烷氧磺酸盐功能化的聚乙撑二氧噻吩水凝胶

引用本文: 杜然, 张学同. 烷氧磺酸盐功能化的聚乙撑二氧噻吩水凝胶[J]. 物理化学学报, 2012, 28(10): 2305-2314. doi: 10.3866/PKU.WHXB201209142 shu

Citation: DU Ran, ZHANG Xue-tong. Alkoxysulfonate-Functionalized Poly(3,4-ethylenedioxythiophene) Hydrogels[J]. Acta Physico-Chimica Sinica, 2012, 28(10): 2305-2314. doi: 10.3866/PKU.WHXB201209142 shu

烷氧磺酸盐功能化的聚乙撑二氧噻吩水凝胶

杜然 ^1,2, ,
张学同 ^1,

基金项目:
国家自然科学基金(20903009) (20903009)

北京理工大学优秀青年教师资助计划(2010YS0903)资助 (2010YS0903)

摘要:

通过氧化偶联聚合方法成功地制备出一种基于烷氧磺酸盐功能化的聚乙撑二氧噻吩水凝胶, 揭示了零维单体胶束向二维纳米片层及三维水凝胶的转变过程, 发现通过改变反应温度或初始单体浓度, 可以诱导水凝胶网络结构单元的维度变化, 即由零维纳米粒子向二维纳米片层进行转化. 提出了一种导电高分子水凝胶的合成方法, 即采用一种氧化剂与一种多价金属盐的混合物作为引发剂, 其中前者用于诱导单体聚合, 后者则充当离子交联试剂, 并发现可以通过引入不同金属离子来改变凝胶的形貌. 此外, 导电高分子水凝胶具有良好的电化学电容, 并具有选择性吸附与可控脱附某些染料分子的特性.

关键词:

导电高分子
/ 水凝胶
/ 电化学
/ 染料
/ 过氧化

English

Alkoxysulfonate-Functionalized Poly(3,4-ethylenedioxythiophene) Hydrogels

DU Ran ^1,2, ,
ZHANG Xue-tong ^1,

1.
1 School of Materials Science & Engineering, Beijing Institute of Technology, Beijing, 100081, P. R. China;
2 College of Chemistry & Molecular Engineering, Peking University, Beijing, 100871, P. R. China
Received Date: 19 July 2012
Available Online: 26 September 2012
Fund Project:
国家自然科学基金(20903009)

北京理工大学优秀青年教师资助计划(2010YS0903)资助

Abstract:

Conducting polymer hydrogels based on alkoxysulfonate-functionalized poly(3, 4-ethylenedioxythiophene) have been synthesized via oxidative coupling polymerization. Formation of hydrogels from zero dimensional (0D) monomer micelles to three dimensional (3D) hydrogels with two dimensional (2D) nanosheets as the building blocks and dimension change of the building blocks of the resulting hydrogels from 0D nanoparticles to 2D nanosheets induced by altering the reaction temperature or initial monomer concentration have been disclosed. A synthetic strategy for the synthesis of the conducting polymer hydrogels based on simultaneous use of one chemical as an oxidant and one multivalent metal ion as an ionic crosslinker has been developed, and metal ions used have significant effect on the morphology of the resulting hydrogels. In addition, the as-prepared conducting polymer hydrogels possess od electrochemical capacity, and exhibit selective adsorption and controllable release towards some dye molecules.

Key words:

1. [1]
  
