有机物单层分散在相关材料制备中的应用

引用本文: 王羽, 蒋骏骢, 朱月香, 谢有畅. 有机物单层分散在相关材料制备中的应用[J]. 物理化学学报, 2012, 28(10): 2327-2335. doi: 10.3866/PKU.WHXB201207303 shu

Citation: WANG Yu, JIANG Jun-Cong, ZHU Yue-Xiang, XIE You-Chang. Applications of Monolayer-Dispersed Organic Compounds in the Preparation of Related Materials[J]. Acta Physico-Chimica Sinica, 2012, 28(10): 2327-2335. doi: 10.3866/PKU.WHXB201207303 shu

有机物单层分散在相关材料制备中的应用

基金项目:
国家自然科学基金(20773004) (20773004)

国家重点基础研究发展规划项目(973) (2011CB808702)资助 (973) (2011CB808702)

摘要:

与无机氧化物和盐类在载体表面自发单层分散相类似, 许多有机物也可以在载体表面自发单层分散.有机物在载体表面单层分散行为和分散后的存在状态与有机物分子形状和结构特点及载体表面性质和孔结构有关. 利用有机物在载体表面的单层分散, 可以设计制备具有优异性能的材料. 本文简要综述了近年来这方面研究工作取得的相关进展, 主要介绍了有机物单层分散在碳/氧化物复合物、氧化物和薄壁中孔碳材料的制备和织构调控方面的一些应用实例. 单层分散的有机物热分解后可在载体表面形成均匀的薄碳层, 以无机多孔氧化物为载体可制备出包覆均匀碳薄层的碳/氧化物复合物, 这种碳/氧化物复合物在染料吸附、催化剂载体和光催化方面显现出好的性能. 以溶胶-凝胶法制备氧化物时, 分散的有机物可以隔离溶胶颗粒, 从而制备出高比表面积的氧化物并可对孔容进行调控, 以此方法制备的γ-氧化铝比表面积可达506 m²·g^-1. 在惰性气氛中加热上述碳/氧化物复合物, 碳层可抑制氧化物的相变; 而在氧气中, 碳层燃烧发热会促进相变, 由此可快速制备超细α-氧化铝. 包覆均匀碳薄层的氧化物载体对碳起支撑作用, 在将氧化物溶解去除后, 可便捷制得高比表面积、大孔容、高中孔率的薄壁中孔碳材料, 碳材料的形貌、孔径分布等可通过选用不同织构的氧化物载体进行调控.

关键词:

English

Applications of Monolayer-Dispersed Organic Compounds in the Preparation of Related Materials

1.
Beijing National Laboratory for Molecular Sciences, State Key Laboratory for Structural Chemistry of Unstable and Stable Species, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China
Received Date: 28 June 2012
Available Online: 26 September 2012
Fund Project:
国家自然科学基金(20773004)

国家重点基础研究发展规划项目(973) (2011CB808702)资助

Abstract:

Many organic compounds will spontaneously disperse on the surface of a solid support to form monolayers, in a manner similar to that of inorganic salts and oxides, and numerous materials with useful properties can be designed and prepared based on this phenomenon. The dispersion behavior and orientation of organic compounds in monolayers depend not only on the molecular structure of organic compounds but also on the surface features and pore structure of the support. This short review summarizes the applications of monolayer-dispersed organic compounds in the preparation and texture control of related materials, including carbon/oxide composites, various other oxides, and mesoporous carbon with thin pore walls. Pyrolysis of organic monolayers can be used to prepare carbon/oxide composites with a uniformly thin carbon layer for use as photocatalysts, catalyst supports, and adsorbents for dyes. During the sol-gel preparation of porous oxides, organic monolayers can also prevent the aggregation of sol particles, thus producing oxides with high specific surface areas and adjustable pore volumes; γ-Al₂O₃ with a specific surface area as high as 506 m²·g^-1 can be prepared in this manner. During calcining under an inert atmosphere, the carbon layer in the aforementioned carbon/oxide composites can significantly inhibit the phase transformation of oxides. Calcining carbon/γ-Al₂O₃ in oxygen at high temperatures, however, results in a rapid γ to α phase transformation. The oxides in these composites can also act as templates for the preparation of carbon materials. Dissolving the support oxides is a convenient method for the preparation of mesoporous carbon materials with high specific surface areas, large pore volumes, high mesopore ratios, and thin pore walls. The morphology and size distribution of pores in these carbon materials can be controlled by choosing oxides with different textures.

