引用本文:
南延青, 俞庆森, 宗汉兴, 林瑞森. 氯苯甲酸在水-DMF混合溶剂中的电离热力学[J]. 物理化学学报,
1995, 11(01): 92-95.
doi:
10.3866/PKU.WHXB19950119
Citation: Nan Yan-Qing, Yu Qing-Sen, Zong Han-Xing, Lin Rui-Sen. Ionization Thermodynamics of Chlorobenzoic Acids in Water-DMF Mixtures at 298.15K[J]. Acta Physico-Chimica Sinica, 1995, 11(01): 92-95. doi: 10.3866/PKU.WHXB19950119
Citation: Nan Yan-Qing, Yu Qing-Sen, Zong Han-Xing, Lin Rui-Sen. Ionization Thermodynamics of Chlorobenzoic Acids in Water-DMF Mixtures at 298.15K[J]. Acta Physico-Chimica Sinica, 1995, 11(01): 92-95. doi: 10.3866/PKU.WHXB19950119
English
Ionization Thermodynamics of Chlorobenzoic Acids in Water-DMF Mixtures at 298.15K
Abstract:
The enthalpies of ionization of benzoic, o-chloro-, m-chloro-, and p-chloro- benzoic acids in water-DMF mixtures were measured at 298.15K with an LKB-2277 Bioactivity Monitor. The corresponding entropies of ionization of the above acids were calculated. The effects caused by solvent and substitutent were explained by interaction between solute and solvent.
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Key words:
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Mixed solvents
- / Benzoic acid
- / Chlorobenzoic acid
- / Ionization thermodynamics
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