  (1) Sakamoto, J.; Heijst, J. V.; Lukin O.; Schlüter, A. D. Angew. Chem. Int. Edit. 2009, 48, 1030. doi: 10.1002/anie.v48:6
  (1) Sakamoto, J.; Heijst, J. V.; Lukin O.; Schlüter, A. D. Angew. Chem. Int. Edit. 2009, 48, 1030. doi: 10.1002/anie.v48:6
2. [2]
  (2) Simpson, C. D.; Brand, J. D.; Berresheim, A. J.; Przybilla, L.;Räder, H. J.; Müllen, K. Chem. Eur. J. 2002, 8, 1424. doi: 10.1002/(ISSN)1521-3765(2) Simpson, C. D.; Brand, J. D.; Berresheim, A. J.; Przybilla, L.;Räder, H. J.; Müllen, K. Chem. Eur. J. 2002, 8, 1424. doi: 10.1002/(ISSN)1521-3765
3. [3]
  (3) Wan, S.; Guo, J.; Kim, J.; Ihee, H.; Jiang, D. L. Angew. Chem.2009, 121, 5547. doi: 10.1002/ange.200900881(3) Wan, S.; Guo, J.; Kim, J.; Ihee, H.; Jiang, D. L. Angew. Chem.2009, 121, 5547. doi: 10.1002/ange.200900881
4. [4]
  (4) Feng, X.; Chen, L.; Dong, Y. P.; Jiang, D. L. Chem. Commun.2011, 47, 1979. doi: 10.1039/c0cc04386a(4) Feng, X.; Chen, L.; Dong, Y. P.; Jiang, D. L. Chem. Commun.2011, 47, 1979. doi: 10.1039/c0cc04386a
5. [5]
  (5) Colson, J.W. ;Woll, A. R.; Mukherjee, A.; Levendorf, M. P.;Spitler, E. L.; Shields, V. B.; Spencer, M. G.; Park, J.; Dichtel,W. R. Science 2011, 332, 228. doi: 10.1126/science.1202747(5) Colson, J.W. ;Woll, A. R.; Mukherjee, A.; Levendorf, M. P.;Spitler, E. L.; Shields, V. B.; Spencer, M. G.; Park, J.; Dichtel,W. R. Science 2011, 332, 228. doi: 10.1126/science.1202747
6. [6]
  (6) Garcia, A. M.; Romero-Salguero, F. J.; Bassani, D. M.; Lehn,J.-M.; Baum, G.; Fenske, D. Chem. Eur. J. 1999, 5, 1803. doi: 10.1002/(ISSN)1521-3765(6) Garcia, A. M.; Romero-Salguero, F. J.; Bassani, D. M.; Lehn,J.-M.; Baum, G.; Fenske, D. Chem. Eur. J. 1999, 5, 1803. doi: 10.1002/(ISSN)1521-3765
7. [7]
  (7) Yu, L.; Chen, M.; Dalton, R. L. Chem. Mater. 1990, 2, 649. doi: 10.1021/cm00012a013(7) Yu, L.; Chen, M.; Dalton, R. L. Chem. Mater. 1990, 2, 649. doi: 10.1021/cm00012a013
8. [8]
  (8) Schlüter, A. D. Adv. Mater. 1991, 3, 282. doi: 10.1002/(ISSN)1521-4095(8) Schlüter, A. D. Adv. Mater. 1991, 3, 282. doi: 10.1002/(ISSN)1521-4095
9. [9]
  (9) Kubo, Y. ; Kitada, Y. ;Wakabayashi, R.; Kishida, T.; Ayabe, M.;Kaneko, K.; Takeuchi, M.; Shinkai, S. Angew. Chem. Int. Edit.2006, 45, 1548. doi: 10.1002/(ISSN)1521-3773(9) Kubo, Y. ; Kitada, Y. ;Wakabayashi, R.; Kishida, T.; Ayabe, M.;Kaneko, K.; Takeuchi, M.; Shinkai, S. Angew. Chem. Int. Edit.2006, 45, 1548. doi: 10.1002/(ISSN)1521-3773
10. [10]
  (10) Wakabayashi, R. ; Kubo, Y.; Kaneko, K.; Takeuchi, M.; Shinkai,S. J. Am. Chem. Soc. 2006, 128, 8744. doi: 10.1021/ja063040x(10) Wakabayashi, R. ; Kubo, Y.; Kaneko, K.; Takeuchi, M.; Shinkai,S. J. Am. Chem. Soc. 2006, 128, 8744. doi: 10.1021/ja063040x
