基于三维多孔石墨烯/含钛共轭聚合物复合多孔薄膜的柔性全固态超级电容器

引用本文: 杜惟实, 吕耀康, 蔡志威, 张诚. 基于三维多孔石墨烯/含钛共轭聚合物复合多孔薄膜的柔性全固态超级电容器[J]. 物理化学学报, 2017, 33(9): 1828-1837. doi: 10.3866/PKU.WHXB201705089 shu

Citation: DU Wei-Shi, LÜ Yao-Kang, CAI Zhi-Wei, ZHANG Cheng. Flexible All-Solid-State Supercapacitor Based on Three-Dimensional Porous Graphene/Titanium-Containing Copolymer Composite Film[J]. Acta Physico-Chimica Sinica, 2017, 33(9): 1828-1837. doi: 10.3866/PKU.WHXB201705089 shu

基于三维多孔石墨烯/含钛共轭聚合物复合多孔薄膜的柔性全固态超级电容器

1.
浙江工业大学化学工程学院, 杭州 310014;
2.
清华大学化学系, 北京 100084;
3.
浙江省食品药品检验研究院, 杭州 310051
基金项目:
国家自然科学基金（21501148）, 浙江省自然科学基金（LQ15E030002, LY15E030006）和中国博士后科学基金（2016M570075）资助项目

摘要: 采用Fe³⁺离子交联的方法制备氧化石墨烯水凝胶，经化学还原制备出一种新型的三维多孔石墨烯薄膜材料命名为rGO-Fe；通过电化学聚合法在rGO-Fe基底上进一步制备了一种三维多孔石墨烯/含钛共轭聚合物复合薄膜材料，命名为rGO-Fe/P（EDOT：P3C）-1-Ti。作为一种新型复合薄膜材料，rGO-Fe/P（EDOT：P3C）-1-Ti较rGO-Fe具有更好的抗拉伸性能，平均厚度为3 μm的rGO-Fe/P（EDOT：P3C）-1-Ti薄膜，可承受载荷拉力0.97 N，优于相同厚度的rGO-Fe薄膜（0.76N）。将rGO-Fe/P（EDOT：P3C）-1-Ti薄膜作为自支撑电极制备了柔性全固态超级电容器，表现出优良的电容性能，且在弯折状态下仍能正常工作。当电流密度为0.1 A·g^-¹时，该柔性全固态超级电容器的质量比容量为71.13·F·g^-1，面积比容量为101 mF·cm^-2，当电流密度为0.6 A·g^-¹时，其质量比容量为18.14 F·g^-1，面积比容量为25.8 mF·cm^-2。

关键词:

English

Flexible All-Solid-State Supercapacitor Based on Three-Dimensional Porous Graphene/Titanium-Containing Copolymer Composite Film

1.
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, P. R. China;
2.
Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China;
3.
Zhejiang Institute For Food and Drug Control, Hangzhou 310051, P. R. China
Received Date: 21 March 2017
Revised Date: 21 April 2017
Available Online: 08 May 2017
Fund Project:
The project was supported by the National Natural Science Foundation of China (21501148), Zhejiang Provincial Natural Science Foundation of China (LQ15E030002, LY15E030006), and China Postdoctoral Science Foundation (CPSF-2015M570075).

Abstract: A new three-dimensional (3D) porous graphene thin film named rGO-Fe was prepared through chemical reduction from Fe³⁺ ions cross-linking graphene oxide hydrogel, and a 3D porous graphene/titanium-containing conjugated polymer composite film named rGO-Fe/P(EDOT:P3C)-1-Ti was further prepared via electrochemical polymerization on the rGO-Fe substrate. As a new composite film, rGO-Fe/P(EDOT:P3C)-1-Ti film with average thickness of 3 μm can withstand the tensile load 0.97 N which is better than that of rGO-Fe (0.76 N). We compared the electrochemical properties of these film materials, and prepared self-supporting electrodes and a flexible all-solid-state supercapacitor based on rGO-Fe/P(EDOT:P3C)-1-Ti. Galvanostatic charge-discharge test results showed that the as prepared flexible supercapacitor delivered a gravimetric specific capacitance of 71.13 F·g^-1 (18.14 F·g^-1) and an area specific capacitance of 101 mF·cm^-2 (25.8 mF·cm^-²) at 0.1 A·g^-1 (0.6 A·g^-1).

