硫化亚铜对电极在量子点敏化太阳电池中的应用

引用本文: 朱俊, 余学超, 王时茂, 董伟伟, 胡林华, 方晓东, 戴松元. 硫化亚铜对电极在量子点敏化太阳电池中的应用[J]. 物理化学学报, 2013, 29(03): 533-538. doi: 10.3866/PKU.WHXB201212124 shu

Citation: ZHU Jun, YU Xue-Chao, WANG Shi-Mao, DONG Wei-Wei, HU Lin-Hua, FANG Xiao-Dong, DAI Song-Yuan. Application of Cu₂S Counter Electrode in Quantum Dot-Sensitized Solar Cells[J]. Acta Physico-Chimica Sinica, 2013, 29(03): 533-538. doi: 10.3866/PKU.WHXB201212124 shu

硫化亚铜对电极在量子点敏化太阳电池中的应用

基金项目:
国家重点基础研究发展计划(973) (2011CBA00700) (973) (2011CBA00700)

国家高技术研究发展计划(863) (2011AA050527) (863) (2011AA050527)

国家自然科学基金(21003130, 21103197, 21173227, 21173228)资助项目 (21003130, 21103197, 21173227, 21173228)

摘要:

报道了一种基于硫族金属复合物N₄H₉Cu₇S₄前驱体溶液制备硫化亚铜对电极的新方法. 分别制备了TiO₂纳米颗粒多孔薄膜和TiO₂纳米棒阵列结构的光阳极, 并在此基础上研究了基于硫化亚铜对电极的CdS/CdSe量子点敏化太阳电池的光电性能, 同时结合电化学阻抗技术考察了硫化亚铜对电极的催化性能. 结果表明: 与铂电极相比, 本方法制备的硫化亚铜电极对多硫电解质具有更高的催化活性, 所组装的CdS/CdSe量子点敏化太阳电池具有更优的光伏性能.

关键词:

English

Application of Cu₂S Counter Electrode in Quantum Dot-Sensitized Solar Cells

1.
1 Key Laboratory of Novel Thin Film Solar Cells, hinese Academy of Sciences, Hefei, 230031, P. R. China;
2 Institute of Plasma Physics, hinese Academy of Sciences, Hefei, 230031, P. R. China;
3 Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei, 230031, P. R. China
Received Date: 09 October 2012
Available Online: 25 February 2013
Fund Project:
国家重点基础研究发展计划(973) (2011CBA00700)

国家高技术研究发展计划(863) (2011AA050527)

国家自然科学基金(21003130, 21103197, 21173227, 21173228)资助项目

Abstract:

Cu₂S counter electrodes were prepared from the metal chalcogenide complex precursor using a novel method. A porous TiO₂ nanoparticle film and TiO₂ nanorod array photoanode were also fabricated. The corresponding CdS/CdSe-sensitized solar cells with the Cu₂S counter electrode were assembled and their photovoltaic performances were studied. The catalytic performance of the Cu₂S counter electrodes was investigated using electrochemical impedance spectroscopy. Compared with a platinum counter electrode, the Cu₂S one exhibited higher catalytic activity and better photovoltaic performance in quantum dot-sensitized solar cells.

Key words:

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沈阳化工大学材料科学与工程学院沈阳 110142

硫化亚铜对电极在量子点敏化太阳电池中的应用

English

Application of Cu₂S Counter Electrode in Quantum Dot-Sensitized Solar Cells

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

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CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

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硫化亚铜对电极在量子点敏化太阳电池中的应用

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Application of Cu2S Counter Electrode in Quantum Dot-Sensitized Solar Cells

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CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

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