Key words:

1. [1]
  
  (1) Xie, Y. C.; Tang, Y. Q. Adv. Catal. 1990, 37, 1. doi: 10.1016/S0360-0564(08)60362-4
  (1) Xie, Y. C.; Tang, Y. Q. Adv. Catal. 1990, 37, 1. doi: 10.1016/S0360-0564(08)60362-4
2. [2]
  (2) Wang, C. M.; Zhao, B. Y.; Xie, Y. C. Chin. J. Catal. 2003, 14 (6),475. [王春明, 赵璧英, 谢有畅. 催化学报, 2003, 14 (6), 475.](2) Wang, C. M.; Zhao, B. Y.; Xie, Y. C. Chin. J. Catal. 2003, 14 (6),475. [王春明, 赵璧英, 谢有畅. 催化学报, 2003, 14 (6), 475.]
3. [3]
  (3) Xie, Y. C.; Zhu, Y. X.; Zhao, B. Y.; Tang, Y. Q. Stud. Surf. Sci. Catal. 1998, 118, 441. doi: 10.1016/S0167-2991(98)80210-3(3) Xie, Y. C.; Zhu, Y. X.; Zhao, B. Y.; Tang, Y. Q. Stud. Surf. Sci. Catal. 1998, 118, 441. doi: 10.1016/S0167-2991(98)80210-3
4. [4]
  (4) Wang, X. Y. Studies on Monolayer Dispersion of OrganicCompounds on Supports and the Sampling Techniques inDRIFT Measurement. Ph. D. Dissertation, Peking University,Beijing, 1999. [王小勇. 有机物在载体表面自发单层分散和漫反射红外表征中合理化制样的研究[D]. 北京: 北京大学,1999.](4) Wang, X. Y. Studies on Monolayer Dispersion of OrganicCompounds on Supports and the Sampling Techniques inDRIFT Measurement. Ph. D. Dissertation, Peking University,Beijing, 1999. [王小勇. 有机物在载体表面自发单层分散和漫反射红外表征中合理化制样的研究[D]. 北京: 北京大学,1999.]
5. [5]
  (5) Xie, Y. C.; Zhang, J. P.; Qiu, J. G.; Tong, X. Z.; Fu, J. P.; Yang,G.; Yan, H. J.; Tang, Y. Q. Adsorption 1996, 3, 27.(5) Xie, Y. C.; Zhang, J. P.; Qiu, J. G.; Tong, X. Z.; Fu, J. P.; Yang,G.; Yan, H. J.; Tang, Y. Q. Adsorption 1996, 3, 27.
6. [6]
  (6) Xie, Y. C.; Zhang, J. P.; Tong, X. Z.; Pan, X. M.; Cai, X. H.;Yang, G.; Tang, Y. Q. Chem. J. Chin. Univ. 1997, 18, 1159. [谢有畅, 张佳平, 童显忠, 潘晓民, 蔡小海, 杨戈, 唐有祺. 高等学校化学学报, 1997, 18, 1159.](6) Xie, Y. C.; Zhang, J. P.; Tong, X. Z.; Pan, X. M.; Cai, X. H.;Yang, G.; Tang, Y. Q. Chem. J. Chin. Univ. 1997, 18, 1159. [谢有畅, 张佳平, 童显忠, 潘晓民, 蔡小海, 杨戈, 唐有祺. 高等学校化学学报, 1997, 18, 1159.]
7. [7]
  (7) Xie, Y. C.; Zhang, J.; Geng, Y.; Tang,W.; Tong, X. Z. LargeScale CO Separation by VPSA Using CuCl/zeolite Adsorbent,In Adsorption, 4th Pacific Basin Conference on AdsorptionScience and Technology, Tianjin, China, May 22-26, 2006;Zhou, L. Ed.;World Scientific, 2006; pp 245-252.(7) Xie, Y. C.; Zhang, J.; Geng, Y.; Tang,W.; Tong, X. Z. LargeScale CO Separation by VPSA Using CuCl/zeolite Adsorbent,In Adsorption, 4th Pacific Basin Conference on AdsorptionScience and Technology, Tianjin, China, May 22-26, 2006;Zhou, L. Ed.;World Scientific, 2006; pp 245-252.
8. [8]