11. [11]
  (11) Asakusa, S.; Okada, H.; Kunitake, T. J. Am. Chem. Soc. 1991,113, 1749. doi: 10.1021/ja00005a044(11) Asakusa, S.; Okada, H.; Kunitake, T. J. Am. Chem. Soc. 1991,113, 1749. doi: 10.1021/ja00005a044
12. [12]
  (12) Zheng, Z. K.; Nottbohm, C. T.; Turchanin, A.; Muzik, H.; Beyer,A.; Heilemann, M.; Sauer, M.; Gölzhäuser, A. Angew. Chem. Int. Edit. 2010, 49, 8493. doi: 10.1002/anie.201004053(12) Zheng, Z. K.; Nottbohm, C. T.; Turchanin, A.; Muzik, H.; Beyer,A.; Heilemann, M.; Sauer, M.; Gölzhäuser, A. Angew. Chem. Int. Edit. 2010, 49, 8493. doi: 10.1002/anie.201004053
13. [13]
  (13) Bauer, T.; Zheng, Z. K.; Renn, A.; Enning, R.; Stemmer, A.;Sakamoto, J.; Schlüter, A. D. Angew. Chem. Int. Edit. 2011, 50,7879. doi: 10.1002/anie.v50.34(13) Bauer, T.; Zheng, Z. K.; Renn, A.; Enning, R.; Stemmer, A.;Sakamoto, J.; Schlüter, A. D. Angew. Chem. Int. Edit. 2011, 50,7879. doi: 10.1002/anie.v50.34
14. [14]
  (14) Nayak, S.; Lyon, L. A. Angew. Chem. Int. Edit. 2005, 44, 7686.doi: 10.1002/(ISSN)1521-3773(14) Nayak, S.; Lyon, L. A. Angew. Chem. Int. Edit. 2005, 44, 7686.doi: 10.1002/(ISSN)1521-3773
15. [15]
  (15) Tokarev, I.; Minko, S. Soft Matter 2009, 5, 511. doi: 10.1039/b813827c(15) Tokarev, I.; Minko, S. Soft Matter 2009, 5, 511. doi: 10.1039/b813827c
16. [16]
  (16) Roy, D.; Cambre, J. N.; Sumerlin, B. S. Prog. Polym. Sci. 2010,35, 278. doi: 10.1016/j.progpolymsci.2009.10.008(16) Roy, D.; Cambre, J. N.; Sumerlin, B. S. Prog. Polym. Sci. 2010,35, 278. doi: 10.1016/j.progpolymsci.2009.10.008
17. [17]
  (17) Raemdonck, K.; Demeester, J.; Smedt, S. D. Soft Matter 2009,5, 707. doi: 10.1039/b811923f(17) Raemdonck, K.; Demeester, J.; Smedt, S. D. Soft Matter 2009,5, 707. doi: 10.1039/b811923f
18. [18]
  (18) Jin, S. P.; Liu, M. Z.; Chen, S. L.; Bian, F. L.; Chen, Y.;Wang,B.; Zhan, F. L.; Liu, S. X. Acta Phys. -Chim. Sin. 2007, 23, 438.[金淑萍, 柳明珠, 陈世兰, 卞凤玲, 陈勇, 王斌, 詹发禄,刘守信. 物理化学学报, 2007, 23, 438.] doi: 10.3866/PKU.WHXB20070330(18) Jin, S. P.; Liu, M. Z.; Chen, S. L.; Bian, F. L.; Chen, Y.;Wang,B.; Zhan, F. L.; Liu, S. X. Acta Phys. -Chim. Sin. 2007, 23, 438.[金淑萍, 柳明珠, 陈世兰, 卞凤玲, 陈勇, 王斌, 詹发禄,刘守信. 物理化学学报, 2007, 23, 438.] doi: 10.3866/PKU.WHXB20070330
19. [19]
  (19) Shen, Y. H.; Liu, H. M.; Li, G. Q.; Zhai, Z. G.; Shu, X. F.; Tai,X. M. Acta Phys. -Chim. Sin. 2011, 27, 1919. [申迎华, 刘慧敏, 李国卿, 翟志国, 树学峰, 台秀梅. 物理化学学报, 2011, 27,1919.] doi: 10.3866/PKU.WHXB20110815(19) Shen, Y. H.; Liu, H. M.; Li, G. Q.; Zhai, Z. G.; Shu, X. F.; Tai,X. M. Acta Phys. -Chim. Sin. 2011, 27, 1919. [申迎华, 刘慧敏, 李国卿, 翟志国, 树学峰, 台秀梅. 物理化学学报, 2011, 27,1919.] doi: 10.3866/PKU.WHXB20110815
