pH值对金莲花染料敏化太阳能电池性能的影响

引用本文: 杨桂军, 王棽睿, 张永昌, 王刚, 陈慧媛, 南辉, 申何萍, 林红. pH值对金莲花染料敏化太阳能电池性能的影响[J]. 物理化学学报, 2013, 29(03): 539-545. doi: 10.3866/PKU.WHXB201212254 shu

Citation: YANG Gui-Jun, WANG Shen-Rui, ZHANG Yong-Chang, WANG Gang, CHEN Hui-Yuan, NAN Hui, LIN Hong, Effect of pH Values on Performance of Trollius Chinensis Pigment Sensitized Solar Cells[J]. Acta Physico-Chimica Sinica, 2013, 29(03): 539-545. doi: 10.3866/PKU.WHXB201212254 shu

pH值对金莲花染料敏化太阳能电池性能的影响

杨桂军 ^1, ,
王棽睿 ^2, ,
张永昌 ^3, ,
王刚 ^1, ,
陈慧媛 ^1, ,
南辉 ^1, ,
申何萍 ^3, ,
林红 ^{1,3,
,}

通讯作者: 林红,

基金项目:
青海省昆仑学者计划

青海省科技厅三江源项目(2010-N-S03) (2010-N-S03)

青海省科技厅国际合作项目(2011-H-802)资助 (2011-H-802)

摘要:

首先从高原金莲花中提取天然染料, 通过紫外-可见(UV-Vis)吸收光谱和傅里叶变换红外(FTIR)吸收光谱确定其主要成分为花色苷. 调节色素溶液的pH值, 组装染料敏化太阳能电池(DSCs)并进行光电性能测试.研究发现, 随着pH值的升高, 电池的开路电压逐渐升高, 但是短路电流密度却先升高后降低. 分析认为这是由于在不同pH值下, 花色苷的结构会发生转换造成的. 在pH=5时, 该天然染料敏化太阳能电池的光电转换效率最高, 达到0.292%.

关键词:

English

Effect of pH Values on Performance of Trollius Chinensis Pigment Sensitized Solar Cells

1.
1 Collage of Chemical Engineering, Qinghai University, Xining, Qinghai 810016, P. R. China;
2 Collage of Material, Beijing University of Technology, Beijing 100081, P. R. China;
3 State Key Laboratory of New Ceramics & Fine Processing, Department of Material Science and Engineering, Tsinghua University, Beijing 100084,P. R. China

Corresponding author: ,

Received Date: 09 October 2012
Available Online: 25 February 2013
Fund Project:
青海省昆仑学者计划

青海省科技厅三江源项目(2010-N-S03)

青海省科技厅国际合作项目(2011-H-802)资助

Abstract:

Trollius chinensis pigment was extracted, and ultraviolet-visible (UV-Vis) absorption and Fourier transform infrared (FTIR) spectroscopy confirmed that anthocyanin compounds were the main components. Dye sensitized solar cells (DSCs) were sensitized from the natural pigments dissolved in different pH solutions. Open-circuit voltage increased with increasing pH,while short-circuit current density first increased and then decreased, attributed to an anthocyanin structural change with pH value. The highest observed power conversion efficiency was 0.292% at pH=5.

Key words:

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

pH值对金莲花染料敏化太阳能电池性能的影响

通讯作者: 林红,

English

Effect of pH Values on Performance of Trollius Chinensis Pigment Sensitized Solar Cells

Corresponding author: ,

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

pH值对金莲花染料敏化太阳能电池性能的影响

通讯作者: 林红,

English

Effect of pH Values on Performance of Trollius Chinensis Pigment Sensitized Solar Cells

Corresponding author: ,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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