  (8) Wang, X.Y.;Wang, M.; Zhao, B.Y.; Xie,Y. C. Acta Phys. -Chim. Sin. 1998, 14 (10), 869. [王小勇, 王敏, 赵璧英, 谢有畅.物理化学学报, 1998, 14 (10), 869.] doi: 10.3866/PKU.WHXB19981002(8) Wang, X.Y.;Wang, M.; Zhao, B.Y.; Xie,Y. C. Acta Phys. -Chim. Sin. 1998, 14 (10), 869. [王小勇, 王敏, 赵璧英, 谢有畅.物理化学学报, 1998, 14 (10), 869.] doi: 10.3866/PKU.WHXB19981002
9. [9]
  (9) Wang, X. Y.; Zhao, B. Y.; Xie, Y. C. Acta Chim. Sin. 2000, 58 (7), 759. [王小勇, 赵璧英, 谢有畅. 化学学报, 2000, 58 (7),759.](9) Wang, X. Y.; Zhao, B. Y.; Xie, Y. C. Acta Chim. Sin. 2000, 58 (7), 759. [王小勇, 赵璧英, 谢有畅. 化学学报, 2000, 58 (7),759.]
10. [10]
  (10) Zhu, Y. X.; Pan, X. M.; Xie, Y. C. Acta Phys. -Chim. Sin. 1999,15 (9), 830. [朱月香, 潘晓民, 谢有畅. 物理化学学报, 1999,15 (9), 830.] doi: 10.3866/PKU.WHXB19990911(10) Zhu, Y. X.; Pan, X. M.; Xie, Y. C. Acta Phys. -Chim. Sin. 1999,15 (9), 830. [朱月香, 潘晓民, 谢有畅. 物理化学学报, 1999,15 (9), 830.] doi: 10.3866/PKU.WHXB19990911
11. [11]
  (11) Lin, L.; Lin,W.;Wang, P.; Zhu, Y. X.; Zhao, B. Y.; Xie, Y. C.Acta Phys. -Chim. Sin. 2004, 20, 1179. [林莉, 林伟,王培, 朱月香, 赵璧英, 谢有畅. 物理化学学报, 2004, 20,1179.] doi: 10.3866/PKU.WHXB20041002(11) Lin, L.; Lin,W.;Wang, P.; Zhu, Y. X.; Zhao, B. Y.; Xie, Y. C.Acta Phys. -Chim. Sin. 2004, 20, 1179. [林莉, 林伟,王培, 朱月香, 赵璧英, 谢有畅. 物理化学学报, 2004, 20,1179.] doi: 10.3866/PKU.WHXB20041002
12. [12]
  (12) Lin, L.; Lin,W.; Zhu, Y. X.; Zhao, B. Y.; Xie, Y. C.; Jia, G. Q.;Li, C. Langmuir 2005, 21, 5040. doi: 10.1021/la047097d(12) Lin, L.; Lin,W.; Zhu, Y. X.; Zhao, B. Y.; Xie, Y. C.; Jia, G. Q.;Li, C. Langmuir 2005, 21, 5040. doi: 10.1021/la047097d
13. [13]
  (13) Wang, Y.; Lin, L.; Zhu, B. S.; Zhu, Y. X.; Xie, Y. C. Appl. Surf. Sci. 2008, 254, 6560. doi: 10.1016/j.apsusc.2008.04.022(13) Wang, Y.; Lin, L.; Zhu, B. S.; Zhu, Y. X.; Xie, Y. C. Appl. Surf. Sci. 2008, 254, 6560. doi: 10.1016/j.apsusc.2008.04.022
14. [14]
  (14) Lin, L.; Lin,W.; Zhu, Y. X.; Zhao, B. Y.; Xie, Y. C.; He, Y.; Zhu,Y. F. J. Mol. Catal. A: Chem. 2005, 236, 46. doi: 10.1016/j.molcata.2005.04.028(14) Lin, L.; Lin,W.; Zhu, Y. X.; Zhao, B. Y.; Xie, Y. C.; He, Y.; Zhu,Y. F. J. Mol. Catal. A: Chem. 2005, 236, 46. doi: 10.1016/j.molcata.2005.04.028
15. [15]
  (15) Lin, L. Studies on Novel Carbon/Oxide Composites. Ph. D.Dissertation, Peking University, Beijing, 2007. [林莉. 新型碳/氧化物复合物研究[D]. 北京: 北京大学, 2007.](15) Lin, L. Studies on Novel Carbon/Oxide Composites. Ph. D.Dissertation, Peking University, Beijing, 2007. [林莉. 新型碳/氧化物复合物研究[D]. 北京: 北京大学, 2007.]
