S掺杂促进Fe/N/C催化剂氧还原活性的实验与理论研究

引用本文: 陈驰, 张雪, 周志有, 张新胜, 孙世刚. S掺杂促进Fe/N/C催化剂氧还原活性的实验与理论研究[J]. 物理化学学报, 2017, 33(9): 1875-1883. doi: 10.3866/PKU.WHXB201705088 shu

Citation: CHEN Chi, ZHANG Xue, ZHOU Zhi-You, ZHANG Xin-Sheng, SUN Shi-Gang. Experimental Boosting of the Oxygen Reduction Activity of an Fe/N/C Catalyst by Sulfur Doping and Density Functional Theory Calculations[J]. Acta Physico-Chimica Sinica, 2017, 33(9): 1875-1883. doi: 10.3866/PKU.WHXB201705088 shu

S掺杂促进Fe/N/C催化剂氧还原活性的实验与理论研究

陈驰 ^1, ,
张雪 ^2, ,
周志有 ^2, ,
张新胜 ^2, ,
孙世刚 ^1,

1.
华东理工大学化工学院, 化学工程联合国家重点实验室, 上海 200237;
2.
厦门大学化学化工学院, 固体表面物理化学国家重点实验室, 厦门 361005
基金项目:
国家自然科学基金（21373175和21621091）资助项目

摘要: 向Fe/N/C非贵金属催化剂中再引入S掺杂是进一步提高其氧还原催化活性的有效方法。为了探究活性提高的原因，本文以三聚氰胺-甲醛树脂为前驱体，氯化钙为模板，氯化铁为铁源，通过添加硫氰化钾（KSCN）来控制热解催化剂的S掺杂量。通过对比分析催化剂的物化性质，结合密度泛函理论（DFT）计算，分析S掺杂促进Fe/N/C催化剂氧还原活性的原因。透射电子显微镜（TEM）和N₂吸脱附等温线测试结果表明，S元素可抑制含铁纳米粒子的形成，促使形成多孔碳结构，提高比表面积。X射线光电子能谱（XPS）结果表明，适量S前驱体可实现较高的S掺杂含量，得到最优的活性，过量的S反而会导致Fe和S的掺杂量同时降低，影响活性。DFT计算结果表明在Fe-N₄大环中引入S掺杂，可增强O₂分子和中间体OOH与Fe-N₄结构中的Fe的相互作用，促进形成Fe―O键，从而导致O―O键的键能显著降低，为后续反应O―O键的断裂提供可能，促进ORR反应的进行。

关键词:

English

Experimental Boosting of the Oxygen Reduction Activity of an Fe/N/C Catalyst by Sulfur Doping and Density Functional Theory Calculations

1.
State Key Laboratory of Chemical Engineering, College of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, P. R. China;
2.
State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, P. R. China
Received Date: 30 March 2017
Revised Date: 28 April 2017
Available Online: 08 May 2017
Fund Project:
The project was supported by the NationalNatural Science Foundation of China (21373175 and 21621091).

Abstract: S doping in Fe/N/C non-precious metal catalysts is an effective approach to further improve their catalytic activity for the oxygen reduction reaction (ORR). However, the enhancement mechanism is not yet clear. Here, we synthesized an Fe/N/C catalyst using melamine-formaldehyde resin as the N and C precursors, CaCl₂ as the template, and FeCl₃ as the Fe precursor. The effects of S doping on the morphology, textural property, composition, and ORR catalytic activity were investigated by adding various amounts of KSCN as a precursor. Transmission electron microscopy (TEM) and N₂ adsorption- desorption isotherm results revealed that S prevented the growth of Fe-containing nanoparticles, and facilitated the formation of a porous structure, which increased both the catalyst surface area and mass transfer rate. X-ray photoelectron spectroscopy (XPS) results indicated that a suitable amount of S precursor led to a high doping level of S and provided the highest ORR activity. However, too much S in the precursor decreased the doping levels of both Fe and S, due to the formation of FeS, which could be completely removed by acid leaching. Density functional theory (DFT) calculations showed that the addition of S in an Fe-N₄ macrocycle could enhance the interaction strength of the Fe―O bond between the O₂ molecule or the intermediate OOHspecies and Fe in the Fe-N₄ structure, resulting in a significant decrease in the O―O bond energy, and may help in bond breaking in subsequent reactions, facilitating the ORR process.

Key words:

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沈阳化工大学材料科学与工程学院沈阳 110142

S掺杂促进Fe/N/C催化剂氧还原活性的实验与理论研究

English

Experimental Boosting of the Oxygen Reduction Activity of an Fe/N/C Catalyst by Sulfur Doping and Density Functional Theory Calculations

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

S掺杂促进Fe/N/C催化剂氧还原活性的实验与理论研究

English

Experimental Boosting of the Oxygen Reduction Activity of an Fe/N/C Catalyst by Sulfur Doping and Density Functional Theory Calculations

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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