微接触印刷技术在ITO基底上快速转移Au纳米粒子图案

引用本文: 汤儆, 庞文辉, 任禾, 陈巧兰, 宋子旺, 林建航. 微接触印刷技术在ITO基底上快速转移Au纳米粒子图案[J]. 物理化学学报, 2013, 29(03): 612-618. doi: 10.3866/PKU.WHXB201212281 shu

Citation: TANG Jing, PANG Wen-Hui, Ren He, CHEN Qiao-Lan, SONG Zi-Wang, LIN Jian-Hang. Rapid Transfer of Au Nanoparticle Pattern onto ITO Substrate Using Microcontact Printing Technique[J]. Acta Physico-Chimica Sinica, 2013, 29(03): 612-618. doi: 10.3866/PKU.WHXB201212281 shu

微接触印刷技术在ITO基底上快速转移Au纳米粒子图案

汤儆 ^1, ,
庞文辉 ^1, ,
任禾 ^1, ,
陈巧兰 ^1, ,
宋子旺 ^1, ,
林建航 ^2,

基金项目:
国家自然科学基金(21173048, 21073038)资助项目 (21173048, 21073038)

摘要:

采用无氰化学镀金法在聚二甲基硅氧烷(PDMS)印章表面镀金, 通过微接触印刷技术将PDMS印章上的Au 纳米粒子(AuNPs)分别转移到氧化铟锡(ITO)透明导电膜玻璃, 修饰了(3-巯基丙基)三甲氧基硅烷(MPTMS)的ITO基底(MPTMS/ITO)和表面电镀了铜膜的ITO(Cu/ITO)表面上, 同时形成有序的结构或者图案.通过场发射扫描电镜(FE-SEM), 原子力显微镜(AFM)和显微共聚焦激光拉曼光谱仪等对实验结果进行表征.结果表明, 该转移AuNPs的方法对基底表面特性并无特殊要求, 是一种简单、快速、无污染、低成本的AuNPs转移技术, 而且转移了AuNPs的ITO基底具有表面增强拉曼光谱(SERS)活性, 有望在SERS中有所应用.

关键词:

English

Rapid Transfer of Au Nanoparticle Pattern onto ITO Substrate Using Microcontact Printing Technique

1.
1 Key Laboratory of Analysis and Detection Technology for Food Safety, Ministry of Education, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, P. R. China;
2 Instrμmental Measurement and Analysis Center, Fuzhou University, Fuzhou 350002, P. R. China
Received Date: 09 October 2012
Available Online: 25 February 2013
Fund Project:
国家自然科学基金(21173048, 21073038)资助项目

Abstract:

A poly(dimethylsiloxane) (PDMS) stamp was electrolessly plated using a cyanide-free solution. ld nanoparticles (AuNPs) were transferred from the PDMS stamp to indium tin oxide (ITO), (3- mercaptopropyl) trimethoxysilane modified ITO (MPTMS/ITO), and an ITO substrate electrodeposited with a thin copper film (Cu/ITO). AuNPs formed well-ordered structures which were characterized by field emission scanning electron microscopy (FE-SEM), atomic force microscopy (AFM), and Raman spectroscopy. Microcontact printing allowed thin AuNPs films to be directly transferred from PDMS to substrate, so is a simple, fast, cheap and environmentally-friendly technique. AuNPs patterned on the ITO substrate exhibited surface-enhanced Raman spectroscopy (SERS) activity which will be investigated in subsequent studies.

Key words:

1. [1]
  
