硫化亚铜对电极在量子点敏化太阳电池中的应用

引用本文: 朱俊, 余学超, 王时茂, 董伟伟, 胡林华, 方晓东, 戴松元. 硫化亚铜对电极在量子点敏化太阳电池中的应用[J]. 物理化学学报, 2013, 29(03): 533-538. doi: 10.3866/PKU.WHXB201212124 shu

Citation: ZHU Jun, YU Xue-Chao, WANG Shi-Mao, DONG Wei-Wei, HU Lin-Hua, FANG Xiao-Dong, DAI Song-Yuan. Application of Cu₂S Counter Electrode in Quantum Dot-Sensitized Solar Cells[J]. Acta Physico-Chimica Sinica, 2013, 29(03): 533-538. doi: 10.3866/PKU.WHXB201212124 shu

硫化亚铜对电极在量子点敏化太阳电池中的应用

基金项目:
国家重点基础研究发展计划(973) (2011CBA00700) (973) (2011CBA00700)

国家高技术研究发展计划(863) (2011AA050527) (863) (2011AA050527)

国家自然科学基金(21003130, 21103197, 21173227, 21173228)资助项目 (21003130, 21103197, 21173227, 21173228)

摘要:

报道了一种基于硫族金属复合物N₄H₉Cu₇S₄前驱体溶液制备硫化亚铜对电极的新方法. 分别制备了TiO₂纳米颗粒多孔薄膜和TiO₂纳米棒阵列结构的光阳极, 并在此基础上研究了基于硫化亚铜对电极的CdS/CdSe量子点敏化太阳电池的光电性能, 同时结合电化学阻抗技术考察了硫化亚铜对电极的催化性能. 结果表明: 与铂电极相比, 本方法制备的硫化亚铜电极对多硫电解质具有更高的催化活性, 所组装的CdS/CdSe量子点敏化太阳电池具有更优的光伏性能.

关键词:

English

Application of Cu₂S Counter Electrode in Quantum Dot-Sensitized Solar Cells

1.
1 Key Laboratory of Novel Thin Film Solar Cells, hinese Academy of Sciences, Hefei, 230031, P. R. China;
2 Institute of Plasma Physics, hinese Academy of Sciences, Hefei, 230031, P. R. China;
3 Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei, 230031, P. R. China
Received Date: 09 October 2012
Available Online: 25 February 2013
Fund Project:
国家重点基础研究发展计划(973) (2011CBA00700)

国家高技术研究发展计划(863) (2011AA050527)

国家自然科学基金(21003130, 21103197, 21173227, 21173228)资助项目

Abstract:

Cu₂S counter electrodes were prepared from the metal chalcogenide complex precursor using a novel method. A porous TiO₂ nanoparticle film and TiO₂ nanorod array photoanode were also fabricated. The corresponding CdS/CdSe-sensitized solar cells with the Cu₂S counter electrode were assembled and their photovoltaic performances were studied. The catalytic performance of the Cu₂S counter electrodes was investigated using electrochemical impedance spectroscopy. Compared with a platinum counter electrode, the Cu₂S one exhibited higher catalytic activity and better photovoltaic performance in quantum dot-sensitized solar cells.

Key words:

1. [1]
  