20. [20]
  (20) Chen, L.; Kim, B. S.; Nishino, M.; ng, J. P.; Osada, Y.Macromolecules 2000, 33, 1232. doi: 10.1021/ma990923i(20) Chen, L.; Kim, B. S.; Nishino, M.; ng, J. P.; Osada, Y.Macromolecules 2000, 33, 1232. doi: 10.1021/ma990923i
21. [21]
  (21) Dai, T.; Jiang, X.; Hua, S.;Wang, X.; Lu, Y. Chem. Commun.2008, 4279.(21) Dai, T.; Jiang, X.; Hua, S.;Wang, X.; Lu, Y. Chem. Commun.2008, 4279.
22. [22]
  (22) Du, R.; Xu, Y. Z.; Luo, Y. J. ; Zhang, X. T.; Zhang, J. Chem. Commun. 2011, 47, 6287. doi: 10.1039/c1cc10915d(22) Du, R.; Xu, Y. Z.; Luo, Y. J. ; Zhang, X. T.; Zhang, J. Chem. Commun. 2011, 47, 6287. doi: 10.1039/c1cc10915d
23. [23]
  (23) Mano, N.; Yoo, J. E.; Tarver, J.; Loo, Y. L.; Heller, A. J. Am. Chem. Soc. 2007, 129, 7006. doi: 10.1021/ja071946c(23) Mano, N.; Yoo, J. E.; Tarver, J.; Loo, Y. L.; Heller, A. J. Am. Chem. Soc. 2007, 129, 7006. doi: 10.1021/ja071946c
24. [24]
  (24) Pan, L.; Yu, G.; Zhai, D.; Lee, H. R.; Zhao,W.; Liu, N.;Wang,H.; Tee, B. C. K.; Shi, Y.; Cui, Y. Proc. Natl. Acad. Sci. U. S. A.2012, 109, 9287. doi: 10.1073/pnas.1202636109(24) Pan, L.; Yu, G.; Zhai, D.; Lee, H. R.; Zhao,W.; Liu, N.;Wang,H.; Tee, B. C. K.; Shi, Y.; Cui, Y. Proc. Natl. Acad. Sci. U. S. A.2012, 109, 9287. doi: 10.1073/pnas.1202636109
25. [25]
  (25) Calvert, P. Adv. Mater. 2009, 21, 743. doi: 10.1002/adma.v21:7(25) Calvert, P. Adv. Mater. 2009, 21, 743. doi: 10.1002/adma.v21:7
26. [26]
  (26) Slaughter, B. V.; Khurshid, S. S.; Fisher, O. Z.;Khademhosseini, A.; Peppas, N. A. Adv. Mater. 2009, 21, 3307.doi: 10.1002/adma.v21:32/33(26) Slaughter, B. V.; Khurshid, S. S.; Fisher, O. Z.;Khademhosseini, A.; Peppas, N. A. Adv. Mater. 2009, 21, 3307.doi: 10.1002/adma.v21:32/33
27. [27]
  (27) Wang, Q. G.; Mynar, J. L.; Yoshida, M.; Lee, E.; Lee, M.;Okuro, K.; Kinbara, K.; Aida, T. Nature 2010, 463, 339. doi: 10.1038/nature08693(27) Wang, Q. G.; Mynar, J. L.; Yoshida, M.; Lee, E.; Lee, M.;Okuro, K.; Kinbara, K.; Aida, T. Nature 2010, 463, 339. doi: 10.1038/nature08693
28. [28]
  (28) Xu, Y.; Sheng, K.; Li, C.; Shi, G. Q. ACS Nano 2010, 4, 4324.doi: 10.1021/nn101187z(28) Xu, Y.; Sheng, K.; Li, C.; Shi, G. Q. ACS Nano 2010, 4, 4324.doi: 10.1021/nn101187z
29. [29]
  (29) Xu, Y.;Wu, Q.; Sun, Y.; Bai, H.; Shi, G. Q. ACS Nano 2010, 4,7358. doi: 10.1021/nn1027104(29) Xu, Y.;Wu, Q.; Sun, Y.; Bai, H.; Shi, G. Q. ACS Nano 2010, 4,7358. doi: 10.1021/nn1027104