16. [16]
  (16) Chen, J.; Zeng, C. F.; Zhang, L. X.; Xu, N. P. Acta Phys. -Chim. Sin. 2007, 23 (9), 1463. [陈军, 曾昌凤, 张利雄, 徐南平.物理化学学报, 2007, 23 (9), 1463.] doi: 10.3866/PKU.WHXB20070930(16) Chen, J.; Zeng, C. F.; Zhang, L. X.; Xu, N. P. Acta Phys. -Chim. Sin. 2007, 23 (9), 1463. [陈军, 曾昌凤, 张利雄, 徐南平.物理化学学报, 2007, 23 (9), 1463.] doi: 10.3866/PKU.WHXB20070930
17. [17]
  (17) Wang, C. M. Spontaneous Monolayer Dispersion of OrganicCompounds onto Supports and Its Application in the Preparationof High-Surface-Area γ-Alumina. Ph. D. Dissertation, PekingUniversity, Beijing, 2005. [王春明. 有机物在载体表面的单层分散及其在制备高比表面积氧化铝中的应用. 北京: 北京大学, 2005.](17) Wang, C. M. Spontaneous Monolayer Dispersion of OrganicCompounds onto Supports and Its Application in the Preparationof High-Surface-Area γ-Alumina. Ph. D. Dissertation, PekingUniversity, Beijing, 2005. [王春明. 有机物在载体表面的单层分散及其在制备高比表面积氧化铝中的应用. 北京: 北京大学, 2005.]
18. [18]
  (18) Jiang, D. E.; Zhao, B. Y.; Huang, H. Z.; Xie, Y. C.; Pan, G. C.;Ran, G. P.; Min, E. Z. Appl. Catal. A 2000, 192, 1. doi: 10.1016/S0926-860X(99)00327-0(18) Jiang, D. E.; Zhao, B. Y.; Huang, H. Z.; Xie, Y. C.; Pan, G. C.;Ran, G. P.; Min, E. Z. Appl. Catal. A 2000, 192, 1. doi: 10.1016/S0926-860X(99)00327-0
19. [19]
  (19) Zhu, J. F.;Wang, C. M.; Zhu, Y. X.; Zhao, B. Y.; Xie, Y. C.Chin. J. Chem. 2005, 23, 506. doi: 10.1002/(ISSN)1614-7065(19) Zhu, J. F.;Wang, C. M.; Zhu, Y. X.; Zhao, B. Y.; Xie, Y. C.Chin. J. Chem. 2005, 23, 506. doi: 10.1002/(ISSN)1614-7065
20. [20]
  (20) Rao, K. S. R.; Rao, P. K.; Masthan, S. K. Appl. Catal. 1990, 62,L19.(20) Rao, K. S. R.; Rao, P. K.; Masthan, S. K. Appl. Catal. 1990, 62,L19.
21. [21]
  (21) Reddy, G. K.; Rao, K. S. R.; Rao, P. K. Catal. Lett. 1999, 59,157. doi: 10.1023/A:1019084924525(21) Reddy, G. K.; Rao, K. S. R.; Rao, P. K. Catal. Lett. 1999, 59,157. doi: 10.1023/A:1019084924525
22. [22]
  (22) de Lecea, C. S. M.; Lineres-Solano, A.; Díaz-Auňón, J. A.;L'Argentière, P. C. Carbon 2000, 38, 157. doi: 10.1016/S0008-6223(99)00230-4(22) de Lecea, C. S. M.; Lineres-Solano, A.; Díaz-Auňón, J. A.;L'Argentière, P. C. Carbon 2000, 38, 157. doi: 10.1016/S0008-6223(99)00230-4
23. [23]
  (23) Li, H. T.; Chen, H. R.; Zhang, Y.; Gao, C. G.; Zhao, Y. X. Chin. J. Catal. 2011, 32 (1), 111. [李海涛, 陈昊然, 张因, 高春光,赵永祥. 催化学报, 2011, 32 (1), 111.](23) Li, H. T.; Chen, H. R.; Zhang, Y.; Gao, C. G.; Zhao, Y. X. Chin. J. Catal. 2011, 32 (1), 111. [李海涛, 陈昊然, 张因, 高春光,赵永祥. 催化学报, 2011, 32 (1), 111.]
