1,3-二(4-吡啶基)丙烷Cd(Ⅱ)配合物的合成、晶体结构及发光性质研究

江晶 王冬杰 刘志鹏 汪俊龙 李星

引用本文: 江晶, 王冬杰, 刘志鹏, 汪俊龙, 李星. 1,3-二(4-吡啶基)丙烷Cd(Ⅱ)配合物的合成、晶体结构及发光性质研究[J]. 无机化学学报, 2013, 29(9): 1952-1956. doi: 10.3969/j.issn.1001-4861.2013.00.260 shu
Citation:  JIANG Jing, WANG Dong-Jie, LIU Zhi-Peng, WANG Jun-Long, LI Xing. Synthesis, Crystal Structure and Luminescent Properties of a Cd(Ⅱ) Complex with 1, 3-Di(4-pyridy)propane[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(9): 1952-1956. doi: 10.3969/j.issn.1001-4861.2013.00.260 shu

1,3-二(4-吡啶基)丙烷Cd(Ⅱ)配合物的合成、晶体结构及发光性质研究

  • 基金项目:

    浙江省自然科学基金(No.LY12B01005) (No.LY12B01005)

    上海市分子催化和功能材料重点实验室开放课题(No.2012MCIF02) (No.2012MCIF02)

    王宽诚幸福基金资助项目。 

摘要: 以1, 3-二(4-吡啶基)丙烷(L)为配体,合成了一种新的Cd(Ⅱ)配合物{[CdL2(H2O)2]·2(C7H6N5)}n(C7H6N5=5-(3-氨基苯基)四唑离子)。X射线单晶衍射结构分析表明该配合物为一维链状结构,Cd(Ⅱ)分别与4个1, 3-二(4-吡啶基)丙烷配体的4个氮原子,2个配位水分子的氧原子形成了六配位的扭曲八面体几何构型,1, 3-二(4-吡啶基)丙烷配体桥梁相邻的Cd(Ⅱ)离子形成了一维的无限延伸的链状结构,分子间通过O-H…N、N-H…N氢键作用构筑成三维超分子网络结构。

English

  • 
    1. [1] Noro S, Kitagawa S, Kondo M, et al. Angew. Chem., Int. Ed., 2000,39:2082-2085[1] Noro S, Kitagawa S, Kondo M, et al. Angew. Chem., Int. Ed., 2000,39:2082-2085

    2. [2] Zaworotko M J. Chem. Soc. Rev., 1994,23:283-288[2] Zaworotko M J. Chem. Soc. Rev., 1994,23:283-288

    3. [3] Yaghi O M, Li H, Davis C, et al. Acc. Chem. Rev., 1998,31: 474-484[3] Yaghi O M, Li H, Davis C, et al. Acc. Chem. Rev., 1998,31: 474-484

    4. [4] Janiak C. Angew. Chem., Int. Ed. Engl., 1997,36:1431-1434[4] Janiak C. Angew. Chem., Int. Ed. Engl., 1997,36:1431-1434

    5. [5] Goodgame D M L, Grachvogel D A, Williams D J. Angew. Chem., Int. Ed. Engl., 1999,38:153-156[5] Goodgame D M L, Grachvogel D A, Williams D J. Angew. Chem., Int. Ed. Engl., 1999,38:153-156

    6. [6] MacDonald J W, Whitesides G M. Chem. Rev., 1994,94:2383-2420[6] MacDonald J W, Whitesides G M. Chem. Rev., 1994,94:2383-2420

    7. [7] Eddaoudi M, Kim J, O'Keeffe M, et al. J Am. Chem. Soc., 2002,124:376-377[7] Eddaoudi M, Kim J, O'Keeffe M, et al. J Am. Chem. Soc., 2002,124:376-377

    8. [8] Tabellion F M, Seidel S R, Arif A M, et al. Angew. Chem., Int. Ed., 2001,40:1529[8] Tabellion F M, Seidel S R, Arif A M, et al. Angew. Chem., Int. Ed., 2001,40:1529

    9. [9] Pan L, Woodlock E B, Wang X, et al. Chem. Commun., 2001, 35:1762-1763[9] Pan L, Woodlock E B, Wang X, et al. Chem. Commun., 2001, 35:1762-1763

    10. [10] Tong M L, Wu Y M, Ru J, et al. Inorg. Chem., 2002,41:4846-4848[10] Tong M L, Wu Y M, Ru J, et al. Inorg. Chem., 2002,41:4846-4848

    11. [11] Sheldrick G M. SHELXL-97, Program for the Solution of Crystal Structures, University of Göttingen, Germany, 1997.[11] Sheldrick G M. SHELXL-97, Program for the Solution of Crystal Structures, University of Göttingen, Germany, 1997.

    12. [12] Sheldrick G M. SHELXL-97, Program for Refinement of Crystal Structures, University of Göttingen, Germany, 1997.[12] Sheldrick G M. SHELXL-97, Program for Refinement of Crystal Structures, University of Göttingen, Germany, 1997.

    13. [13] Zhao W W, Zhong X G, Zhang Y L, et al. Polymer, 1994,35 (15):3348-3350[13] Zhao W W, Zhong X G, Zhang Y L, et al. Polymer, 1994,35 (15):3348-3350

    14. [14] Huang Y G, Zhou Y F, Wu B L, et al. Chinese J. Struct. Chem., 2005,24:1123-1128[14] Huang Y G, Zhou Y F, Wu B L, et al. Chinese J. Struct. Chem., 2005,24:1123-1128

    15. [15] Xue X, Wang X S, Wang L Z, et al. Inorg. Chem., 2002,41: 6544-6546[15] Xue X, Wang X S, Wang L Z, et al. Inorg. Chem., 2002,41: 6544-6546

    16. [16] Tao J, Tong M L, Shi J X, et al. Chem. Commun., 2002,42: 2043-2044[16] Tao J, Tong M L, Shi J X, et al. Chem. Commun., 2002,42: 2043-2044

    17. [17] Tao J, Shi J X, Tong M L. Inorg. Chem., 2001,40:6328-6330[17] Tao J, Shi J X, Tong M L. Inorg. Chem., 2001,40:6328-6330

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  • 收稿日期:  2012-12-30
  • 网络出版日期:  2013-04-07
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