核-壳结构氧还原反应电催化剂

引用本文: 常乔婉, 肖菲, 徐源, 邵敏华. 核-壳结构氧还原反应电催化剂[J]. 物理化学学报, 2017, 33(1): 9-17. doi: 10.3866/PKU.WHXB201609202 shu

Citation: CHANG Qiao-Wan, XIAO Fei, XU Yuan, SHAO Min-Hua. Core-Shell Electrocatalysts for Oxygen Reduction Reaction[J]. Acta Physico-Chimica Sinica, 2017, 33(1): 9-17. doi: 10.3866/PKU.WHXB201609202 shu

核-壳结构氧还原反应电催化剂

香港科技大学化学工程与生物分子工程学系, 香港

作者简介: CHANG Qiao-Wan,received a BS in Chemical Engineering from Tianjin University and BS (Double Degree) in Finance from Nankai University in 2014.She is now undertaking an MPhil degree at the Hong Kong University of Science and Technology under the supervision of Professor SHAO Min-Hua.Her main research interests are advanced materials for fuel cells;XIAO Fei,received a BS in Materials Science and Engineering from University of Science and Technology Beijing.She is now undertaking an MPhil degree at the Hong Kong University of Science and Technology under the supervision of Professor SHAO Min-Hua.Her main research interests are electrocatalysts for oxygen reduction reaction;XU Yuan,received a BS in Chemistry from South China Normal University in 2014,and a MSc in Chemical and Biomolecular Engineering from the Hong Kong University of Science and Technology in 2015.She is now a Research Assistant at the Hong Kong University of Science and Technology under the supervision of Professor SHAO Min-Hua.Her main research interests are advanced materials for fuel cells;SHAO Min-Hua,earned his BS (1999) and MS (2002) degrees in Chemistry from Xiamen University,and a PhD degree in Materials Science and Engineering from State University of New York at Stony Brook (2006).He joined UTC Power in 2007 to lead the development of advanced catalysts and supports for PEMFC and PAFC.In 2013,he joined Ford Motor Company to conduct research on lithium-ion batteries for electrified vehicles.He then joined the Hong Kong University of Science and Technology in the Department of Chemical and Biomolecular Engineering as an Associate Professor in 2014.His research mainly focuses on electrocatalysis and advanced batteries.;

基金项目:
香港特别行政区研究资助局（26206115）资助项目

摘要: 金属铂是最高效的氧还原反应催化剂而被广泛应用于质子交换膜燃料电池，但其高成本阻碍了燃料电池的商业化进程。此专论主要总结了近年来核-壳结构纳米催化剂的设计、合成及在燃料电池中的应用，讨论了多种提高核-壳结构纳米催化剂的策略包括去合金化、形貌控制、表面改性等，以及在放大制备及燃料电池测试中遇到的问题。

关键词:

English

Core-Shell Electrocatalysts for Oxygen Reduction Reaction

Department of Chemical and Biomolecular Engineering, The Hong Kong University of Science and Technology, Hong Kong, P. R. China
Received Date: 02 August 2016
Revised Date: 20 September 2016
Fund Project:
The project was supported by the Research Grant Council of the Hong Kong Special Administrative Region, China (26206115).

Abstract: The high cost of platinum in catalyst layers hinders the commercialization of proton exchange membrane fuel cells. This Account reviews recent progress on core-shell nanostructures for oxygen reduction reaction (ORR) in acidic media, which is the cathodic reaction in fuel cells. The synthesis, characterization and evaluation of different types of core-shell electrocatalysts are summarized. Various strategies to improve the performance of core-shell electrocatalysts, including dealloying, morphology control, and surface modification are presented. The issues of mass production and fuel cell performance of core-shell electrocatalysts are also discussed.

Key words:

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沈阳化工大学材料科学与工程学院沈阳 110142

核-壳结构氧还原反应电催化剂

English

Core-Shell Electrocatalysts for Oxygen Reduction Reaction

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核-壳结构氧还原反应电催化剂

English

Core-Shell Electrocatalysts for Oxygen Reduction Reaction

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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