund Project:
国家自然科学基金(21173048, 21073038)资助项目

Abstract:

A poly(dimethylsiloxane) (PDMS) stamp was electrolessly plated using a cyanide-free solution. ld nanoparticles (AuNPs) were transferred from the PDMS stamp to indium tin oxide (ITO), (3- mercaptopropyl) trimethoxysilane modified ITO (MPTMS/ITO), and an ITO substrate electrodeposited with a thin copper film (Cu/ITO). AuNPs formed well-ordered structures which were characterized by field emission scanning electron microscopy (FE-SEM), atomic force microscopy (AFM), and Raman spectroscopy. Microcontact printing allowed thin AuNPs films to be directly transferred from PDMS to substrate, so is a simple, fast, cheap and environmentally-friendly technique. AuNPs patterned on the ITO substrate exhibited surface-enhanced Raman spectroscopy (SERS) activity which will be investigated in subsequent studies.

Key words:

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

微接触印刷技术在ITO基底上快速转移Au纳米粒子图案

English

Rapid Transfer of Au Nanoparticle Pattern onto ITO Substrate Using Microcontact Printing Technique

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

微接触印刷技术在ITO基底上快速转移Au纳米粒子图案

English

Rapid Transfer of Au Nanoparticle Pattern onto ITO Substrate Using Microcontact Printing Technique

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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