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以烟酸为配体的铜配合物的合成、晶体结构及磁学性质

刘光祥

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引用本文: 刘光祥. 以烟酸为配体的铜配合物的合成、晶体结构及磁学性质[J]. 无机化学学报, 2013, 29(9): 1914-1920. doi: 10.3969/j.issn.1001-4861.2013.00.290 shu
Citation:  LIU Guang-Xiang. Synthesis, Crystal Structure and Magnetic Property of a Copper(Ⅱ) Coordination Polymer Constructed from Nicotinic Acid[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(9): 1914-1920. doi: 10.3969/j.issn.1001-4861.2013.00.290 shu

以烟酸为配体的铜配合物的合成、晶体结构及磁学性质

  • 基金项目:

    国家自然科学基金(No.20971004, 21271106) (No.20971004, 21271106)

    教育部科学技术重点项目(No.210102)资助项目。 (No.210102)

摘要: 以氯化铜和烟酸(Hnic)为原料,在水热条件下得到了一个配位聚合物[Cu2(nic)4(H2O)]n(1),并利用元素分析、红外光谱以及X-射线单晶洐射对其进行了表征。该晶体属单斜晶系,P21/c空间群,a=1.071 56(3) nm,b=1.958 79(6) nm,c=1.379 50(3) nm,β=104.498 (2),V=2.803 31(13) nm3,Dc=1.501 g·cm-3,Z=4,F(000)=1 280,Goof=1.014,R1=0.041 7,wR2=0.113 2。单晶结构分析显示,相邻的2个Cu(Ⅱ)离子通过2个羧基和1个水分子体桥联形成双核铜单元,双核铜单元再通过烟酸配体连接形成五连接的三维(44·66)结构的金属有机骨架。变温磁化率研究显示,双核单元内铜离子之间存在反铁磁相互作用。

English

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  • 收稿日期:  2013-01-26
  • 网络出版日期:  2013-03-30
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