  (1) Semonin, O.; Luther, J. M.; Choi, S.; Chen, H. Y.; Gao, J.;Nozik, A. J.; Beard, M. C. Science 2011, 334, 1530. doi: 10.1126/science.1209845
  (1) Semonin, O.; Luther, J. M.; Choi, S.; Chen, H. Y.; Gao, J.;Nozik, A. J.; Beard, M. C. Science 2011, 334, 1530. doi: 10.1126/science.1209845
2. [2]
  (2) Mora-Serö, I.; Bisquert, J. J. Phys. Chem. Lett. 2010, 1, 3046.doi: 10.1021/jz100863b(2) Mora-Serö, I.; Bisquert, J. J. Phys. Chem. Lett. 2010, 1, 3046.doi: 10.1021/jz100863b
3. [3]
  (3) Rühle, S.; Shalom, M.; Zaban, A. ChemPhysChem 2010, 11,2290. doi: 10.1002/cphc.201000069(3) Rühle, S.; Shalom, M.; Zaban, A. ChemPhysChem 2010, 11,2290. doi: 10.1002/cphc.201000069
4. [4]
  (4) Hetsch, F.; Xu, X.;Wang, H.;Wang, H.; Kershaw, S.; Rogach,A. L. J. Phys. Chem. Lett. 2011, 2, 1879. doi: 10.1021/jz200802j(4) Hetsch, F.; Xu, X.;Wang, H.;Wang, H.; Kershaw, S.; Rogach,A. L. J. Phys. Chem. Lett. 2011, 2, 1879. doi: 10.1021/jz200802j
5. [5]
  (5) Shi, J. F.; Fan, Y.; Xu, X. Q.; Xu, G.; Chen, L. H. ActaPhys. -Chim. Sin. 2012, 28 (4), 857. [史继富, 樊晔, 徐雪青, 徐刚, 陈丽华. 物理化学学报, 2012, 28 (4), 857.] doi: 10.3866/PKU.WHXB201202204(5) Shi, J. F.; Fan, Y.; Xu, X. Q.; Xu, G.; Chen, L. H. ActaPhys. -Chim. Sin. 2012, 28 (4), 857. [史继富, 樊晔, 徐雪青, 徐刚, 陈丽华. 物理化学学报, 2012, 28 (4), 857.] doi: 10.3866/PKU.WHXB201202204
6. [6]
  (6) Yu, X. Y.; Liao, J. Y.; Qiu, K. Q.; Kuang, D. B.; Su, C. Y. ACSNano 2011, 5, 9494. doi: 10.1021/nn203375g(6) Yu, X. Y.; Liao, J. Y.; Qiu, K. Q.; Kuang, D. B.; Su, C. Y. ACSNano 2011, 5, 9494. doi: 10.1021/nn203375g
7. [7]
  (7) Zhang, Q. B.; Feng, Z. F.; Han, N. N.; Lin, L. L.; Zhou, J. Z.;Lin, Z. H. Acta Phys. -Chim. Sin. 2010, 26 (11), 2927. [张桥保, 冯增芳, 韩楠楠, 林玲玲, 周剑章, 林仲华. 物理化学学报,2010, 26 (11), 2927.] doi: 10.3866/PKU.WHXB20101113(7) Zhang, Q. B.; Feng, Z. F.; Han, N. N.; Lin, L. L.; Zhou, J. Z.;Lin, Z. H. Acta Phys. -Chim. Sin. 2010, 26 (11), 2927. [张桥保, 冯增芳, 韩楠楠, 林玲玲, 周剑章, 林仲华. 物理化学学报,2010, 26 (11), 2927.] doi: 10.3866/PKU.WHXB20101113
8. [8]
  (8) Xu, X. Q.; Xu, G. Sci. Sin. Chim. 2011, 41 (1), 37. [徐雪青,徐刚. 中国科学: 化学, 2011, 41 (1), 37.] doi: 10.1007/s11426-010-4170-1(8) Xu, X. Q.; Xu, G. Sci. Sin. Chim. 2011, 41 (1), 37. [徐雪青,徐刚. 中国科学: 化学, 2011, 41 (1), 37.] doi: 10.1007/s11426-010-4170-1
9. [9]
  (9) Jovanovski, V.; nzález-Pedro, V.; Giménez, S.; Azaceta, E.;Cabañero, G.; Grande, H.; Tena-Zaera, R.; Mora-Seró, I.;Bisquert, J. J. Am. Chem. Soc. 2011, 133, 20156. doi: 10.1021/ja2096865(9) Jovanovski, V.; nzález-Pedro, V.; Giménez, S.; Azaceta, E.;Cabañero, G.; Grande, H.; Tena-Zaera, R.; Mora-Seró, I.;Bisquert, J. J. Am. Chem. Soc. 2011, 133, 20156. doi: 10.1021/ja2096865
10. [10]
  (10) Hagfeldt, A.; Boschloo, G.; Sun, L.; Kloo, L.; Pettersson, H.Chem. Rev. 2010, 110, 6595. doi: 1021/cr900356p(10) Hagfeldt, A.; Boschloo, G.; Sun, L.; Kloo, L.; Pettersson, H.Chem. Rev. 2010, 110, 6595. doi: 1021/cr900356p
11. [11]
  (11) Hodes, G.; Manassen, J.; Cahen, D. J. Electrochem. Soc. 1980,127, 544. doi: 10.1149/1.2129709(11) Hodes, G.; Manassen, J.; Cahen, D. J. Electrochem. Soc. 1980,127, 544. doi: 10.1149/1.2129709
12. [12]
  (12) Mitzi, D. B. Inorg. Chem. 2007, 46, 926. doi: 10.1021/ic0621291(12) Mitzi, D. B. Inorg. Chem. 2007, 46, 926. doi: 10.1021/ic0621291
13. [13]
  (13) Hu, L. H.; Dai, S. Y.;Weng, J.; Xiao, S. F.; Sui, Y. F.; Huang, Y.;Chen, S. H.; Kong, F. T.; Pan, X.; Liang, L. Y.;Wang, K. J.J. Phys. Chem. B 2007, 111, 358. doi: 10.1021/jp065541a(13) Hu, L. H.; Dai, S. Y.;Weng, J.; Xiao, S. F.; Sui, Y. F.; Huang, Y.;Chen, S. H.; Kong, F. T.; Pan, X.; Liang, L. Y.;Wang, K. J.J. Phys. Chem. B 2007, 111, 358. doi: 10.1021/jp065541a
14. [14]
