<em>β</em>-环糊精诱导的三氧化钼水溶性的增加

引用本文: 邵志成, 宋乐新, 滕越, 党政, 夏娟. β-环糊精诱导的三氧化钼水溶性的增加[J]. 物理化学学报, 2013, 29(03): 460-466. doi: 10.3866/PKU.WHXB201301071 shu

Citation: SHAO Zhi-Cheng, SONG Le-Xin, TENG Yue, DANG Zheng, XIA Juan. Increased Water Solubility of Molybdenum Trioxide Induced by β-Cyclodextrin[J]. Acta Physico-Chimica Sinica, 2013, 29(03): 460-466. doi: 10.3866/PKU.WHXB201301071 shu

β-环糊精诱导的三氧化钼水溶性的增加

基金项目:
国家自然科学基金(21071139) (21071139)

中国科学技术大学国家同步辐射实验室资助项目

摘要:

报道了由β-环糊精诱导的三氧化钼(MoO₃)水溶性增加及其与β-环糊精浓度的相关性, 认为MoO₃水溶性的增加是由于β-环糊精的加入导致了MoO₃在水中的沉淀-溶解平衡向溶解方向移动. 几个独立的实验证明了由β-环糊精和钼酸根离子(MoO₄^2-)组成的灰蓝色产物的形成. 结果表明: (1) X射线光电子能谱显示, 与MoO₃相比, 灰蓝色产物中钼的3d_5/2和3d_3/2电子轨道的结合能有明显的降低; (2) 在灰蓝色产物中出现了213 nm处的强吸收带(Mo＝O)和775 nm处的宽吸收峰(Mo―O); (3) 由于MoO₄^2-的影响, β-环糊精的质子有很明显的低场漂移. 总之, 我们的工作不仅明确地揭示了β-环糊精和MoO₄^2-之间的分子-离子相互作用, 同时揭示了这种相互作用在改善MoO₃物理性质上的潜在应用价值.

关键词:

English

Increased Water Solubility of Molybdenum Trioxide Induced by β-Cyclodextrin

1.
Department of Chemistry, University of Science and Technology of China, Hefei 230026, P. R. China
Received Date: 02 November 2012
Available Online: 25 February 2013
Fund Project:
国家自然科学基金(21071139)

中国科学技术大学国家同步辐射实验室资助项目

Abstract:

Increased water solubility of molybdenum trioxide (MoO₃) induced by β-cyclodextrin (CD), with solubility dependent on β-CD concentration is reported. The dynamic equilibrium established between MoO₃ precipitation and dissolution shifted towards dissolution upon the addition of aqueous β-CD, to form a bluish-grey product. This was confirmed to be of β-CD and MoO₄^2- by: (1) X-ray photoelectron spectroscopy showed decreased Mo 3d_5/2 and 3d_3/2 binding energies of the product compared with those of MoO₃; (2) a strong band at 213 nm and new broad peak near 775 nm of the product were attributed to Mo＝O and Mo―O bond absorption; (3) a downfield shift of β-CD protons due to the effect of MoO₄^2- ions. An interaction between β-CD and MoO₄^2- has been revealed and hints at the possibility of exploiting it for improving MoO₃ physical properties

Key words:

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沈阳化工大学材料科学与工程学院沈阳 110142

β-环糊精诱导的三氧化钼水溶性的增加

English

Increased Water Solubility of Molybdenum Trioxide Induced by β-Cyclodextrin

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

β-环糊精诱导的三氧化钼水溶性的增加

English

Increased Water Solubility of Molybdenum Trioxide Induced by β-Cyclodextrin

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

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