引用本文:
刘文渊, 王岩, 曹红, 宋心琦. 计算机模拟动力学模型改进光化学反应量子产率的测定[J]. 物理化学学报,
1986, 2(05): 457-460.
doi:
10.3866/PKU.WHXB19860511
Citation: Liu Wenyuan, Wang yan, Cao Hong, Song Xinqi. IMPROVEMENT OF THE DETERMINATION OF QUANTUM YIELD IN PHOTOCHEMISTRY REACTION BY USING SIMULATIVE KINETIC MODEL ON COMPUTER[J]. Acta Physico-Chimica Sinica, 1986, 2(05): 457-460. doi: 10.3866/PKU.WHXB19860511
Citation: Liu Wenyuan, Wang yan, Cao Hong, Song Xinqi. IMPROVEMENT OF THE DETERMINATION OF QUANTUM YIELD IN PHOTOCHEMISTRY REACTION BY USING SIMULATIVE KINETIC MODEL ON COMPUTER[J]. Acta Physico-Chimica Sinica, 1986, 2(05): 457-460. doi: 10.3866/PKU.WHXB19860511
计算机模拟动力学模型改进光化学反应量子产率的测定
English
IMPROVEMENT OF THE DETERMINATION OF QUANTUM YIELD IN PHOTOCHEMISTRY REACTION BY USING SIMULATIVE KINETIC MODEL ON COMPUTER
Abstract:
Under ordinary conditions, azobenzene exists mainly as transisomer, and its photoisomerism is well known. In this work, We determined the quantum yield of this isomerization reaction by using simulative kinetic model on computer. We suggested a kinetic equation for azobenzene isomerization as
E=E_∞-Aexp(-Bt~σ)
In which, E and E_∞ are the absorbance of the azobenzene solution under radiation and photostatic state respectively, t is the radiation time A, B, C are emperical parameters. The kinetic equation can be solved by computer with a program written by ourselves, the values obtained were fitted to the practical data well.
...
E=E_∞-Aexp(-Bt~σ)
In which, E and E_∞ are the absorbance of the azobenzene solution under radiation and photostatic state respectively, t is the radiation time A, B, C are emperical parameters. The kinetic equation can be solved by computer with a program written by ourselves, the values obtained were fitted to the practical data well.
...
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