  (14) Liu, B.; Aydil, E. S. J. Am. Chem. Soc. 2009, 131, 3985. doi: 10.1021/ja8078972(14) Liu, B.; Aydil, E. S. J. Am. Chem. Soc. 2009, 131, 3985. doi: 10.1021/ja8078972
15. [15]
  (15) Mora-Serö, I.; Giménez, S.; Fabregat-Santia , F.; Gömez, R.;Shen, Q.; Toyoda, T.; Bisquert, J. Accounts Chem. Res. 2009,42, 1848. doi: 10.1021/ar900134d(15) Mora-Serö, I.; Giménez, S.; Fabregat-Santia , F.; Gömez, R.;Shen, Q.; Toyoda, T.; Bisquert, J. Accounts Chem. Res. 2009,42, 1848. doi: 10.1021/ar900134d
16. [16]
  (16) Diguna, L. J.; Shen, Q.; Kobayashi, J.; Toyoda, T. Appl. Phys.Lett. 2007, 91, 023116. doi: 10.1063/1.2757130(16) Diguna, L. J.; Shen, Q.; Kobayashi, J.; Toyoda, T. Appl. Phys.Lett. 2007, 91, 023116. doi: 10.1063/1.2757130
17. [17]
  (17) Shen, Q.; Kobayashi, J.; Diguna, L. J.; Toyoda, T. J. Appl. Phys.2008, 103, 084304. doi: 10.1063/1.2903059(17) Shen, Q.; Kobayashi, J.; Diguna, L. J.; Toyoda, T. J. Appl. Phys.2008, 103, 084304. doi: 10.1063/1.2903059
18. [18]
  (18) nzález-Pedro, V.; Xu, X.; Mora-Seró, I.; Bisquert, J. ACSNano 2010, 4, 5783. doi: 10.1021/nn101534y(18) nzález-Pedro, V.; Xu, X.; Mora-Seró, I.; Bisquert, J. ACSNano 2010, 4, 5783. doi: 10.1021/nn101534y
19. [19]
  (19) Tachan, Z.; Shalom, M.; Hod, I.; Rühle, S.; Tirosh, S.; Zaban, A.J. Phys. Chem. C 2011, 115, 6162. doi: 10.1021/jp112010m(19) Tachan, Z.; Shalom, M.; Hod, I.; Rühle, S.; Tirosh, S.; Zaban, A.J. Phys. Chem. C 2011, 115, 6162. doi: 10.1021/jp112010m
20. [20]
  (20) Buerger, M. J.;Wuensch, B. J. Science 1963, 141, 276. doi: 10.1126/science.141.3577.276(20) Buerger, M. J.;Wuensch, B. J. Science 1963, 141, 276. doi: 10.1126/science.141.3577.276
21. [21]
  (21) Tsao, H. N.; Burschka, J.; Yi, C.; Kessler, F.; Nazeeruddin, M.K.; Grätzel, M. Energy Environ. Sci. 2011, 4, 4921. doi: 10.1039/c1ee02389f(21) Tsao, H. N.; Burschka, J.; Yi, C.; Kessler, F.; Nazeeruddin, M.K.; Grätzel, M. Energy Environ. Sci. 2011, 4, 4921. doi: 10.1039/c1ee02389f
22. [22]
  (22) O'Regan, B.; Moser, J.; Anderson, M.; Grätzel, M. J. Phys.Chem. 1990, 94, 8720. doi: 10.1021/j100387a017(22) O'Regan, B.; Moser, J.; Anderson, M.; Grätzel, M. J. Phys.Chem. 1990, 94, 8720. doi: 10.1021/j100387a017
23. [23]
  (23) Södergren, S.; Hagfeldt, A.; Olsson, J.; Lindquist, S. E. J. Phys.Chem. 1994, 98, 5552. doi: 10.1021/j100072a023(23) Södergren, S.; Hagfeldt, A.; Olsson, J.; Lindquist, S. E. J. Phys.Chem. 1994, 98, 5552. doi: 10.1021/j100072a023
24. [24]
  (24) Solbrand, A.; Lindström, H.; Rensmo, H.; Hagfeldt, A.;Lindquist, S. E.; Södergren, S. J. Phys. Chem. B 1997, 101,2514. doi: 10.1021/jp962819y(24) Solbrand, A.; Lindström, H.; Rensmo, H.; Hagfeldt, A.;Lindquist, S. E.; Södergren, S. J. Phys. Chem. B 1997, 101,2514. doi: 10.1021/jp962819y
25. [25]
  (25) Boix, P. P.; Lee, Y. H.; Fabregat-Santia , F.; Im, S. H.;Mora-Serö, I.; Bisquert, J.; Seok, S., II. ACS Nano 2012, 6, 873.doi: 10.1021/nn204382k
  (25) Boix, P. P.; Lee, Y. H.; Fabregat-Santia , F.; Im, S. H.;Mora-Serö, I.; Bisquert, J.; Seok, S., II. ACS Nano 2012, 6, 873.doi: 10.1021/nn204382k

扫一扫看文章

计量

PDF下载量: 1120
文章访问数: 2207
HTML全文浏览量: 45

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

硫化亚铜对电极在量子点敏化太阳电池中的应用

English

Application of Cu₂S Counter Electrode in Quantum Dot-Sensitized Solar Cells

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

硫化亚铜对电极在量子点敏化太阳电池中的应用

English

Application of Cu2S Counter Electrode in Quantum Dot-Sensitized Solar Cells

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

Application of Cu₂S Counter Electrode in Quantum Dot-Sensitized Solar Cells

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs