双亲性无规共聚物自组装胶束结构及其乳化性能

引用本文: 刘娜, 易成林, 孙建华, 王娟勤, 刘晓亚. 双亲性无规共聚物自组装胶束结构及其乳化性能[J]. 物理化学学报, 2013, 29(02): 327-334. doi: 10.3866/PKU.WHXB201212032 shu

Citation: LIU Na, YI Cheng-Lin, SUN Jian-Hua, WANG Juan-Qin, LIU Xiao-Ya. Structure and Emulsification Performance of Amphiphilic Copolymer Self-Assembled Micelles[J]. Acta Physico-Chimica Sinica, 2013, 29(02): 327-334. doi: 10.3866/PKU.WHXB201212032 shu

双亲性无规共聚物自组装胶束结构及其乳化性能

基金项目:
国家自然科学基金(20974041, 21174056) (20974041, 21174056)

中央高校基本科研业务费专项资金(JUDCF09007)资助项目 (JUDCF09007)

摘要:

以不同交联度、溶胀程度的双亲无规共聚物聚[(苯乙烯-alt-马来酸酐)-co-(7-对乙烯基苄氧基-4-甲基香豆素-alt-马来酸酐)](PSMVM)胶束作为聚合物胶束乳化剂稳定甲苯/水体系, 重点研究光交联度对胶束结构及其乳化性能的影响. 结果表明, 胶束交联度、溶胀度和荷电性对胶束结构及乳化性能有较大影响.

关键词:

双亲性
/ 自组装
/ 光交联度
/ 溶胀度
/ 乳化

English

Structure and Emulsification Performance of Amphiphilic Copolymer Self-Assembled Micelles

1.
Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, Jiangsu Province, P. R. China
Received Date: 23 October 2012
Available Online: 14 January 2013
Fund Project:
国家自然科学基金(20974041, 21174056)

中央高校基本科研业务费专项资金(JUDCF09007)资助项目

Abstract:

The photosensitive amphiphilic copolymer poly-(styrene-alt-maleic anhydride)-co-poly (7-(4-vinylbenzyloxyl)-4-methylcoumarin-alt-maleic anhydride) (PSMVM) micelles with various degrees of swelling were used as polymeric micellar emulsifiers to stabilize toluene-in-water emulsions. This paper focuses on the influence of the degree of photo-crosslinking on the micellar structure and the emulsification performance of the micelles. The research results indicated that the degree of photo-crosslinking, the degree of swelling, and the charge on the micelles played an important role in the micellar structure and the emulsifying performance of the micelles.

Key words:

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

双亲性无规共聚物自组装胶束结构及其乳化性能

English

Structure and Emulsification Performance of Amphiphilic Copolymer Self-Assembled Micelles

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

双亲性无规共聚物自组装胶束结构及其乳化性能

English

Structure and Emulsification Performance of Amphiphilic Copolymer Self-Assembled Micelles

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

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