  (1) Bratton, D.; Yang, D.; Dai, J.; Ober, C. K. Polym. Adv. Technol.2006, 17, 94.
  (1) Bratton, D.; Yang, D.; Dai, J.; Ober, C. K. Polym. Adv. Technol.2006, 17, 94.
2. [2]
  (2) Mendes, P. M.; Jacke, S.; Critchley, K.; Plaza, J.; Chen, Y.;Nikitin, K.; Palmer, R. E.; Preece, J. A.; Evans, S. D.;Fitzmaurice, D. Langmuir 2004, 20, 3766. doi: 10.1021/la049803g(2) Mendes, P. M.; Jacke, S.; Critchley, K.; Plaza, J.; Chen, Y.;Nikitin, K.; Palmer, R. E.; Preece, J. A.; Evans, S. D.;Fitzmaurice, D. Langmuir 2004, 20, 3766. doi: 10.1021/la049803g
3. [3]
  (3) Kim, S. O.; Solak, H. H.; Stoykovich, M. P.; Ferrier, N. J.; dePablo, J. J.; Nealey, P. F. Nature 2003, 424, 411. doi: 10.1038/nature01775(3) Kim, S. O.; Solak, H. H.; Stoykovich, M. P.; Ferrier, N. J.; dePablo, J. J.; Nealey, P. F. Nature 2003, 424, 411. doi: 10.1038/nature01775
4. [4]
  (4) Xia, Y.; Whitesides, G. M. Angew. Chem. Int. Edit. 1998, 37,550.(4) Xia, Y.; Whitesides, G. M. Angew. Chem. Int. Edit. 1998, 37,550.
5. [5]
  (5) Qin, D.; Xia, Y.; Whitesides, G. M. Nat. Protoc. 2010, 5, 491.doi: 10.1038/nprot.2009.234(5) Qin, D.; Xia, Y.; Whitesides, G. M. Nat. Protoc. 2010, 5, 491.doi: 10.1038/nprot.2009.234
6. [6]
  (6) Rogers, J.; Nuzzo, R. Mater. Today 2005, 8, 50.(6) Rogers, J.; Nuzzo, R. Mater. Today 2005, 8, 50.
7. [7]
  (7) Gao, H.; svami, N. N.; Deng, J.; Tan, L. S.; Sander, M. S.Langmuir 2006, 22, 8078. doi: 10.1021/la060658b(7) Gao, H.; svami, N. N.; Deng, J.; Tan, L. S.; Sander, M. S.Langmuir 2006, 22, 8078. doi: 10.1021/la060658b
8. [8]
  (8) Kolb, D. M.; Simeone, F. C. Electrochim. Acta 2005, 50, 2989.doi: 10.1016/j.electacta.2004.12.042(8) Kolb, D. M.; Simeone, F. C. Electrochim. Acta 2005, 50, 2989.doi: 10.1016/j.electacta.2004.12.042
9. [9]
  (9) Porter, L. A.; Choi, H. C.; Schmeltzer, J. M.; Ribbe, A. E.;Elliott, L. C. C.; Buriak, J. M. Nano Lett. 2002, 2, 1369. doi: 10.1021/nl025790k(9) Porter, L. A.; Choi, H. C.; Schmeltzer, J. M.; Ribbe, A. E.;Elliott, L. C. C.; Buriak, J. M. Nano Lett. 2002, 2, 1369. doi: 10.1021/nl025790k
10. [10]
  (10) Ruiz, S. A.; Chen, C. S. Soft Matter 2007, 3, 168.(10) Ruiz, S. A.; Chen, C. S. Soft Matter 2007, 3, 168.
11. [11]
  (11) Kumar, A.; Whitesides, G. M. Appl. Phys. Lett. 1993, 63, 2002.(11) Kumar, A.; Whitesides, G. M. Appl. Phys. Lett. 1993, 63, 2002.
12. [12]
  (12) Whitesides, G. M.; Ostuni, E.; Takayama, S.; Jiang, X. Y.;Ingber, D. E. Annu. Rev. Biomed. Eng. 2001, 3, 335.(12) Whitesides, G. M.; Ostuni, E.; Takayama, S.; Jiang, X. Y.;Ingber, D. E. Annu. Rev. Biomed. Eng. 2001, 3, 335.
13. [13]