Key words:

Graphene
/ Electrochemical polymerization
/ Cross-linking
/ Porous film
/ Titanium-containing conjugated polymer
/ Flexible all-solid-state supercapacitor

1. [1]
  (1) Yang, P.; Mai, W. Nano Energy 2014, 8, 274.doi: 10.1016/j.nanoen.2014.05.022
2. [2]
  (2) Chee, W. K.; Lim, H. N.; Zainal, Z.; Huang, N. M.; Harrison, I.; Andou, Y. J. Phys. Chem. C 2016, 120, 4153.doi: 10.1021/acs.jpcc.5b10187
3. [3]
  (3) Xiong, Z.; Liao, C.; Han, W.; Wang X. Adv. Mater. 2015, 27, 4469.doi: 10.1002/adma.201501983
4. [4]
  (4) Chen, D.; Tang, L.; Li, J. Chem. Soc. Rev. 2010, 39, 3157.doi: 10.1002/adma.201501983
5. [5]
  (5) Sun, Y.; Wu, Q.; Shi, G. Energ. Environ. Sci. 2011, 4, 1113.doi: 10.1039/C0EE00683A
6. [6]
  (6) He, Q.; Wu, S.; Yin, Z.; Zhang, H. Chem. Sci. 2012, 3, 1764.doi: 10.1039/c2sc20205k
7. [7]
  (7) Huang, Y.; Liang, J.; Cheng, Y. Small 2012, 8, 1805.doi: 10.1002/smll.201102635
8. [8]
  (8) Maiti, U.; Lim, J.; Lee, K.; Lee, W.; Kim, S. Adv. Mater. 2014, 26,615.doi: 10.1002/adma.201303503
9. [9]
  (9) Xu, Y.; Lin, Z.; Huang, X.; Liu, Y.; Huang, Y.; Duan, X. ACS Nano 2013, 7, 4042.doi: 10.1021/nn4000836
10. [10]
  (10) Wu, Z.; Winter, A.; Chen, L.; Sun Y.; Turchanin, A.; Feng, X.; Müllen, K. Adv. Mater. 2012, 24, 5130.doi: 10.1002/adma.201201948
11. [11]
  (11) Lee, S.; Kim, H.; Hwang, J.; Lee, W.; Kwon, J.; Bielawski, C.W.; Kim, S. O. Angew. Chem. Int. Ed. 2010, 49, 10282.doi: 10.1002/ange.201006240
12. [12]
  (12) Liu, T.; Song, W.; Fan, L. Electrochim. Acta 2015, 173, 1.doi: 10.1016/j.electacta.2015.05.041
13. [13]
  (13) Chabot, V.; Higgins, D.; Yu, A.; Xiao, X.; Chen, Z.; Zhang, J.Energy Environ. Sci. 2014, 7, 1564.doi: 10.1039/c3ee43385d
14. [14]
  (14) Liu, M.; Ma, X.; Gan, L.; Xu, Z.; Zhu, D.; Chen, L. J. Mater. Chem.A 2014, 2, 17107.doi: 10.1039/C4TA02888K
15. [15]
  (15) Miao, L.; Duan, H.; Liu, M.; Lu, W.; Zhu, D.; Chen, T.; Li, L.; Gan, L. Chem. Eng. J. 2017, 317, 651.doi: 10.1016/j.cej.2017.02.110
16. [16]
  (16) Zhu, D.; Wang, Y.; Lu, W.; Zhang, H.; Song, Z.; Luo, D.; Gan, L.; Liu, M.; Sun, D. Carbon 2017, 111, 667.doi: 10.1016/j.carbon.2016.10.016
17. [17]
  (17) Zhu, D.; Cheng, K.; Wang, Y.; Sun, D.; Gan, L.; Chen, T.; Jiang, J.; Liu, M. Electrochim. Acta 2017, 224, 17.doi: 10.1016/j.electacta.2016.12.023
18. [18]
  (18) Li, C.; Shi, G. Nanoscale 2012, 4, 5549.doi: 10.1039/C2NR31467C
19. [19]
  (19) Zhang, Y.; Gong, S.; Zhang, Q.; Ming, P.; Wan, S.; Peng J.; Jiang, L.; Chang, Q. Chem. Soc. Rev. 2016, 45, 2378.doi: 10.1039/c5cs00258c
20. [20]
