引用本文:
薛淑萍, 王海娟. [M(2,2'-bpy)2]2SiW12O40(M=Mn,Co;bpy=联吡啶)的合成、结构及其电催化水产氧性能[J]. 应用化学,
2013, 30(3): 305-309.
doi:
10.3724/SP.J.1095.2013.20290
Citation: XUE Shuping, WANG Haijuan. Synthesis and Structure of [M(2,2'-bpy)2]2SiW12O40(M=Mn,Co; bpy=bipyridine) and Its Electrocatalytic Oxidation of H2O to O2[J]. Chinese Journal of Applied Chemistry, 2013, 30(3): 305-309. doi: 10.3724/SP.J.1095.2013.20290
Citation: XUE Shuping, WANG Haijuan. Synthesis and Structure of [M(2,2'-bpy)2]2SiW12O40(M=Mn,Co; bpy=bipyridine) and Its Electrocatalytic Oxidation of H2O to O2[J]. Chinese Journal of Applied Chemistry, 2013, 30(3): 305-309. doi: 10.3724/SP.J.1095.2013.20290
[M(2,2'-bpy)2]2SiW12O40(M=Mn,Co;bpy=联吡啶)的合成、结构及其电催化水产氧性能
English
Synthesis and Structure of [M(2,2'-bpy)2]2SiW12O40(M=Mn,Co; bpy=bipyridine) and Its Electrocatalytic Oxidation of H2O to O2
Abstract:
Two complexes of[M(2,2'-bpy)2]2SiW12O40 (M=Mn(1) and M=Co(2)) have been synthesized under hydrothermal conditions and their structures were determined by using elemental analyses,IR,TG and single-crystal X-ray diffraction methods.The results showed that complexes 1 and 2 were isomorphic.The electrocatalytic activities of the two complexes toward the oxidation of H2O to O2 were preliminary evaluated.The result showed that only complex 1 has such electrocatalytic activity.
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Key words:
- polyoxometalate
- / Keggin structure
- / hydrothermal synthesis
- / electrocatalytic oxidation
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