24. [24]
  (24) Zheng, M. Y.; Shu, Y. Y.; Sun, J.; Zhang, T. Catal. Lett. 2008,121, 90. doi: 10.1007/s10562-007-9300-9(24) Zheng, M. Y.; Shu, Y. Y.; Sun, J.; Zhang, T. Catal. Lett. 2008,121, 90. doi: 10.1007/s10562-007-9300-9
25. [25]
  (25) Lin, B. Y.;Wang, R.; Lin, J. X.; Ni, J.;Wei, K. M. Catal. Commun. 2011, 12, 1452. doi: 10.1016/j.catcom.2011.05.029(25) Lin, B. Y.;Wang, R.; Lin, J. X.; Ni, J.;Wei, K. M. Catal. Commun. 2011, 12, 1452. doi: 10.1016/j.catcom.2011.05.029
26. [26]
  (26) He, S. B.; Sun, C. L.; Du, H. Z.; Dai, X. H.;Wang, B. Chem. Eng. J. 2008, 141, 284. doi: 10.1016/j.cej.2007.12.036(26) He, S. B.; Sun, C. L.; Du, H. Z.; Dai, X. H.;Wang, B. Chem. Eng. J. 2008, 141, 284. doi: 10.1016/j.cej.2007.12.036
27. [27]
  (27) Liu, Y.; Chen, J.; Yao, J. F.; Lu, Y.; Zhang, L. X.; Liu, X. Q.Chem. Eng. J. 2009, 148, 201. doi: 10.1016/j.cej.2009.01.010(27) Liu, Y.; Chen, J.; Yao, J. F.; Lu, Y.; Zhang, L. X.; Liu, X. Q.Chem. Eng. J. 2009, 148, 201. doi: 10.1016/j.cej.2009.01.010
28. [28]
  (28) Matos, J.; Laine, J.; Hermann, J. M.; Uzcategui, D.; Brito, J. L.Appl. Catal. B 2007, 70, 461. doi: 10.1016/j.apcatb.2005.10.040(28) Matos, J.; Laine, J.; Hermann, J. M.; Uzcategui, D.; Brito, J. L.Appl. Catal. B 2007, 70, 461. doi: 10.1016/j.apcatb.2005.10.040
29. [29]
  (29) Tsumura, T.; Kojitani, N.; Izumi, I.; Iwashita, N.; Toyada, M.;Inagaki, M. J. Mater. Chem. 2002, 12, 1391. doi: 10.1039/b201942f(29) Tsumura, T.; Kojitani, N.; Izumi, I.; Iwashita, N.; Toyada, M.;Inagaki, M. J. Mater. Chem. 2002, 12, 1391. doi: 10.1039/b201942f
30. [30]
  (30) Janus, M.; Inagaki, M.; Tryba, B.; Toyoda, M.; Morawski, A.W.Appl. Catal. B 2006, 63, 272. doi: 10.1016/j.apcatb.2005.10.005(30) Janus, M.; Inagaki, M.; Tryba, B.; Toyoda, M.; Morawski, A.W.Appl. Catal. B 2006, 63, 272. doi: 10.1016/j.apcatb.2005.10.005
31. [31]
  (31) Inagaki, M.; Kojin, F.; Tryba, B.; Toyoda, M. Carbon 2005, 43,1652. doi: 10.1016/j.carbon.2005.01.043(31) Inagaki, M.; Kojin, F.; Tryba, B.; Toyoda, M. Carbon 2005, 43,1652. doi: 10.1016/j.carbon.2005.01.043
32. [32]
  (32) Khan, S. U. M.; Al-Shahry, M.; Ingler,W. B., Jr. Science 2002,297, 2243. doi: 10.1126/science.1075035(32) Khan, S. U. M.; Al-Shahry, M.; Ingler,W. B., Jr. Science 2002,297, 2243. doi: 10.1126/science.1075035
33. [33]