  (20) Park, S.; Lee, K. S.; Bozoklu, G.; Cai, W.; Nguyen, S. T.; Ruoff, R. S. ACS Nano 2008, 2, 572. doi: 10.1021/nn700349a
21. [21]
  (21) Putz, K. W.; Compton, O. C.; Palmeri, M. J.; Nguyen, S. T.; Brinson, L. C. Adv. Funct. Mater. 2010, 20, 3322.doi: 10.1002/adfm.201000723
22. [22]
  (22) Bai, H.; Li, C.; Wang, X. L., Shi G.J. Phys. Chem. C 2011, 115, 5545.doi: 10.1021/jp1120299
23. [23]
  (23) Choi, B. G.; Park, H. S.; Park, T. J.; Yang, M.; Kim, J. S.; Jang, S.; Heo, N. S.; Lee, S. Y.; Kong, J.; Hong W. ACS Nano 2010, 4, 2910.doi: 10.1021/nn100145x
24. [24]
  (24) Lv, Y. K.; Liu, Y. Y.; Pan, Y.; Liu, G.; Chen, J.; Guo, Y.; Shen,L,; Zhang, C. Chem. J. Chin. Univ. 2017, 38, 484. [吕耀康, 刘幼幼, 潘云, 刘刚, 陈钧, 郭云, 慎炼, 张诚. 高等学校化学学报,2017, 38, 484.]doi: 10.7503/cjcu20160829
25. [25]
  (25) Li, C.; Shi, G. Q. Adv. Mater. 2014, 26, 3992.doi: 10.1002/adma.201306104
26. [26]
  (26)Krishnamoorthy, K.; Veerapandian, M.; Yun, K.; Kim, S. J. Carbon 2013, 53, 38.doi: 10.1016/j.carbon.2012.10.013
27. [27]
  (27) Lv, Y. K.; Liu, M.; Gan, L.; Cao, Y.; Chen, L.; Xiong, W.; Xu, Z.; Hao, Z.; Liu, H.; Chen L. Chem. Lett. 2011, 40, 236.doi: 10.1246/cl.2011.236
28. [28]
  (28) Shao, Y. Y.; Wang, J.; Engelhard, M.; Wang, C.; Lin, Y. J. Mater. Chem. 2010, 20, 743.doi: 10.1039/b917975e
29. [29]
  (29) Mills, P.; Sullivan, J. L. J. Phys. D: Appl. Phys. 1983, 16, 723.doi: 10.1088/0022-3727/16/5/005
30. [30]
  (30) Park, S.; Lee, K. S.; Bozoklu, G.; Cai, W.; Nguyen, S. B.; Ruoff, R. S. ACS Nano 2008, 2, 572.doi: 10.1021/nn700349a
31. [31]
  (31) Lin, X.; Shen, X.; Sun, X.; Liu, X.; Wu, Y.; Wang, Z.; Kim, J.K. ACS Appl. Mater. Interfaces 2016, 8, 2360.doi: 10.1021/acsami.5b11486.
32. [32]
  (32) Liu, R.; Xu, A. RSC Adv. 2014, 4, 40390.doi: 10.1039/c4ra08319a
33. [33]
  (33) Ming, P.; Song, Z.; Gong, S.; Zhang, Y.; Duan, J.; Zhang, Q.; Jiang, L.; Cheng, Q. J. Mater. Chem.A 2015, 3, 21194.doi: 10.1039/c5ta05742f
34. [34]
  (34) Yan, X.; Chen, J.; Yang, J.; Xue, Q.; Miele, P. ACS Appl. Mater. Interfaces 2010, 2, 2521.doi: 10.1021/am100293r

扫一扫看文章

计量

PDF下载量: 1
文章访问数: 827
HTML全文浏览量: 62

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

基于三维多孔石墨烯/含钛共轭聚合物复合多孔薄膜的柔性全固态超级电容器

English

Flexible All-Solid-State Supercapacitor Based on Three-Dimensional Porous Graphene/Titanium-Containing Copolymer Composite Film

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

基于三维多孔石墨烯/含钛共轭聚合物复合多孔薄膜的柔性全固态超级电容器

English

Flexible All-Solid-State Supercapacitor Based on Three-Dimensional Porous Graphene/Titanium-Containing Copolymer Composite Film

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs