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基于四氟对苯二甲酸为配体的两个锌(Ⅱ)的配合物的合成、晶体结构和荧光性质

贾晓燕 ,  程美令 ,  刘琦 ,  洪健 ,  陈林提 ,  包金婷 ,  李占锋 ,  纪云洲

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引用本文: 贾晓燕, 程美令, 刘琦, 洪健, 陈林提, 包金婷, 李占锋, 纪云洲. 基于四氟对苯二甲酸为配体的两个锌(Ⅱ)的配合物的合成、晶体结构和荧光性质[J]. 无机化学学报, 2013, 29(9): 1999-2006. doi: 10.3969/j.issn.1001-4861.2013.00.268 shu
Citation:  JIA Xiao-Yan, CHENG Mei-Ling, LIU Qi, HONG Jian, CHEN Lin-Ti, BAO Jin-Ting, LI Zhan-Feng, JI Yun-Zhou. Synthesis, Crystal Structures and Photoluminescent Properties of Two Zinc(Ⅱ) Complexes Based on Tetrafluoroterephthalate Ligand[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(9): 1999-2006. doi: 10.3969/j.issn.1001-4861.2013.00.268 shu

基于四氟对苯二甲酸为配体的两个锌(Ⅱ)的配合物的合成、晶体结构和荧光性质

  • 基金项目:

    国家自然科学基金(No.20971060 

    南京大学配位化学国家重点实验室开放课题 

    江苏高校优势学科建设工程资助项目。 

摘要: 本文以四氟对苯二甲酸(H2tfbdc)和2,2'-联吡啶(bpy)为配体,合成了2个锌(Ⅱ)的配合物[Zn2(bpy)4(Htfbdc)2(tfbdc)] (1) and[Zn(bpy)(H2O)2(tfbdc)] (2)。并用元素分析、红外光谱、X-射线单晶衍射结构分析、热重分析等对其进行了表征。化合物1和2均属于三斜晶系,空间群为P1。配合物1和2中的锌(Ⅱ)离子分别位于畸变的八面体和畸变的三角双锥构型中。配合物1为双核结构,它们通过分子间氢键进一步形成一个二维的结构;配合物2是一个单核的两性离子,两性离子间通过氢键形成一个三维的空间网状超分子结构。考察了两种配合物的固体荧光性质。

English

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  • 收稿日期:  2012-11-16
  • 网络出版日期:  2013-03-03
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