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4, 5-二氰基咪唑构筑的锌(Ⅱ)、钴(Ⅱ)配合物的合成、晶体结构及荧光性质

胡拖平 ,  刘建锋 ,  吕旭燕 ,  肖立群 ,  宋江锋

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引用本文: 胡拖平, 刘建锋, 吕旭燕, 肖立群, 宋江锋. 4, 5-二氰基咪唑构筑的锌(Ⅱ)、钴(Ⅱ)配合物的合成、晶体结构及荧光性质[J]. 无机化学学报, 2013, 29(9): 1928-1934. doi: 10.3969/j.issn.1001-4861.2013.00.270 shu
Citation:  HU Tuo-Ping, LIU Jian-Feng, LÜ Xu-Yan, XIAO Li-Qun, SONG Jiang-Feng. Syntheses, Crystal Structures and Fluorescent Properties of Two Complexes (Zn(Ⅱ) and Co(Ⅱ)) Based on 2H-Imidazole-4, 5-dicarbonitrile[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(9): 1928-1934. doi: 10.3969/j.issn.1001-4861.2013.00.270 shu

4, 5-二氰基咪唑构筑的锌(Ⅱ)、钴(Ⅱ)配合物的合成、晶体结构及荧光性质

  • 基金项目:

    国家国际科技合作(No.2011DFA51980) (No.2011DFA51980)

    省自然科学基金(No.2011081022)资助项目。 (No.2011081022)

摘要: 以4, 5-二氰基咪唑(HIMDN)配体,用常温扩散法合成了2个新颖的金属-有机配合物{[Zn2(IMDN)4(H2O)3]·(H2O)3}n(1)和[Co(IMDN)2(H2O)2]n(2),并通过元素分析、红外分析、热重分析和X-射线单晶衍射对其进行了表征。结果表明配合物1中2个中心Zn(Ⅱ)离子的配位环境不同,一个是四配位,另一个是六配位。配合物2的中心钴(Ⅱ)离子为六配位。2个配合物都为一维链状结构,并且均通过氢键作用显示出三维结构。此外还研究了配合物1的荧光性质。

English

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  • 收稿日期:  2013-10-09
  • 网络出版日期:  2013-05-01
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