30. [30]
  (30) Dai, T. Y.; Qing, X. T.; Lu, Y.; Xia, Y. Y. Polymer 2009, 50,5236. doi: 10.1016/j.polymer.2009.09.025(30) Dai, T. Y.; Qing, X. T.; Lu, Y.; Xia, Y. Y. Polymer 2009, 50,5236. doi: 10.1016/j.polymer.2009.09.025
31. [31]
  (31) Grimme, S. Angew. Chem. Int. Edit. 2008, 47, 3430. doi: 10.1002/(ISSN)1521-3773(31) Grimme, S. Angew. Chem. Int. Edit. 2008, 47, 3430. doi: 10.1002/(ISSN)1521-3773
32. [32]
  (32) Xu, C. Y.; Li, L. K.; Guo, Q. Q.; Hou, H.W.; Fan, Y. T. Inorg. Chem. Commun. 2011, 14, 1204. doi: 10.1016/j.inoche.2011.04.018(32) Xu, C. Y.; Li, L. K.; Guo, Q. Q.; Hou, H.W.; Fan, Y. T. Inorg. Chem. Commun. 2011, 14, 1204. doi: 10.1016/j.inoche.2011.04.018
33. [33]
  (33) Ghosh, S.; Rasmusson, J.; Inganäs, O. Adv. Mater. 1998, 10,1097. doi: 10.1002/(ISSN)1521-4095(33) Ghosh, S.; Rasmusson, J.; Inganäs, O. Adv. Mater. 1998, 10,1097. doi: 10.1002/(ISSN)1521-4095
34. [34]
  (34) Karlsson, R. H.; Herland, A.; Hamedi, M.;Wigenius, J. A.;Åslund, A.; Liu, X.; Fahlman, M.; Inganäs, O.; Konradsson, P.Chem. Mater. 2009, 21, 1815. doi: 10.1021/cm801512r(34) Karlsson, R. H.; Herland, A.; Hamedi, M.;Wigenius, J. A.;Åslund, A.; Liu, X.; Fahlman, M.; Inganäs, O.; Konradsson, P.Chem. Mater. 2009, 21, 1815. doi: 10.1021/cm801512r
35. [35]
  (35) Zhang, X. T.; Chang, D.W.; Liu, J. R.; Luo, Y. J. J. Mater. Chem. 2010, 20, 5080. doi: 10.1039/c0jm00050g(35) Zhang, X. T.; Chang, D.W.; Liu, J. R.; Luo, Y. J. J. Mater. Chem. 2010, 20, 5080. doi: 10.1039/c0jm00050g
36. [36]
  (36) Guiseppi-Elie, A. Biomaterials 2010, 31, 2701. doi: 10.1016/j.biomaterials.2009.12.052(36) Guiseppi-Elie, A. Biomaterials 2010, 31, 2701. doi: 10.1016/j.biomaterials.2009.12.052
37. [37]
  (37) Cutler, C. A.; Bouguettaya, M.; Kang, T. S.; Reynolds, J. R.Macromolecules 2005, 38, 3068. doi: 10.1021/ma047396+(37) Cutler, C. A.; Bouguettaya, M.; Kang, T. S.; Reynolds, J. R.Macromolecules 2005, 38, 3068. doi: 10.1021/ma047396+
38. [38]
  (38) Liu, R.; Duay, J.; Lee, S. B. ACS Nano 2010, 4, 4299. doi: 10.1021/nn1010182(38) Liu, R.; Duay, J.; Lee, S. B. ACS Nano 2010, 4, 4299. doi: 10.1021/nn1010182
39. [39]
  (39) Yamamoto, T.; Sakamaki, M.; Fukumoto, H. Synth. Met. 2003,139, 169. doi: 10.1016/S0379-6779(03)00104-8(39) Yamamoto, T.; Sakamaki, M.; Fukumoto, H. Synth. Met. 2003,139, 169. doi: 10.1016/S0379-6779(03)00104-8
40. [40]
  (40) Barsch, U.; Beck, F. Electrochimica Acta 1996, 41, 1761. doi: 10.1016/0013-4686(95)00493-9(40) Barsch, U.; Beck, F. Electrochimica Acta 1996, 41, 1761. doi: 10.1016/0013-4686(95)00493-9