  (33) Xu, C.; Killmeyer, R.; Grey, M. L.; Khan, S. U. M. Appl. Catal. B 2006, 64, 312. doi: 10.1016/j.apcatb.2005.11.008(33) Xu, C.; Killmeyer, R.; Grey, M. L.; Khan, S. U. M. Appl. Catal. B 2006, 64, 312. doi: 10.1016/j.apcatb.2005.11.008
34. [34]
  (34) Sakthivel, S.; Kisch, H. Angew. Chem. Int. Edit. 2003, 42, 4908.doi: 10.1002/(ISSN)1521-3773(34) Sakthivel, S.; Kisch, H. Angew. Chem. Int. Edit. 2003, 42, 4908.doi: 10.1002/(ISSN)1521-3773
35. [35]
  (35) Ren,W. J.; Ai, Z. H.; Jia, F. L.; Zhang, L. Z.; Fan, X. X.; Zou, Z.G. Appl. Catal. B 2007, 69, 138. doi: 10.1016/j.apcatb.2006.06.015(35) Ren,W. J.; Ai, Z. H.; Jia, F. L.; Zhang, L. Z.; Fan, X. X.; Zou, Z.G. Appl. Catal. B 2007, 69, 138. doi: 10.1016/j.apcatb.2006.06.015
36. [36]
  (36) Lin, L.; Zhou, Y.; Zhu, Y. X.; Xie, Y. C. Chin. J. Catal. 2006, 27 (1), 45. [林莉, 周毅, 朱月香, 谢有畅. 催化学报, 2006,27 (1), 45.](36) Lin, L.; Zhou, Y.; Zhu, Y. X.; Xie, Y. C. Chin. J. Catal. 2006, 27 (1), 45. [林莉, 周毅, 朱月香, 谢有畅. 催化学报, 2006,27 (1), 45.]
37. [37]
  (37) Matos, J.; Laine, J.; Hermann, J. M. Appl. Catal. B 1998, 18,281. doi: 10.1016/S0926-3373(98)00051-4(37) Matos, J.; Laine, J.; Hermann, J. M. Appl. Catal. B 1998, 18,281. doi: 10.1016/S0926-3373(98)00051-4
38. [38]
  (38) Zhao, B. Y.; Xu, X. P.; Ma, H. R.; Sun, D. H.; Gao, J. M. Catal. Lett. 1997, 45, 237. doi: 10.1023/A:1019048503124(38) Zhao, B. Y.; Xu, X. P.; Ma, H. R.; Sun, D. H.; Gao, J. M. Catal. Lett. 1997, 45, 237. doi: 10.1023/A:1019048503124
39. [39]
  (39) Gao, Y.; Zhao, H. B.; Zhao, B. Y. J. Mater. Sci. 2000, 35, 917.doi: 10.1023/A:1004702508967(39) Gao, Y.; Zhao, H. B.; Zhao, B. Y. J. Mater. Sci. 2000, 35, 917.doi: 10.1023/A:1004702508967
40. [40]
  (40) Jiang, D. E.; Pan, G. C.; Zhao, B. Y.; Ran, G. P.; Xie, Y. C.; Min,E. Z. Appl. Catal. A 2000, 201, 169. doi: 10.1016/S0926-860X(00)00437-3(40) Jiang, D. E.; Pan, G. C.; Zhao, B. Y.; Ran, G. P.; Xie, Y. C.; Min,E. Z. Appl. Catal. A 2000, 201, 169. doi: 10.1016/S0926-860X(00)00437-3
41. [41]
  (41) Zhu, Y. X.; Zhao, B. Y.; Zhou, C. J.;Wang, R. Q.; Xie, Y. C.Chin. J. Chem. 2001, 19, 131.(41) Zhu, Y. X.; Zhao, B. Y.; Zhou, C. J.;Wang, R. Q.; Xie, Y. C.Chin. J. Chem. 2001, 19, 131.
42. [42]
  (42) Mitchell, L. D.; Whitfield, P. S.; Margeson, J.; Beaudoin, J. J.J. Mater. Sci. Lett. 2002, 21 (22), 1773. doi: 10.1023/A:1020937224402(42) Mitchell, L. D.; Whitfield, P. S.; Margeson, J.; Beaudoin, J. J.J. Mater. Sci. Lett. 2002, 21 (22), 1773. doi: 10.1023/A:1020937224402
43. [43]
