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4-氯苯氧乙酸及4,4’-bipy=4,4’-联吡啶构筑的层状锌配合物的合成、晶体结构

季宁宁 ,  张亚男 ,  石智强 ,  何国芳

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引用本文: 季宁宁, 张亚男, 石智强, 何国芳. 4-氯苯氧乙酸及4,4’-bipy=4,4’-联吡啶构筑的层状锌配合物的合成、晶体结构[J]. 无机化学学报, 2013, 29(9): 1957-1961. doi: 10.3969/j.issn.1001-4861.2013.00.230 shu
Citation:  JI Ning-Ning, ZHANG Ya-Nan, SHI Zhi-Qiang, HE Guo-Fang. Hydrothermal Synthesis, Crystal Structure and Characterization of Two-Dimension Zinc(Ⅱ) Complex Based on p-Chlorophenoxyacetic Acid and 4,4’-Bipyridine[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(9): 1957-1961. doi: 10.3969/j.issn.1001-4861.2013.00.230 shu

4-氯苯氧乙酸及4,4’-bipy=4,4’-联吡啶构筑的层状锌配合物的合成、晶体结构

  • 基金项目:

    山东省高等学校优秀青年教师国内访问学者 

    泰安市科技发展计划(No.20081009)资助项目。 (No.20081009)

摘要: 水热条件下,合成了一个新的锌(Ⅱ)配位聚合物[Zn(PCPA)2(4,4'-bipy)(H2O)]n(PCPA=4-氯苯氧乙酸,4,4'-bipy=4,4'-联吡啶),并通过元素分析、红外光谱、紫外光谱、热重分析、X-射线粉末衍射和X-射线单晶衍射对其进行了表征。锌(Ⅱ)分别与来自2个4,4'-bipy的2个氮原子、3个4-氯苯氧乙酸的3个氧原子和1个水分子中的1个氧原子配位,形成变形的八面体的配位构型。由于4-氯苯氧乙酸和4,4'-bipy的桥联作用,配合物在空间形成了二维层状结构,在此二维层状结构中存在的O-H…O氢键起到了稳定结构的作用。

English

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  • 收稿日期:  2012-10-05
  • 网络出版日期:  2013-03-21
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