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β-二亚胺配体支持的铝氧硼六元环化合物的合成、表征及其热稳定性研究

郝朋飞 ,  杨智 ,  马小莉 ,  李加荣

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引用本文: 郝朋飞, 杨智, 马小莉, 李加荣. β-二亚胺配体支持的铝氧硼六元环化合物的合成、表征及其热稳定性研究[J]. 无机化学学报, 2013, 29(9): 1909-1913. doi: 10.3969/j.issn.1001-4861.2013.00.296 shu
Citation:  HAO Peng-Fei, YANG Zhi, MA Xiao-Li, LI Jia-Rong. Synthesis, Characterization and Thermal Stability of the Aluminum Boroxine-Linked Compound with N-aryl Substituted β-Diketiminato Ligand[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(9): 1909-1913. doi: 10.3969/j.issn.1001-4861.2013.00.296 shu

β-二亚胺配体支持的铝氧硼六元环化合物的合成、表征及其热稳定性研究

  • 基金项目:

    国家自然科学基金(No.21001016) (No.21001016)

    北京市自然科学基金(No.2132044) (No.2132044)

    教育部新世纪优秀人才支持计划-10-0050资助项目。 

摘要: LAlH2(L=(Z)-4-[(2,6-二异丙基苯基)氨基]戊-3-烯-2-亚基-2,6-二异丙基苯胺)与2-三氟甲基苯硼酸反应,合成含铝氧硼六元环的化合物LAl[OB(2-CF3C6H4)]2(μ-O)。化合物是以铝原子为螺中心将无机环AlO3B2和有机环C3N2连在一起的独特例子。通过X射线单晶衍射测定了化合物的单晶结构,对其进行了元素分析、IR、1H NMR等表征。并通过热重分析对化合物进行了热稳定性研究。

English

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  • 收稿日期:  2013-02-16
  • 网络出版日期:  2013-05-15
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