磷酸钒钠Na3V2(PO4)3电化学储能研究进展

引用本文: 宋维鑫, 侯红帅, 纪效波. 磷酸钒钠Na₃V₂(PO₄)₃电化学储能研究进展[J]. 物理化学学报, 2017, 33(1): 103-129. doi: 10.3866/PKU.WHXB201608303 shu

Citation: SONG Wei-Xin, HOU Hong-Shuai, JI Xiao-Bo. Progress in the Investigation and Application of Na₃V₂(PO₄)₃ for Electrochemical Energy Storage[J]. Acta Physico-Chimica Sinica, 2017, 33(1): 103-129. doi: 10.3866/PKU.WHXB201608303 shu

磷酸钒钠Na₃V₂(PO₄)₃电化学储能研究进展

1.
中南大学化学化工学院, 长沙 410083;
2.
Department of Materials, Imperial College London, London SW72AZ, UK

作者简介: 宋维鑫,1990年生。2012年、2015年分别获中南大学工学学士、硕士学位。2015年获英国帝国理工学院(Imperial College Lodon)校长奖学金于材料系攻读博士学位。主要研究方向为基于功能化石墨烯的复合材料设计与电化学研究,能源存储和转化;侯红帅,1988年生,2016年博士毕业于中南大学化学化工学院,获"湖南省优秀毕业生",主要研究方向为锂/钠离子电池电极材料。现为中南大学化学化工学院副教授;纪效波,1980年生。2007年博士毕业于牛津大学,现为中南大学化学化工学院教授、博士生导师,英国皇家化学会会士,国家优秀青年基金获得者。主要研究方向为新能源材料与能源器件,主持国家自然科学基金4项。;

基金项目:
国家自然科学基金（21473258，21673298，51622406）资助项目

摘要: 锂离子电池在全球范围内的广泛应用加剧了对锂资源的消耗，其成本和原料将限制其未来发展。钠与锂具有相似物理化学性质，并且储量丰富。根据锂离子“摇椅式”电池原理，富钠离子化合物可类似富锂离子正极材料，提供可脱嵌的钠离子及结构。钠离子较锂离子大，其可逆脱嵌反应要求材料结构具有较大的容钠位与离子迁移通道。聚阴离子体磷酸钒钠Na₃V₂（PO₄）₃属于钠离子超导体（NASICON）材料，其NASICON结构骨架形成了稳定的容钠位，并且开放的三维离子迁移通道利于提高钠离子的扩散。Na₃V₂（PO₄）₃作为电池正极材料，具有理想的比容量、电压平台与循环稳定性，从而受到了广泛关注。本文首先介绍了Na₃V₂（PO₄）₃结构特点，其次结合团队已有的工作基础对Na₃V₂（PO₄）₃在钠离子电池、混合离子电池、水系电池，混合超级电容器等体系中的应用与反应机理进行了阐述；总结了基于Na₃V₂（PO₄）₃设计的复合材料与结构并探讨了Na₃V₂（PO₄）₃可能存在的问题与未来发展趋势。

关键词:

English

Progress in the Investigation and Application of Na₃V₂(PO₄)₃ for Electrochemical Energy Storage

1.
College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P. R. China;
2.
Department of Materials, Imperial College London, London SW72AZ, UK
Received Date: 23 June 2016
Revised Date: 26 August 2016
Fund Project:
The project was supported by the National Natural Science Foundation of China (21473258, 21673298, 51622406).

Abstract: Lithium ion batteries (LiBs) have been widely utilized, but the limited lithium resource restricts development and application of LiBs in large-scale energy storage. Sodium has similar physicochemical characteristics to that of lithium and is suitable to transfer between two electrodes as a cation in the "rocking chair" mechanism of LiBs. Na-containing compounds have been proposed as the electrodes to store sodium ions and provide channels for diffusion. Polyanion Na₃V₂(PO₄)₃ is a Na-super-ionic conductor (NASICON) with specific Na sites in its crystal structure and three-dimensional open channels. Recently, Na₃V₂(PO₄)₃ has been demonstrated as potential electrode material with promising properties for energy storage. In this review we systematically summarize the structure of Na₃V₂(PO₄)₃, the application and mechanism in a specific energy system, and the recent development of Na₃V₂(PO₄)₃ structure for use as electrodes. The potential problems and trends of Na₃V₂(PO₄)₃ are also discussed.

Key words:

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