41. [41]
  (41) Zotti, G.; Zecchin, S.; Schiavon, G.; Groenendaal, L. B. Chem. Mater. 2000, 12, 2996. doi: 10.1021/cm000400l(41) Zotti, G.; Zecchin, S.; Schiavon, G.; Groenendaal, L. B. Chem. Mater. 2000, 12, 2996. doi: 10.1021/cm000400l
42. [42]
  (42) Chang, X. H.; Chen, D. R.; Jiao, X. L. Polymer 2010, 51, 3801.doi: 10.1016/j.polymer.2010.06.018(42) Chang, X. H.; Chen, D. R.; Jiao, X. L. Polymer 2010, 51, 3801.doi: 10.1016/j.polymer.2010.06.018
43. [43]
  (43) Ling, S. K.; Tian, H. Y.;Wang, S. B.; Rufford, T.; Zhu, Z. H.;Buckley, C. E. J. Colloid Interface Sci. 2011, 357, 157.(43) Ling, S. K.; Tian, H. Y.;Wang, S. B.; Rufford, T.; Zhu, Z. H.;Buckley, C. E. J. Colloid Interface Sci. 2011, 357, 157.
44. [44]
  (44) Hao, G. P.; Li,W. C.;Wang, S.; Zhang, S. F.; Lu, A. H. Carbon2010, 48, 3330. doi: 10.1016/j.carbon.2010.05.011(44) Hao, G. P.; Li,W. C.;Wang, S.; Zhang, S. F.; Lu, A. H. Carbon2010, 48, 3330. doi: 10.1016/j.carbon.2010.05.011
45. [45]
  (45) Mohan, D.; Singh, K. P.; Singh, G.; Kumar, K. Ind. Eng. Chem. Res. 2002, 41, 3688. doi: 10.1021/ie010667+(45) Mohan, D.; Singh, K. P.; Singh, G.; Kumar, K. Ind. Eng. Chem. Res. 2002, 41, 3688. doi: 10.1021/ie010667+
46. [46]
  (46) Zhang, X. M.; Peng, C. S.; Xu, G. C. J. Incl. Phenom. Macrocycl. Chem. 2012, 72, 165.(46) Zhang, X. M.; Peng, C. S.; Xu, G. C. J. Incl. Phenom. Macrocycl. Chem. 2012, 72, 165.
47. [47]
  (47) Crini, G.; Badot, P. M. Prog. Polym. Sci. 2008, 33, 399. doi: 10.1016/j.progpolymsci.2007.11.001(47) Crini, G.; Badot, P. M. Prog. Polym. Sci. 2008, 33, 399. doi: 10.1016/j.progpolymsci.2007.11.001
48. [48]
  (48) Purkait, M. K.; DasGupta, S.; De, S. J. Environ. Manage. 2005,76, 135. doi: 10.1016/j.jenvman.2005.01.012(48) Purkait, M. K.; DasGupta, S.; De, S. J. Environ. Manage. 2005,76, 135. doi: 10.1016/j.jenvman.2005.01.012
49. [49]
  (49) Graciani, M. D. M.; Rodríguez, A.; Fernández, G.; Moyá, M. L.Langmuir 1997, 13, 4239. doi: 10.1021/la970291y
  (49) Graciani, M. D. M.; Rodríguez, A.; Fernández, G.; Moyá, M. L.Langmuir 1997, 13, 4239. doi: 10.1021/la970291y

扫一扫看文章

计量

PDF下载量: 604
文章访问数: 2860
HTML全文浏览量: 25

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

烷氧磺酸盐功能化的聚乙撑二氧噻吩水凝胶

English

Alkoxysulfonate-Functionalized Poly(3,4-ethylenedioxythiophene) Hydrogels

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

烷氧磺酸盐功能化的聚乙撑二氧噻吩水凝胶

English

Alkoxysulfonate-Functionalized Poly(3,4-ethylenedioxythiophene) Hydrogels

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs