SO42-/SnO2-Fe2O3固体酸催化下的环酮Baeyer-Villiger氧化反应及缩合反应

引用本文: 杨志旺, 陈丽娜, 洪伟, 康瑞雪, 王佳, 贾娜, 赵磊, 马恒昌. SO₄^2-/SnO₂-Fe₂O₃固体酸催化下的环酮Baeyer-Villiger氧化反应及缩合反应[J]. 物理化学学报, doi: 10.3866/PKU.WHXB201206121 shu

Citation: YANG Zhi-Wang, CHEN Li-Na, HONG Wei, KANG Rui-Xue, WANG Jia, JIA Na, ZHAO Lei, MA Heng-Chang. Baeyer-Villiger Oxidation and Acetalization of Cyclic Ketones on SO₄^2-/SnO₂-Fe₂O₃ Solid Acid Catalysts[J]. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB201206121 shu

SO₄^2-/SnO₂-Fe₂O₃固体酸催化下的环酮Baeyer-Villiger氧化反应及缩合反应

基金项目:
国家自然科学基金(21163016, 21174114) (21163016, 21174114)

甘肃省自然科学基金(1010RJZA024) (1010RJZA024)

西北师范大学&ldquo

知识与科技创新工程项目&rdquo

(NWNU-KJCXGC-03-63)资助 (NWNU-KJCXGC-03-63)

摘要:

采用共沉淀的方法制备了不同Fe 掺杂量的SO₄^2-/SnO₂-Fe₂O₃固体超强酸催化剂. 利用傅里叶变换红外(FTIR)光谱, 粉末X射线衍射(XRD), N₂吸附-脱附实验(BET), 热重(TG)分析和扫描电镜(SEM)等方法对样品进行了表征. 考察了所得催化剂对4-叔丁基环己酮与乙二醇缩合反应的催化性能. 实验结果表明, 与未经过掺杂改性的SO₄^2-/SnO₂固体酸催化剂相比, 改性后催化剂的催化性能得到了改善. 研究了以Fe/Sn 摩尔比为0.5的SO₄^2-/SnO₂-Fe₂O₃固体酸为催化剂, 部分醛酮类化合物与乙二醇及1,2-丙二醇的缩合反应. 考察了反应时间、催化剂用量等因素对反应的影响. 同时, 将所得催化剂应用于环酮Baeyer-Villiger 氧化反应中, 催化剂表现出良好的催化活性, 且催化剂具有一定的循环使用性.

关键词:

English

Baeyer-Villiger Oxidation and Acetalization of Cyclic Ketones on SO₄^2-/SnO₂-Fe₂O₃ Solid Acid Catalysts

1.
Key Laboratory of Eco-Environment-Related Polymer Materials, Ministry of Education, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, P. R. China
Received Date: 26 March 2012
Available Online: 02 August 2012
Fund Project:
国家自然科学基金(21163016, 21174114)

甘肃省自然科学基金(1010RJZA024)

西北师范大学&ldquo

知识与科技创新工程项目&rdquo

(NWNU-KJCXGC-03-63)资助

Abstract:

Fe-doped SO₄^2-/SnO₂ (STF) solid acid catalysts with different amounts of iron were prepared via co-condensation, followed by sulfation and calcination. These materials were characterized by Fourier transform infrared (FTIR) spectroscopy, X-ray powder diffraction (XRD), N₂ adsorption-desorption analysis (BET), thermogravimetric (TG) analysis, and scanning electron microscopy (SEM). The Fe-doped catalysts exhibited more activity than undoped catalysts in acetalization reactions of 4-tert-butylcyclohexanone and diols. The catalytic acetalization of several ketones and 1,2-diols with the SO₄^2-/SnO₂-Fe₂O₃ catalysts (with the Fe/Sn molar ratio of 0.5) were studied. The influence of the reaction time and the amount of the catalysts on the acetalization were also investigated. In addition, the high performance of this Fe-modified catalyst was demonstrated in the Baeyer-Villiger oxidation of cyclic ketones. The catalyst can be recycled several times without any significant loss in catalytic activity.

Key words:

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

SO₄^2-/SnO₂-Fe₂O₃固体酸催化下的环酮Baeyer-Villiger氧化反应及缩合反应

English

Baeyer-Villiger Oxidation and Acetalization of Cyclic Ketones on SO₄^2-/SnO₂-Fe₂O₃ Solid Acid Catalysts

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