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基于三核锰(Ⅲ)结构单元的二维配位聚合物的合成、结构和磁性研究

郭利芳 ,  王兆喜 ,  李明星

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引用本文: 郭利芳, 王兆喜, 李明星. 基于三核锰(Ⅲ)结构单元的二维配位聚合物的合成、结构和磁性研究[J]. 无机化学学报, 2013, 29(9): 1921-1927. doi: 10.3969/j.issn.1001-4861.2013.00.274 shu
Citation:  GUO Li-Fang, WANG Zhao-Xi, LI Ming-Xing. A Two-Dimensional Manganese(Ⅲ) Coordination Polymer Constructed from[Mn3O] Units：Synthesis, Crystal Structure and Magnetic Properties[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(9): 1921-1927. doi: 10.3969/j.issn.1001-4861.2013.00.274 shu

基于三核锰(Ⅲ)结构单元的二维配位聚合物的合成、结构和磁性研究

  • 基金项目:

    国家自然科学基金(No.20901049, 21171115) (No.20901049, 21171115)

    浙江省有机化学与皮革化工重中之重学科开放基金(No.100061200130)资助项目。 (No.100061200130)

摘要: 新合成了钠离子桥联三核锰结构单元的配位聚合物{[NaMn3ⅢO(sao)3(tfbdc)(H2O)4]·0.5H2O·2CH3CH2OH}n(1) (H2tfbdc=2, 3, 5, 6-四氟对苯二甲酸;H2sao=水杨醛肟),对其进行了元素分析、红外光谱、热重分析和单晶X-射线衍射结构分析。配合物属于三斜晶系,空间群P1。该配合物是一个由三核锰结构单元[Mn3O]构成的、钠离子和四氟对苯二甲酸桥联的二维配位聚合物。磁学性质研究表明,该配合物中锰离子之间存在着反铁磁性耦合作用。

English

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  • 收稿日期:  2013-02-01
  • 网络出版日期:  2013-05-01
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