  (43) Wang, C. M.; Zhao, B. Y.; Zhu, Y. X.; Xie, Y. C. Chin. J. Catal.2004, 25 (5), 341. [王春明, 赵璧英, 朱月香, 谢有畅. 催化学报, 2004, 25 (5), 341.](43) Wang, C. M.; Zhao, B. Y.; Zhu, Y. X.; Xie, Y. C. Chin. J. Catal.2004, 25 (5), 341. [王春明, 赵璧英, 朱月香, 谢有畅. 催化学报, 2004, 25 (5), 341.]
44. [44]
  (44) Wang, C. M.;Wang, P.;Wang, H.; Zhao, B. Y.; Zhu, Y. X.; Xie,Y. C. Chin. J. Catal. 2005, 26 (9), 797. [王春明, 王培,王晖, 赵璧英, 朱月香, 谢有畅. 催化学报, 2005, 26 (9), 797.](44) Wang, C. M.;Wang, P.;Wang, H.; Zhao, B. Y.; Zhu, Y. X.; Xie,Y. C. Chin. J. Catal. 2005, 26 (9), 797. [王春明, 王培,王晖, 赵璧英, 朱月香, 谢有畅. 催化学报, 2005, 26 (9), 797.]
45. [45]
  (45) Yu, X. F.;Wu, N. Z.; Xie, Y. C.; Tang, Y. Q. J. Mater. Chem.2000, 10, 1629. doi: 10.1039/a909893c(45) Yu, X. F.;Wu, N. Z.; Xie, Y. C.; Tang, Y. Q. J. Mater. Chem.2000, 10, 1629. doi: 10.1039/a909893c
46. [46]
  (46) Zeng, L.;Wang, C. M.;Wei, J. Y.; Zhu, Y. X.; Xie, Y. C. Acta Phys. -Chim. Sin. 2004, 20, 251. [曾莉, 王春明, 尉继英,朱月香, 谢有畅. 物理化学学报, 2004, 20, 251.] doi: 10.3866/PKU.WHXB20040307(46) Zeng, L.;Wang, C. M.;Wei, J. Y.; Zhu, Y. X.; Xie, Y. C. Acta Phys. -Chim. Sin. 2004, 20, 251. [曾莉, 王春明, 尉继英,朱月香, 谢有畅. 物理化学学报, 2004, 20, 251.] doi: 10.3866/PKU.WHXB20040307
47. [47]
  (47) Wu, Y. C.; Yang, Y.; Li, Y.; Cui, P. Acta Phys. -Chim. Sin. 2005,21, 79. [吴玉程, 杨晔, 李勇, 崔平. 物理化学学报,2005, 21, 79.] doi: 10.3866/PKU.WHXB20050116(47) Wu, Y. C.; Yang, Y.; Li, Y.; Cui, P. Acta Phys. -Chim. Sin. 2005,21, 79. [吴玉程, 杨晔, 李勇, 崔平. 物理化学学报,2005, 21, 79.] doi: 10.3866/PKU.WHXB20050116
48. [48]
  (48) Zhang, J.; Xu, Q.; Li, M. J.; Feng, Z. C.; Li, C. J. Phys. Chem. C2009, 113, 1698. doi: 10.1021/jp808013k(48) Zhang, J.; Xu, Q.; Li, M. J.; Feng, Z. C.; Li, C. J. Phys. Chem. C2009, 113, 1698. doi: 10.1021/jp808013k
49. [49]
  (49) Guo, Y.;Wang, P.; Yu, G.;Wang, Y.; Zhu, Y. X.; Xie, Y. C. Acta Phys. -Chim. Sin. 2010, 26, 1887. [郭颖, 王培, 隗罡,王羽, 朱月香, 谢有畅. 物理化学学报, 2010, 26, 1887.] doi: 10.3866/PKU.WHXB20100712(49) Guo, Y.;Wang, P.; Yu, G.;Wang, Y.; Zhu, Y. X.; Xie, Y. C. Acta Phys. -Chim. Sin. 2010, 26, 1887. [郭颖, 王培, 隗罡,王羽, 朱月香, 谢有畅. 物理化学学报, 2010, 26, 1887.] doi: 10.3866/PKU.WHXB20100712
50. [50]
  (50) Zhang, Q. H.; Gao, L.; Guo, J. K. Appl. Catal. B 2000, 26, 207.doi: 10.1016/S0926-3373(00)00122-3(50) Zhang, Q. H.; Gao, L.; Guo, J. K. Appl. Catal. B 2000, 26, 207.doi: 10.1016/S0926-3373(00)00122-3
51. [51]
