Stereoselective Synthesis of 2-(4-Hydroxyphenyl)-3-hydroxymethyl-1,4-benzodioxane-6-aldehyde-The Key Intermediate of Sinaiticin

Xue Gong SHE Wen Xin GU Hua WANG Xin Fu PAN

引用本文: Xue Gong SHE,  Wen Xin GU,  Hua WANG,  Xin Fu PAN. Stereoselective Synthesis of 2-(4-Hydroxyphenyl)-3-hydroxymethyl-1,4-benzodioxane-6-aldehyde-The Key Intermediate of Sinaiticin[J]. Chinese Chemical Letters, 1999, 10(2): 107-108. shu
Citation:  Xue Gong SHE,  Wen Xin GU,  Hua WANG,  Xin Fu PAN. Stereoselective Synthesis of 2-(4-Hydroxyphenyl)-3-hydroxymethyl-1,4-benzodioxane-6-aldehyde-The Key Intermediate of Sinaiticin[J]. Chinese Chemical Letters, 1999, 10(2): 107-108. shu

Stereoselective Synthesis of 2-(4-Hydroxyphenyl)-3-hydroxymethyl-1,4-benzodioxane-6-aldehyde-The Key Intermediate of Sinaiticin

  • 基金项目:

    We are grateful to the National Natural Science Foundation of China for financial support.

摘要: 2-(4-Hydroxyphenyl)-3-hydroxymethyl-l,4-benzodioxane-6-aldehyde 8, the key intermediate of sinaiticin 10. was synthesized in 6 steps from caffeic acid 4 and 4-hydroxybenzaldehyde 1, the coupling reaction is the key step.

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  • 收稿日期:  1998-07-23
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