  (13) Liu, J.; Ye, Q.; Yu, B.;Wang, X.; Zhou, F. Chem. Commun.2012, 48, 398.(13) Liu, J.; Ye, Q.; Yu, B.;Wang, X.; Zhou, F. Chem. Commun.2012, 48, 398.
14. [14]
  (14) Schmalenberg, K. E.; Buettner, H. M.; Uhrich, K. E.Biomaterials 2004, 25, 1851.(14) Schmalenberg, K. E.; Buettner, H. M.; Uhrich, K. E.Biomaterials 2004, 25, 1851.
15. [15]
  (15) Daniel, M. C.; Astruc, D. Chem. Rev. 2004, 104, 293.(15) Daniel, M. C.; Astruc, D. Chem. Rev. 2004, 104, 293.
16. [16]
  (16) Saha, K.; Agasti, S. S.; Kim, C.; Li, X.; Rotello, V. M. Chem.Rev. 2012, 112, 2739.(16) Saha, K.; Agasti, S. S.; Kim, C.; Li, X.; Rotello, V. M. Chem.Rev. 2012, 112, 2739.
17. [17]
  (17) Nguyen, D. T.; Kim, D. J.; Kim, K. S. Micron 2011, 42, 207.(17) Nguyen, D. T.; Kim, D. J.; Kim, K. S. Micron 2011, 42, 207.
18. [18]
  (18) Eustis, S.; El-Sayed, M. A. Chem. Soc. Rev. 2006, 35, 209.(18) Eustis, S.; El-Sayed, M. A. Chem. Soc. Rev. 2006, 35, 209.
19. [19]
  (19) Sharma, J.; Ke, Y.; Lin, C.; Chhabra, R.;Wang, Q.; Nangreave,J.; Liu, Y.; Yan, H. Angew. Chem. Int. Edit. 2008, 47, 5157.(19) Sharma, J.; Ke, Y.; Lin, C.; Chhabra, R.;Wang, Q.; Nangreave,J.; Liu, Y.; Yan, H. Angew. Chem. Int. Edit. 2008, 47, 5157.
20. [20]
  (20) Shipway, A. N.; Katz, E.;Willner, I. ChemPhysChem 2000, 1, 18.(20) Shipway, A. N.; Katz, E.;Willner, I. ChemPhysChem 2000, 1, 18.
21. [21]
  (21) Feng, X.; Meitl, M. A.; Bowen, A. M.; Huang, Y.; Nuzzo, R. G.;Rogers, J. A. Langmuir 2007, 23, 12555.(21) Feng, X.; Meitl, M. A.; Bowen, A. M.; Huang, Y.; Nuzzo, R. G.;Rogers, J. A. Langmuir 2007, 23, 12555.
22. [22]
  (22) Hidber, P. C.; Helbig,W.; Kim, E.; Whitesides, G. M. Langmuir1996, 12, 1375.(22) Hidber, P. C.; Helbig,W.; Kim, E.; Whitesides, G. M. Langmuir1996, 12, 1375.
23. [23]
  (23) Santhanam, V.; Andres, R. P. Nano Lett. 2003, 4, 41.(23) Santhanam, V.; Andres, R. P. Nano Lett. 2003, 4, 41.
24. [24]
  (24) Chien, H.W.; Kuo,W. H.;Wang, M. J.; Tsai, S.W.; Tsai,W. B.Langmuir 2012, 28, 5775.(24) Chien, H.W.; Kuo,W. H.;Wang, M. J.; Tsai, S.W.; Tsai,W. B.Langmuir 2012, 28, 5775.
25. [25]
  (25) Xue, M.; Zhang, Z.; Zhu, N.;Wang, F.; Zhao, X.; Cao, T.Langmuir 2009, 25, 4347.(25) Xue, M.; Zhang, Z.; Zhu, N.;Wang, F.; Zhao, X.; Cao, T.Langmuir 2009, 25, 4347.
26. [26]
  (26) Nie, S.; Emory, S. R. Science 1997, 275, 1102.(26) Nie, S.; Emory, S. R. Science 1997, 275, 1102.
27. [27]
  (27) Le Ru, E. C.; Etche in, P. G. Principles of Surface-EnhancedRaman Spectroscopy, 1st ed.; Elsevier Science: Great Britain,2008; pp 367-385.(27) Le Ru, E. C.; Etche in, P. G. Principles of Surface-EnhancedRaman Spectroscopy, 1st ed.; Elsevier Science: Great Britain,2008; pp 367-385.