  (51) Ikeda, S.; Sugiyama, N.; Murakami, S.; Kominami, H.; Kera, Y.;Noguchi, H.; Uosaki, K.; Torimoto, T.; Ohatani, B. Phys. Chem. Chem. Phys. 2003, 5, 778.(51) Ikeda, S.; Sugiyama, N.; Murakami, S.; Kominami, H.; Kera, Y.;Noguchi, H.; Uosaki, K.; Torimoto, T.; Ohatani, B. Phys. Chem. Chem. Phys. 2003, 5, 778.
52. [52]
  (52) Zhang, J.; Li, M. J.; Feng, Z. C.; Chen, J.; Li, C. J. Phys. Chem. B 2006, 110, 927. doi: 10.1021/jp0552473(52) Zhang, J.; Li, M. J.; Feng, Z. C.; Chen, J.; Li, C. J. Phys. Chem. B 2006, 110, 927. doi: 10.1021/jp0552473
53. [53]
  (53) Wang, P.;Wang, C. M.; Lin, L.; Zhu, Y. X.; Xie, Y. C. J. Am. Ceram. Soc. 2006, 89, 2744.(53) Wang, P.;Wang, C. M.; Lin, L.; Zhu, Y. X.; Xie, Y. C. J. Am. Ceram. Soc. 2006, 89, 2744.
54. [54]
  (54) Wang, P.; Lin, L.; Zhu, Y. X.; Xie, Y. C. J. Am. Ceram. Soc.2007, 90, 402. doi: 10.1111/jace.2007.90.issue-2(54) Wang, P.; Lin, L.; Zhu, Y. X.; Xie, Y. C. J. Am. Ceram. Soc.2007, 90, 402. doi: 10.1111/jace.2007.90.issue-2
55. [55]
  (55) Wang,Y.;Yu, G.; Cai, B.; Zhu,Y. X.; Xie,Y. C. Acta Phys. -Chim. Sin. 2011, 27, 729. [王羽, 魁罡, 蔡斌, 朱月香, 谢有畅. 物理化学学报, 2011, 27, 729.] doi: 10.3866/PKU.WHXB20110321(55) Wang,Y.;Yu, G.; Cai, B.; Zhu,Y. X.; Xie,Y. C. Acta Phys. -Chim. Sin. 2011, 27, 729. [王羽, 魁罡, 蔡斌, 朱月香, 谢有畅. 物理化学学报, 2011, 27, 729.] doi: 10.3866/PKU.WHXB20110321
56. [56]
  (56) Wang, Y.; Dong, H.; Geng, L.; Yu, G.; Zhu, Y. X.; Xie, Y. C.Acta Phys. -Chim. Sin. 2012, 28, 1525. [王羽, 董会,耿靓, 隗罡, 朱月香, 谢有畅. 物理化学学报, 2012, 28,1525.] doi: 10.3866/PKU.WHXB201203271(56) Wang, Y.; Dong, H.; Geng, L.; Yu, G.; Zhu, Y. X.; Xie, Y. C.Acta Phys. -Chim. Sin. 2012, 28, 1525. [王羽, 董会,耿靓, 隗罡, 朱月香, 谢有畅. 物理化学学报, 2012, 28,1525.] doi: 10.3866/PKU.WHXB201203271
57. [57]
  (57) Wang, Y. Controllable Synthesis of Novel Mesoporous CarbonMaterials with Thin PoreWalls. Ph. D. Dissertation, PekingUniversity, Beijing, 2011. [王羽. 新型薄壁中孔碳材料的可控制备[D]. 北京: 北京大学, 2011.]
  (57) Wang, Y. Controllable Synthesis of Novel Mesoporous CarbonMaterials with Thin PoreWalls. Ph. D. Dissertation, PekingUniversity, Beijing, 2011. [王羽. 新型薄壁中孔碳材料的可控制备[D]. 北京: 北京大学, 2011.]

扫一扫看文章

计量

PDF下载量: 741
文章访问数: 2520
HTML全文浏览量: 29

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

有机物单层分散在相关材料制备中的应用

English

Applications of Monolayer-Dispersed Organic Compounds in the Preparation of Related Materials

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

有机物单层分散在相关材料制备中的应用

English

Applications of Monolayer-Dispersed Organic Compounds in the Preparation of Related Materials

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs