对固体圆二色光谱测试方法的再认识—

引用本文: 章慧, 颜建新, 吴舒婷, 李丹, 万仕刚, 丁雷, 林丽榕. 对固体圆二色光谱测试方法的再认识——兼谈“浓度效应”[J]. 物理化学学报, 2013, 29(12): 2481-2497. doi: 10.3866/PKU.WHXB201310152 shu

Citation: ZHANG Hui, YAN Jian-Xin, WU Shu-Ting, LI Dan, WAN Shi-Gang, DING Lei, LIN Li-Rong. Further Understanding on the Measurement Methods for Solid-State Circular Dichroism Spectroscopy——Discussion on Concentration Effects[J]. Acta Physico-Chimica Sinica, 2013, 29(12): 2481-2497. doi: 10.3866/PKU.WHXB201310152 shu

对固体圆二色光谱测试方法的再认识——兼谈“浓度效应”

章慧 ^1,3, ,
颜建新 ^1, ,
吴舒婷 ^2, ,
李丹 ^1, ,
万仕刚 ^1, ,
丁雷 ^1, ,
林丽榕 ^1,

基金项目:
国家自然科学基金(21273175, 21271150, 21001026) (21273175, 21271150, 21001026)

中国科学院福建物质结构研究所结构化学国家重点实验室基金(20110006, 20130008)资助项目 (20110006, 20130008)

摘要:

对近期发展的固体圆二色(CD)光谱测试方法进行了概述、评价和比较, 着重探讨了“浓度效应”的存在使固体CD光谱失真的原因. 通过对本课题组和其他作者已报道的四种化合物的固体CD谱再测试的反思, 强调了依手性化合物的手性光谱学性质不同, 根据浓度梯度实验选择其合适测试浓度的必要性. 对固有手性的阻转异构化合物(S)-1,1'-联二萘酚(S-BINOL)进行了成膜法固体CD谱浓度梯度测试, 发现所得固体薄膜CD谱中也存在着“浓度效应”

关键词:

English

Further Understanding on the Measurement Methods for Solid-State Circular Dichroism Spectroscopy——Discussion on Concentration Effects

1.
1 Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China;
2 Department of Chemistry, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, P. R. China;
3 State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Struture of Matter, Chinese Academy of Sciences, Fuzhou 350002, P. R. China
Received Date: 19 July 2013
Available Online: 28 November 2013
Fund Project:
国家自然科学基金(21273175, 21271150, 21001026)

中国科学院福建物质结构研究所结构化学国家重点实验室基金(20110006, 20130008)资助项目

Abstract:

In this paper, the recent developments in measurement methods of solid-state circular dichroism (CD) spectroscopy were summarized and discussed, especially the effects of concentration on solid-state CD spectral distortions. By reinspection and introspection of the solid-state CD spectra of four reported compounds, concentration gradient measurements were proved to be necessary for appropriate concentrations, which are greatly related to the chiroptical properties. The thin film solid-state CD measurements of the inherently chiral atropisomer (S)-1,1'-bi-2-naphthol (S-BINOL) were carried out with concentration gradient measurements. Using this film-state technique for the first time, the results show some subtle correlations between the CD curves and the special concentrations.

Key words:

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沈阳化工大学材料科学与工程学院沈阳 110142

对固体圆二色光谱测试方法的再认识——兼谈“浓度效应”

English

Further Understanding on the Measurement Methods for Solid-State Circular Dichroism Spectroscopy——Discussion on Concentration Effects

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中国化学会秘书处

对固体圆二色光谱测试方法的再认识——兼谈“浓度效应”

English

Further Understanding on the Measurement Methods for Solid-State Circular Dichroism Spectroscopy——Discussion on Concentration Effects

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

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CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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