28. [28]
  (28) Bai, H. J.; Shao, M. L.; u, H. L.; Xu, J. J.; Chen, H. Y.Langmuir 2009, 25, 10402.(28) Bai, H. J.; Shao, M. L.; u, H. L.; Xu, J. J.; Chen, H. Y.Langmuir 2009, 25, 10402.
29. [29]
  (29) u, H. L.; Xu, J. J.; Xia, X. H.; Chen, H. Y. ACS Appl. Mater.Interfaces 2010, 2, 1324.(29) u, H. L.; Xu, J. J.; Xia, X. H.; Chen, H. Y. ACS Appl. Mater.Interfaces 2010, 2, 1324.
30. [30]
  (30) Wu, J.; Bai, H. J.; Zhang, X. B.; Xu, J. J.; Chen, H. Y. Langmuir2009, 26, 1191.(30) Wu, J.; Bai, H. J.; Zhang, X. B.; Xu, J. J.; Chen, H. Y. Langmuir2009, 26, 1191.
31. [31]
  (31) Tang, J.; Tian, X. C.; Zhou, F. Q.; Liu, Y. Q.; Lin, J. H. ActaPhys. -Chim. Sin. 2011, 27, 641. [汤儆, 田晓春, 周富庆,刘跃强, 林建航. 物理化学学报, 2011, 27, 641]. doi: 10.3866/PKU.WHXB20110322(31) Tang, J.; Tian, X. C.; Zhou, F. Q.; Liu, Y. Q.; Lin, J. H. ActaPhys. -Chim. Sin. 2011, 27, 641. [汤儆, 田晓春, 周富庆,刘跃强, 林建航. 物理化学学报, 2011, 27, 641]. doi: 10.3866/PKU.WHXB20110322
32. [32]
  (32) Tang, J.; Tian, X. C.; Pang,W. H.; Liu, Y. Q.; Lin, J. H.Electrochim. Acta 2012, 81, 8.(32) Tang, J.; Tian, X. C.; Pang,W. H.; Liu, Y. Q.; Lin, J. H.Electrochim. Acta 2012, 81, 8.
33. [33]
  (33) Ballarin, B.; Cassani, M. C.; Scavetta, E.; Tonelli, D.Electrochim. Acta 2008, 53, 8034.(33) Ballarin, B.; Cassani, M. C.; Scavetta, E.; Tonelli, D.Electrochim. Acta 2008, 53, 8034.
34. [34]
  (34) Wang, H.; Huang, Y.; Tan, Z.; Hu, X. Anal. Chim. Acta 2004,526, 13.(34) Wang, H.; Huang, Y.; Tan, Z.; Hu, X. Anal. Chim. Acta 2004,526, 13.
35. [35]
  (35) Huang, Y. F.;Wu, D. Y.; Zhu, H. P.; Zhao, L. B.; Liu, G. K.;Ren, B.; Tian, Z. Q. Phys. Chem. Chem. Phys. 2012, 14, 8485.(35) Huang, Y. F.;Wu, D. Y.; Zhu, H. P.; Zhao, L. B.; Liu, G. K.;Ren, B.; Tian, Z. Q. Phys. Chem. Chem. Phys. 2012, 14, 8485.
36. [36]
  (36) Osawa, M.; Matsuda, N.; Yoshii, K.; Uchida, I. J. Phys. Chem.1994, 98, 12702.(36) Osawa, M.; Matsuda, N.; Yoshii, K.; Uchida, I. J. Phys. Chem.1994, 98, 12702.
37. [37]
  (37) Zong, S.;Wang, Z.; Yang, J.; Cui, Y. Anal. Chem. 2011, 83,4178.
  (37) Zong, S.;Wang, Z.; Yang, J.; Cui, Y. Anal. Chem. 2011, 83,4178.

扫一扫看文章

计量

PDF下载量: 1337
文章访问数: 1950
HTML全文浏览量: 88

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

微接触印刷技术在ITO基底上快速转移Au纳米粒子图案

English

Rapid Transfer of Au Nanoparticle Pattern onto ITO Substrate Using Microcontact Printing Technique

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

微接触印刷技术在ITO基底上快速转移Au纳米粒子图案

English

Rapid Transfer of Au Nanoparticle Pattern onto ITO Substrate Using Microcontact Printing Technique

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs